Coating composition and articles made therefrom

Patent metadata

Field	Value
Publication number	US-10072159-B2
Application number	US-201113983861-A
Country	US
Kind code	B2
Filing date	Mar 2, 2011
Priority date	Mar 2, 2011
Publication date	Sep 11, 2018
Grant date	Sep 11, 2018

Abstract

The instant invention provides an aqueous dispersion, a coating composition, coating layers and coated article made therefrom. The coating composition according to the present invention comprises: (1) the inventive aqueous dispersion comprising the melt blending product of: (a) from 50 to 99 percent by weight of one or more first polyesters, based on the total solid content of the dispersion, wherein said one or more first polyesters have an acid number in the range of from less than 15, for example less than 10, or in the alternative less than 5, based on the total solid content of the one or more first polyesters; (b) from 1 to 50 percent by weight of one or more stabilizing agents comprising at least one second polyester, based on the total solid content of the dispersion, wherein said second polyester has a carboxylic acid group and an acid number equal to or greater than 15, for example greater than 20, based on the solid content of the second polyester; (c) one or more neutralizing agents; and (d) from 15 to 90 percent by weight of water, based on the total weight of the dispersion; wherein said dispersion has a solid content of 10 to 85 percent, based on the total weight of the dispersion; and (2) one or more cross-linking agents.

First claim

We claim:

1. A coating comprising:
at least one or more film layers derived from an aqueous dispersion comprising the melt blending product of:
(a) from 50 to 99 percent by weight of one or more first polyesters, based on the total solid content of the dispersion, wherein said one or more first polyesters have an acid number in the range of from 2 to 3, based on the total solid content of the one or more first polyesters;
(b) from 1 to 50 percent by weight of one or more stabilizing agents comprising at least one second polyester, based on the total solid content of the dispersion, wherein said second polyester has a carboxylic acid group and an acid number equal to or greater than 15, based on the solid content of the second polyester;
(c) one or more neutralizing agents;
(d) from 15 to 90 percent by weight of water, based on the total weight of the dispersion;
(e) one or more crosslinking agents;
wherein said dispersion has a solid content of 10 to 85 percent, based on the total weight of the dispersion, and wherein the volume average particle size of the dispersion is less than 5 microns; wherein said coating has a cross cut adhesion, before retort, rating of at least 3B, measured according to ASTM-D 3359-08, and a Wedge bend pass rating of at least 50 percent measured via a Gardner “COVERALL” Bend Tester 1G 1125.

2. The coating according to claim 1 , wherein said first polyester has a glass transition temperature (T g ) of at least 30° C.

3. A can or coil coating composition the coating of claim 1 .

4. A coated article comprising:
one or more substrates;
at least one or more coating layers derived from an aqueous dispersion comprising the melt blending product of:
(a) from 50 to 99 percent by weight of one or more first polyesters, based on the total solid content of the dispersion, wherein said one or more first polyesters have an acid number in the range of from 2 to 3, based on the total solid content of the one or more first polyesters;
(b) from 1 to 50 percent by weight of one or more stabilizing agents comprising at least one second polyester, based on the total solid content of the dispersion, wherein said second polyester has a carboxylic acid group and an acid number equal to or greater than 15, based on the solid content of the second polyester;
(c) one or more neutralizing agents;
(d) from 15 to 90 percent by weight of water, based on the total weight of the dispersion;
(e) one or more crosslinking agents;
wherein said dispersion has a solid content of 10 to 85 percent, based on the total weight of the dispersion, and wherein the volume average particle size of the dispersion is less than 5 microns; wherein said coating has a cross cut adhesion, before retort, rating of at least 3B, measured according to ASTM-D 3359-08, and a Wedge bend pass rating of at least 50 percent measured via a Gardner “COVERALL” Bend Tester 1G 1125.

5. A method for making a coated article comprising the steps of:
selecting a substrate;
selecting a coating composition comprising an aqueous dispersion comprising the melt blending product of:
(a) from 50 to 99 percent by weight of one or more first polyesters, based on the total solid content of the dispersion, wherein said one or more first polyesters have an acid number in the range of from 2 to 3, based on the total solid content of the one or more first polyesters;
(b) from 1 to 50 percent by weight of one or more stabilizing agents comprising at least one second polyester, based on the total solid content of the dispersion, wherein said second polyester has a carboxylic acid group and an acid number equal to or greater than 15, based on the solid content of the second polyester;
(c) one or more neutralizing agents;
(d) from 15 to 90 percent by weight of water, based on the total weight of the dispersion;
(e) one or more crosslinking agents;
wherein said dispersion has a solid content of 10 to 85 percent, based on the total weight of the dispersion, and wherein the volume average particle size of the dispersion is less than 5 microns;
applying said coating composition to at least one surface of said substrate;
removing at least a portion of the water from said the coating composition;
thereby forming one or more coating layers associated with said substrate; and
thereby forming said coated substrate into a coated article
wherein said coating has a cross cut adhesion, before retort, rating of at least 3B, measured according to ASTM-D 3359-08, and a Wedge bend pass rating of at least 50 percent measured via a Gardner “COVERALL” Bend Tester 1G 1125.

Assignees

• Diehl Charles F
• Kainz Bernhard
• Young Timothy J
• Malotky David L
• Lindenmuth Denise
• Dow Global Technologies Llc
• Rohm & Haas

Inventors

• Diehl Charles F
• Kainz Bernhard
• Young Timothy J
• Malotky David L
• Lindenmuth Denise

Classifications

• C09D5/024

  characterised by the additives · CPC title

• C08L67/02

  Polyesters derived from dicarboxylic acids and dihydroxy compounds (C08L67/06 takes precedence) · CPC title

• C08L2205/02

  containing two or more polymers of the same C08L -group · CPC title

• B05D7/24

  for applying particular liquids or other fluent materials · CPC title

• C08K3/011

  Crosslinking or vulcanising agents, e.g. accelerators · CPC title