Coating composition and articles made therefrom

Patent metadata

Field	Value
Publication number	US-11421112-B2
Application number	US-201816053756-A
Country	US
Kind code	B2
Filing date	Aug 2, 2018
Priority date	Mar 2, 2011
Publication date	Aug 23, 2022
Grant date	Aug 23, 2022

Abstract

The instant invention provides an aqueous dispersion, a coating composition, coating layers and coated article made therefrom. The coating composition according to the present invention comprises: (1) the inventive aqueous dispersion comprising the melt blending product of: (a) from 50 to 99 percent by weight of one or more first polyesters, based on the total solid content of the dispersion, wherein said one or more first polyesters have an acid number in the range of from less than 15, for example less than 10, or in the alternative less than 5, based on the total solid content of the one or more first polyesters; (b) from 1 to 50 percent by weight of one or more stabilizing agents comprising at least one second polyester, based on the total solid content of the dispersion, wherein said second polyester has a carboxylic acid group and an acid number equal to or greater than 15, for example greater than 20, based on the solid content of the second polyester; (c) one or more neutralizing agents; and (d) from 15 to 90 percent by weight of water, based on the total weight of the dispersion; wherein said dispersion has a solid content of 10 to 85 percent, based on the total weight of the dispersion; and (2) one or more cross-linking agents.

First claim

We claim:

1. An aqueous dispersion comprising the melt blending product of:
(a) from 50 to 99 percent by weight of one or more first polyesters, based on the total solid content of the dispersion, wherein said one or more first polyesters have an acid number of <3 mgKOH/g, based on the total solid content of the one or more first polyesters and wherein the first polyester is a hydroxyl functional polyester having a weight average molecular weight of greater than 5000 g/mol;
(b) from 1 to 50 percent by weight of one or more stabilizing agents comprising at least one second polyester, based on the total solid content of the dispersion, wherein said second polyester has a carboxylic acid group and an acid number equal to or greater than 15, based on the solid content of the second polyester;
(c) one or more neutralizing agents; and
(d) from 15 to 90 percent by weight of water, based on the total weight of the dispersion;
(e) one or more crosslinking agents;
wherein said dispersion has a solid content of 10 to 85 percent, based on the total weight of the dispersion, and and wherein the volume average particle size of the dispersion is less than 5 μm (microns).

2. A coating composition comprising:
the aqueous dispersion of claim 1 ;
optionally one or more solvents;
optionally one or more selected from the group consisting of a polyolefin dispersion, acrylic latex, epoxy resin dispersion, polyurethane dispersion, alkyd dispersion, vinyl acetate dispersion, and ethylene vinyl acetate dispersion; and
optionally one or more additives.

3. A method for making a coated article comprising the steps of:
selecting a substrate;
selecting the coating composition of claim 2 ;
applying said coating composition to at least one surface of said substrate;
removing at least a portion of the water from said coating composition;
thereby forming one or more coating layers associated with said substrate; and
thereby forming said coated substrate into a coated article.

4. A method for making a coated article comprising the steps of:
selecting a substrate;
forming said substrate into an article;
selecting the coating composition of claim 2
applying said coating composition to at least one surface of said article;
removing at least a portion of the water from said coating composition;
thereby forming one or more coating layers associated with at least one surface of said article; and
thereby forming said coated article.

5. A can or coil coating composition comprising the coating composition of claim 2 , in which the dispersion has a volume average particle size of less than 5 μm (microns), and wherein the dispersion contains a first polyester, wherein said first polyester is a linear , saturated, aromatic polyester having a glass transition temperature (T g ) in the range of from greater than 50° C., and molecular weight (M w ) of greater than 5,000, and stabilizing agent comprising a second polyester, wherein said stabilizing agent comprising a second polyester which is compatible with the first polyester, and has an acid number of >20 mg KOH/g.

6. A coating comprising: at least one or more film layers derived from the dispersion of claim 1 .

7. A coated article comprising:
one or more substrates;
at least one or more coating layers derived from the dispersion of claim 1 .

8. The coated article according to claim 7 , wherein said substrate is a pre-coated substrate.

9. The dispersion according to claim 1 , wherein said first polyester has a glass transition temperature (T g ) of at least 30° C.

10. A method for producing an aqueous dispersion comprising the steps of:
selecting from 50 to 99 percent by weight of one or more first polyesters, based on the total solid content of the dispersion, the one or more first polyesters having an acid number of <3 mgKOH/g and wherein the first polyester is a hydroxyl functional polyester having a weight average molecular weight of greater than 5000 g/mol;
selecting from 1 to 50 percent by weight of one or more stabilizing agents comprising at least one second polyester, based on the total solid content of the dispersion, the one or more stabilizing agents comprising at least one second polyester having an acid number equal to or greater than 15;
selecting one or more crosslinking agents;
selecting one or more neutralizing agents;
melt-blending said one or more first polyesters, one or more stabilizing agents, and one or more crosslinking agents, and one or more neutralizing agents in the presence of water;
thereby producing an aqueous dispersion having a solid content of 10 to 85 percent, based on the total weight of the dispersion, and wherein the volume average particle size of the dispersion is less than 5 μm (microns).

Assignees

• Dow Global Technologies Llc
• Rohm & Haas

Inventors

• Diehl Charles F
• Kainz Bernhard
• Young Timothy J
• Malotky David L
• Lindenmuth Denise

Classifications

• C08J3/05 Primary

  from solid polymers · CPC title

• B05D2401/20

  Aqueous dispersion or solution · CPC title

• Y10T428/31786

  Of polyester [e.g., alkyd, etc.] · CPC title

• C08L67/03

  the dicarboxylic acids and dihydroxy compounds having the carboxyl- and the hydroxy groups directly linked to aromatic rings · CPC title

• C09D5/02

  Emulsion paints {including aerosols} · CPC title