Method for modifying polycarbonate blends

Patent metadata

Field	Value
Publication number	US-11414540-B2
Application number	US-201816767741-A
Country	US
Kind code	B2
Filing date	Dec 4, 2018
Priority date	Dec 29, 2017
Publication date	Aug 16, 2022
Grant date	Aug 16, 2022

Abstract

Provided is a method of modifying a blend of polycarbonate and acrylonitrile/butadiene/styrene copolymer comprising adding composite particles to the blend, wherein the composite particles comprise(I) a partially crosslinked polyolefin core and(II) a full or partial shell comprising polymerized units of one or more vinyl monomer, and the resulting modified blend.

First claim

The invention claimed is:

1. A method of modifying a blend of polycarbonate and acrylonitrile/butadiene/styrene copolymer comprising adding composite particles to the blend, wherein the composite particles comprise
(I) a partially crosslinked polyolefin core, wherein the partially crosslinked polyolefin core has a gel fraction of 10% or higher and less than 100%; and
(II) a full or partial shell comprising polymerized units of one or more vinyl monomer.

2. The method of claim 1 wherein the vinyl monomer comprises one or more (meth)acrylate monomer.

3. The method of claim 1 wherein the vinyl monomer comprises one or more unsubstituted alkyl ester of (meth)acrylic acid.

4. The method of claim 1 , wherein the partially crosslinked polyolefin core has gel fraction of 15% or higher and 50% or less.

5. The method of claim 1 , wherein the partially crosslinked polyolefin core is made by a process that comprises performing a crosslinking reaction on an initial polyolefin particle, wherein the initial polyolefin particle comprises one or more polyolefins, and wherein each of the polyolefins in the initial polyolefin particle has melt flow rate at 2.16 kg load at 190° C. of 50 g per 10 minutes or higher.

6. The method of claim 1 , wherein the partially crosslinked polyolefin core is prepared with an ethylene-propylene-diene copolymer crosslinking agent.

7. A compounded composition comprising polycarbonate, acrylonitrile/butadiene/styrene copolymer, and composite particles, wherein the composite particles comprise
(I) a partially crosslinked polyolefin core, wherein the partially crosslinked polyolefin core has a gel fraction of 10% or higher and less than 100%; and
(II) a full or partial shell comprising polymerized units of one or more vinyl monomer.

8. The composition of claim 7 ,
wherein the polycarbonate is present in an amount of 40 to 95% by weight, based on the sum of the weights of the polycarbonate and the acrylonitrile/butadiene/styrene copolymer,
and wherein the composite particles are present in an amount of 1 to 40% by weight based on the total of sum of the weights of the composite particles, the polycarbonate, and the acrylonitrile/butadiene/styrene copolymer.

9. The composition of claim 7 , wherein the amount of the shell that is grafted to the core is 40% or more by weight based on the weight of the shell.

10. The composition of claim 7 , wherein the partially crosslinked polyolefin core is prepared with an ethylene-propylene-diene copolymer crosslinking agent.

Assignees

• Dow Global Technologies Llc
• Rohm & Haas

Inventors

• Chen Liang
• Cruz Carlos A
• Saint-Gerard Yannick
• Huang Jessica Ye
• Crimmins Matthew J
• Hasso Douglas J

Classifications

• C08L55/02

  ABS [Acrylonitrile-Butadiene-Styrene] polymers · CPC title

• C08L69/00 Primary

  Compositions of polycarbonates; Compositions of derivatives of polycarbonates · CPC title

• C08F255/06

  on to ethylene-propylene-diene terpolymers {(C08F255/023 takes precedence)} · CPC title

• C08L2207/53

  Core-shell polymer · CPC title

• C08L51/06 Primary

  grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond · CPC title