Sulfur recovery process for treating low to medium mole percent hydrogen sulfide gas feeds with BTEX in a Claus unit

Patent metadata

Field	Value
Publication number	US-9593015-B2
Application number	US-201514686950-A
Country	US
Kind code	B2
Filing date	Apr 15, 2015
Priority date	Apr 16, 2014
Publication date	Mar 14, 2017
Grant date	Mar 14, 2017

Abstract

An enrichment apparatus and process for enriching a hydrogen sulfide concentration in an acid gas stream to create a hydrogen sulfide rich stream for feed to a Claus. The enrichment apparatus comprises a hydrocarbon selective separation unit operable to separate the acid gas stream into a hydrocarbon rich stream and a purified acid gas stream, wherein the acid gas stream comprises hydrogen sulfide, carbon dioxide, and hydrocarbons, a hydrogen sulfide selective separation unit operable to separate the purified acid gas stream to create the hydrogen sulfide rich stream and a hydrogen sulfide lean stream, the hydrogen sulfide rich stream having a concentration of hydrogen sulfide, and the Claus unit operable to recover sulfur from the carbon dioxide lean stream. The enrichment apparatus can include a carbon dioxide selective separation unit in fluid communication with the hydrogen sulfide selective separation unit, operable to separate the hydrogen sulfide rich stream.

First claim

What is claimed:

1. An enrichment apparatus for enriching a hydrogen sulfide concentration in an acid gas stream to create a hydrogen sulfide rich stream for feed to a Claus unit, the enrichment apparatus comprising:
a hydrocarbon selective separation unit, the hydrocarbon selective separation unit operable to separate the acid gas stream into a hydrocarbon rich stream and a purified acid gas stream,
wherein the acid gas stream comprises hydrogen sulfide, carbon dioxide, and hydrocarbons,
wherein the hydrocarbon rich stream comprises benzene, toluene, ethyl benzene, and xylene;

a hydrogen sulfide selective separation unit in fluid communication with the hydrocarbon selective separation unit, the hydrogen sulfide selective separation unit operable to separate the purified acid gas stream to create the hydrogen sulfide rich stream and a hydrogen sulfide lean stream, the hydrogen sulfide rich stream having a concentration of hydrogen sulfide; and
the Claus unit in fluid communication with the hydrogen sulfide selective separation unit, the Claus unit operable to recover elemental sulfur from the hydrogen sulfide rich stream.

2. The enrichment apparatus of claim 1 , further comprising:
a carbon dioxide selective separation unit in fluid communication with the hydrogen sulfide selective separation unit, the carbon dioxide selective separation unit operable to separate the hydrogen sulfide rich stream to create a carbon dioxide rich permeate and a hydrogen sulfide rich retentate, the hydrogen sulfide rich retentate having a concentration of hydrogen sulfide.

3. The enrichment apparatus of claim 2 , wherein the carbon dioxide selective separation unit is selected from the group consisting of an amorphous fluoroplastic membrane, an amorphous perfluoropolymer membrane, a random fluorocopolymer membrane, a perfluorinated copolymer membrane, and combinations thereof.

4. The enrichment apparatus of claim 1 , wherein the hydrogen sulfide selective separation unit is selected from the group consisting of polyphosphazene type polymer membranes, polyether-polyamide copolymer membranes, ionic liquid membranes, ionic liquid membrane contactors, and combinations thereof.

5. The enrichment apparatus of claim 1 , wherein the hydrocarbon selective separation unit comprises a PDMS type rubbery polymer membrane.

6. The enrichment apparatus of claim 1 , wherein the acid gas stream further comprises contaminants selected from the group consisting of mercaptans, thiols, carbonyl sulfide, carbon disulfide, and combinations thereof.

7. The enrichment apparatus of claim 1 , wherein the hydrogen sulfide concentration in the acid gas stream is between 15% to 55% by volume.

8. The enrichment apparatus of claim 1 , wherein the concentration of hydrogen sulfide in the hydrogen sulfide rich stream is greater than 55% by volume.

