Process of improved sulfur capture from a syngas mixture

Patent metadata

Field	Value
Publication number	US-11420155-B2
Application number	US-202016877425-A
Country	US
Kind code	B2
Filing date	May 18, 2020
Priority date	May 17, 2019
Publication date	Aug 23, 2022
Grant date	Aug 23, 2022

Abstract

A process for sweetening a syngas stream, the process comprising the steps of: providing a syngas stream to a nonselective amine absorption unit, the sour syngas stream comprising syngas, carbon dioxide, and hydrogen sulfide; separating the syngas stream in the nonselective amine absorption unit to obtain an overhead syngas stream and an acid gas stream; introducing the acid gas stream to a membrane separation unit, the acid gas stream comprising hydrogen sulfide and carbon dioxide; separating the acid gas stream in the membrane separation unit to produce a retentate stream and a permeate stream, wherein the retentate stream comprises hydrogen sulfide, wherein the permeate stream comprises carbon dioxide; introducing the retentate stream to a sulfur recovery unit; processing the retentate stream in the sulfur recovery unit to produce a sulfur stream and a tail gas stream, wherein the sulfur stream comprises liquid sulfur.

First claim

What is claimed is:

1. A process for sweetening a syngas stream, the process comprising the steps of:
supplying a syngas stream to a nonselective absorption unit, the syngas stream comprising syngas, carbon dioxide, and hydrogen sulfide;
separating the syngas stream in the nonselective absorption unit to obtain an overhead syngas stream and an acid gas stream;
introducing the acid gas stream to a membrane separation unit, the acid gas stream comprising hydrogen sulfide and carbon dioxide;
separating the acid gas stream in the membrane separation unit to produce a retentate stream and a permeate stream, wherein the retentate stream comprises hydrogen sulfide, wherein the permeate stream comprises carbon dioxide;
introducing the retentate stream to a sulfur recovery unit; and
supplying the permeate stream to a selective amine absorption unit and treating the permeate stream using an amine absorption process to obtain an overhead carbon dioxide stream and a recovered hydrogen sulfide stream.

2. The process of claim 1 , wherein a concentration of hydrogen sulfide in the retentate stream is between 50 mol % and 95 mol %.

3. The process of claim 1 , wherein the concentration of hydrogen sulfide in the retentate stream is greater than 90 mol %.

4. The process of claim 1 , wherein a concentration of hydrogen sulfide in the permeate stream is between 0.01 mol % and 0.1 mol %.

5. The process of claim 1 , wherein a concentration of hydrogen sulfide in the overhead syngas stream is between 1 ppm and 1,000 ppm.

6. The process of claim 1 , wherein a concentration of carbon dioxide in the overhead syngas stream is between 1 mol % and 3 mol %.

7. The process of claim 1 , wherein the membrane separation unit comprises a membrane, wherein the membrane is a carbon dioxide-selective membrane.

8. The process of claim 7 , wherein the membrane has carbon dioxide-hydrogen sulfide selectivity of at least 5.

9. The process of claim 7 , wherein the membrane has carbon dioxide-hydrogen sulfide selectivity of at least 10.

10. The process of claim 7 , wherein the membrane has carbon dioxide-hydrogen sulfide selectivity of at least 20.

11. The process of claim 7 , wherein the membrane has carbon dioxide-hydrogen sulfide selectivity of at least 30 .

12. The process of claim 7 , wherein the membrane comprises a perfluorinated polymer.

13. The process of claim 1 , wherein the membrane separation unit comprises a first membrane separation stage and a second membrane separation stage with the first and second membrane separation stages arranged in a retentate-in-series configuration.

14. The process of claim 1 , wherein the membrane separation unit comprises a first membrane separation stage and a second membrane separation stage with the first and second membrane separation stages arranged in a permeate-in-series configuration.

15. The process of claim 1 , further comprising the step of:
discharging the overhead carbon dioxide stream to the atmosphere without subjecting the overhead carbon dioxide stream to any additional hydrogen sulfide separation.

16. A process for recovering sulfur and carbon dioxide from a syngas stream, the process comprising the steps of:
supplying a syngas stream to a nonselective absorption unit, the syngas stream comprising syngas, carbon dioxide, and hydrogen sulfide;
separating the syngas stream in the nonselective absorption unit using an absorption process to produce an overhead syngas stream and an acid gas stream;
introducing the acid gas stream to a selective absorption unit;
processing the acid gas stream in the selective absorption unit to obtain an overhead carbon dioxide stream and a recovered hydrogen sulfide stream;
introducing the recovered hydrogen sulfide stream to a membrane separation unit, the recovered hydrogen sulfide stream comprising hydrogen sulfide and carbon dioxide;
separating the recovered hydrogen sulfide stream in the membrane separation stage to produce a retentate stream and a permeate stream, wherein the retentate stream comprises hydrogen sulfide, wherein the permeate stream comprises carbon dioxide; and
introducing the retentate stream to a sulfur recovery unit.

17. The process of claim 16 , wherein a concentration of hydrogen sulfide in the retentate stream is between 50 mol % and 95 mol %.

18. The process of claim 16 , wherein a concentration of hydrogen sulfide in the overhead carbon dioxide stream is between 0.01 mol % and 0.1 mol %.

19. The process of claim 16 , further comprising the step of discharging the overhead carbon dioxide stream to the atmosphere without subjecting the overhead carbon dioxide stream to any additional hydrogen sulfide separation.

20. The process of claim 16 , wherein the membrane separation unit comprises a membrane, wherein the membrane is a carbon dioxide-selective membrane.

21. The process of claim 20 , wherein the membrane has carbon dioxide-hydrogen sulfide selectivity of at least 5.

22. The process of claim 16 , wherein the membrane separation unit comprises a first membrane separation stage and a second membrane separation stage with the first and second membrane separation stages arranged in a retentate-in-series configuration.

23. The process of claim 16 , wherein the membrane separation unit comprises a first membrane separation stage and a second membrane separation stage with the first and second membrane separation stages arranged in a permeate-in-series configuration.

Assignees

• Saudi Arabian Oil Co
• Membrane Tech And Research Inc
• SAUDI ARABIAN OIL COMPANY and
• Membrane Tech And Research

Inventors

• Vaidya Milind M
• Duval Sebastien A
• Hamad Feras
• Baker Richard
• Merkel Tim
• Lokhandwala Kaaeid
• Huang Ivy
• Bahamdan Ahmad A
• Al-Otaibi Faisal D

Classifications

• B01D53/1468 Primary

  Removing hydrogen sulfide · CPC title

• B01D2252/2021

  Methanol · CPC title

• Y02C20/40

  of CO2 · CPC title

• B01D2252/20431

  Tertiary amines · CPC title

• B01D53/228

  characterised by specific membranes · CPC title