Oxide superconductor and method for manufacturing the same

Patent metadata

Field	Value
Publication number	US-10679779-B2
Application number	US-201715438018-A
Country	US
Kind code	B2
Filing date	Feb 21, 2017
Priority date	Aug 10, 2016
Publication date	Jun 9, 2020
Grant date	Jun 9, 2020

Abstract

An oxide superconductor of an embodiment includes an oxide superconductor layer having a continuous Perovskite structure containing rare earth elements, barium (Ba), and copper (Cu). The rare earth elements contain a first element which is praseodymium (Pr), at least one second element selected from the group consisting of neodymium (Nd), samarium (Sm), europium (Eu), and gadolinium (Gd), at least one third element selected from the group consisting of yttrium (Y), terbium (Tb), dysprosium (Dy), and holmium (Ho), and at least one fourth element selected from the group consisting of erbium (Er), thulium (Tm), ytterbium (Yb), and lutetium (Lu).

First claim

What is claimed is:

1. An oxide superconductor, comprising:
an oxide superconductor layer having a continuous Perovskite structure including rare earth elements, barium (Ba), and copper (Cu),
wherein:
the rare earth elements include a first element, at least one second element, at least one third element, and at least one fourth element,
the first element is praseodymium (Pr),
the at least one second element is selected from the group consisting of neodymium (Nd), samarium (Sm), europium (Eu), and gadolinium (Gd),
the at least one third element is selected from the group consisting of yttrium (Y), terbium (Tb), dysprosium (Dy), and holmium (Ho), and
the at least one fourth element is selected from the group consisting of erbium (Er), thulium (Tm), ytterbium (Yb), and lutetium (Lu).

2. The oxide superconductor according to claim 1 , wherein the oxide superconductor layer includes fluorine (F) of 2.0×10 15 atoms/cc or more and 5.0×10 19 atoms/cc or less and carbon (C) of 1.0×10 17 atoms/cc or more and 5.0×10 20 atoms/cc or less.

3. The oxide superconductor according to claim 1 , wherein, when the number of atoms of the rare earth elements is N(RE), and the number of atoms of the at least one third element is N(MA), N(MA)/N(RE)≥0.6 is satisfied.

4. The oxide superconductor according to claim 1 , wherein, when the number of atoms of the rare earth elements is N(RE), and the number of atoms of the first element is N(PA), 0.00000001≤N(PA)/N(RE) is satisfied.

5. The oxide superconductor according to claim 1 , wherein, when the number of atoms of the rare earth elements is N(RE), the number of atoms of the first element is N(PA), and the number of atoms of the at least one second element is N(SA), (N(PA)+N(SA))/N(RE)≤0.2 is satisfied.

6. The oxide superconductor according to claim 1 , wherein, when the number of atoms of the at least one third element is N(MA), and the number of atoms of yttrium included in the at least one third element is N(Y), N(Y)/N(MA)≥0.5 is satisfied.

7. The oxide superconductor according to claim 1 , wherein, when the number of atoms of the first element is N(PA), and the number of atoms of the at least one second element is N(SA), 0.05≤N(PA)/(N(PA)+N(SA))≤0.5 is satisfied.

8. The oxide superconductor according to claim 1 , wherein, when the number of atoms of the first element is N(PA), the number of atoms of the at least one second element is N(SA), and the number of atoms of the at least one fourth element is N(CA), 0.8×N(CA)≤N(PA)+N(SA)≤1.2×N(CA) is satisfied.

9. The oxide superconductor according to claim 1 , wherein, in a HAADF-STEM image of the oxide superconductor layer including a first area and a second area, when brightness of the barium is represented by I(Ba), and brightness of the rare earth elements sandwiched by the barium is represented by I(RE), I(RE)/I(Ba) in the first area is 1.3 times or more of I(RE)/I(Ba) in the second area.

10. The oxide superconductor according to claim 1 , further comprising:
a substrate; and
a metal layer,
wherein the oxide superconductor layer is disposed between the substrate and the metal layer.

11. The oxide superconductor according to claim 1 , wherein the continuous Perovskite structure has a size of 500 nm×100 nm or more in a cross section of the oxide superconductor layer in a layer thickness direction thereof.

12. An oxide superconductor, comprising:
an oxide superconductor layer having a continuous Perovskite structure including rare earth elements, barium (Ba), and copper (Cu),
wherein:
the rare earth elements include a first element, at least one second element, and at least one third element,
the first element is praseodymium (Pr),
the at least one second element is selected from the group consisting of gadolinium (Gd), yttrium (Y), terbium (Tb), dysprosium (Dy), and holmium (Ho), and
the at least one third element is being selected from the group consisting of erbium (Er), thulium (Tm), ytterbium (Yb), and lutetium (Lu).

13. The oxide superconductor according to claim 12 , wherein the oxide superconductor layer includes fluorine of 2.0×10 15 atoms/cc or more and 5.0×10 19 atoms/cc or less and carbon of 1.0×10 17 atoms/cc or more and 5.0×10 20 atoms/cc or less.

14. The oxide superconductor according to claim 12 , wherein, when the number of atoms of the rare earth elements is N(RE), and the number of atoms of the at least one second element is N(MA), N(MA)/N(RE)≥0.6 is satisfied.

15. The oxide superconductor according to claim 12 , wherein, when the number of atoms of the rare earth elements is N(RE), and the number of atoms of the first element is N(PA), 0.00000001≤N(PA)/N(RE) is satisfied.

16. The oxide superconductor according to claim 12 , wherein, when the number of atoms of the rare earth elements is N(RE), and the number of atoms of the first element is N(PA), N(PA)/N(RE)≤0.2 is satisfied.

17. The oxide superconductor according to claim 12 , wherein, when the number of atoms of the at least one second element is N(MA), and the number of atoms of yttrium included in the second element is N(Y), N(Y)/N(MA)≥0.5 is satisfied.

18. The oxide superconductor according to claim 12 , further comprising:
a substrate; and
a metal layer,
wherein the oxide superconductor layer is disposed between the substrate and the metal layer.

Assignees

• Toshiba Kk

Inventors

• Araki Takeshi
• Ishii Hirotaka
• Kobayashi Nao

Classifications

• C04B35/64

  Burning or sintering processes (C04B33/32 takes precedence {; powder metallurgy B22F}) · CPC title

• H01L39/143

  Electricity · mapped topic

• C04B2235/449

  Organic acids, e.g. EDTA, citrate, acetate, oxalate · CPC title

• C04B35/624

  Sol-gel processing · CPC title

• C04B2235/3215

  Barium oxides or oxide-forming salts thereof · CPC title