9. A process for enriching a hydrogen sulfide concentration in an acid gas stream to create a hydrogen sulfide rich stream for feeding to a Claus unit, the process comprising the steps of:
feeding the acid gas stream to a hydrocarbon selective separation unit, the acid gas stream comprising hydrogen sulfide, carbon dioxide, and hydrocarbons;
separating the acid gas stream in the hydrocarbon selective separation unit to create a hydrocarbon rich stream and a purified acid gas stream, wherein the hydrocarbon rich stream comprises benzene, toluene, ethyl benzene, and xylene;
feeding the purified acid gas stream to a hydrogen sulfide selective separation unit fluidly connected to the hydrocarbon selective separation unit, the hydrogen sulfide selective separation unit operable to separate the purified acid gas stream;
separating the purified acid gas stream in the hydrogen sulfide selective separation unit to create the hydrogen sulfide rich stream and a hydrogen sulfide lean stream, the hydrogen sulfide rich stream having a concentration of hydrogen sulfide; and
feeding the hydrogen sulfide rich stream to a furnace of the Claus unit, the Claus unit operable to recover elemental sulfur from the hydrogen sulfide rich stream to create an elemental sulfur stream and a waste gas stream.

10. The process of claim 9 , further comprising the steps of:
feeding the hydrogen sulfide rich stream to a carbon dioxide selective separation unit in fluid communication with the hydrogen sulfide selective separation unit, the carbon dioxide selective separation unit operable to separate the hydrogen sulfide rich stream;
separating the hydrogen sulfide rich stream to create a carbon dioxide rich permeate and a hydrogen sulfide rich retentate, the hydrogen sulfide rich retentate having a concentration of hydrogen sulfide; and
feeding the hydrogen sulfide rich retentate to the furnace of the Claus unit.

11. The process of claim 10 , wherein the carbon dioxide selective separation unit is selected from the group consisting of an amorphous fluoroplastic membrane, an amorphous perfluoropolymer membrane, a random fluorocopolymer membrane, a perfluorinated copolymer membrane, and combinations thereof.

12. The process of claim 9 further comprising the step of feeding the hydrocarbon rich stream to a BTX recovery process, the BTX recovery process operable to recover hydrocarbons from the hydrocarbon rich stream.

13. The process of claim 9 , wherein the hydrogen sulfide selective separation unit is selected from the group consisting of polyphosphazene type polymer membranes, polyether-polyamide copolymer membranes, ionic liquid membranes, ionic liquid membrane contactors, and combinations thereof.

14. The process of claim 9 , wherein the hydrocarbon selective separation unit comprises a PDMS type rubbery polymer membrane.

15. The process of claim 9 , wherein the acid gas stream further comprises contaminants is selected from the group consisting of mercaptans, thiols, carbonyl sulfide, carbon disulfide, and combinations thereof.

16. The process of claim 9 , wherein the hydrogen sulfide concentration in the acid gas stream is between 15% to 55% by volume.

17. The process of claim 9 , wherein the hydrogen sulfide rich stream has a hydrogen sulfide concentration greater than 55% by volume.

18. An enrichment apparatus for enriching a hydrogen sulfide concentration in an acid gas stream to create a hydrogen sulfide rich stream for feed to a Claus unit, the enrichment apparatus comprising:
a hydrocarbon selective separation unit, the hydrocarbon selective separation unit operable to separate the acid gas stream into a hydrocarbon rich stream and a purified acid gas stream,
wherein the acid gas stream comprises hydrogen sulfide, carbon dioxide, and hydrocarbons,
wherein the hydrocarbon rich stream comprises benzene, toluene, ethyl benzene, and xylenel;

a carbon dioxide selective separation unit in fluid communication with the hydrocarbon selective separation unit, the carbon dioxide selective separation unit operable to separate the purified acid gas stream to create a carbon dioxide rich stream and a carbon dioxide lean stream, the carbon dioxide lean stream having a concentration of hydrogen sulfide; and
the Claus unit in fluid communication with the carbon dioxide selective separation unit, the Claus unit operable to recover elemental sulfur from the carbon dioxide lean stream.

19. The enrichment apparatus of claim 18 , further comprising:
a hydrogen sulfide selective separation unit in fluid communication with the carbon dioxide selective separation unit, the hydrogen sulfide selective separation unit operable to separate the carbon dioxide rich stream into a hydrogen

Assignees

• Saudi Arabian Oil Co

Inventors

• Ballaguet Jean-Pierre R
• Vaidya Milind M
• Duval Sebastien A
• Harale Aadesh
• Khawajah Anwar H
• Tammana Veera Venkata R

Classifications

• B01D2257/304

  Hydrogen sulfide · CPC title

• B01D53/229

  Integrated processes (Diffusion and at least one other process, e.g. adsorption, absorption) · CPC title

• B01D53/0462

  Temperature swing adsorption · CPC title

• B01D53/228

  characterised by specific membranes · CPC title

• C07C7/12

  by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers · CPC title