Nanofibers and preparation methods therefor

Patent metadata

Field	Value
Publication number	US-11401629-B2
Application number	US-202017608989-A
Country	US
Kind code	B2
Filing date	Nov 13, 2020
Priority date	Nov 13, 2020
Publication date	Aug 2, 2022
Grant date	Aug 2, 2022

Abstract

The present invention discloses a method for preparing graphene nanofibers and non-woven fabrics using a fluid with a ultra-high draw ratio by means of a high-voltage electrospinning method. Compared with other methods for preparing graphene fibers (such as wet spinning, air-assisted spinning, etc.), the graphene fibers obtained by the present method have smaller diameters (about 100 nm to 500 nm) and a higher yield. The fibers themselves have better mechanical and electrical properties. The invention discloses a method for preparing ultra-fine graphene nanofibers and non-woven fabrics by electrospinning a mixed spinning liquid system of polymer and graphene oxide (the polymer is sodium polyacrylate). This method is highly efficient and environmentally friendly, and the resulted graphene nanofibers are the thinnest graphene fibers as currently known.

First claim

What is claimed is:

1. A preparation method for a nano-fiber, comprising steps of:
(1): preparing a mixed spinning solution with an ultra-high draw ratio using sodium polyacrylate and graphene oxide, wherein the ultra-high draw ratio is a draw ratio of no less than 2000%, the graphene oxide (GO) in the spinning solution has sheets with sizes ranging from 20 μm to 30 μm and a concentration ranging from 0.5 wt % to 1.2 wt %, and a mass fraction ranging from 30% to 60% relative to a total mass of the sodium polyacrylate and the graphene oxide; and
(2): electrospinning the mixed spinning solution prepared in step (1) to obtain a graphene oxide-sodium polyacrylate composite nanofiber, wherein the graphene oxide sheets in the composite nanofiber are overlapped and connected one after another along an axial direction of the fiber, and roll in a circumferential direction.

2. The preparation method of claim 1 , further comprising step of:
chemically reducing the composite nanofiber obtained in step (2) to obtain a reduced graphene oxide-sodium polyacrylate composite nanofiber.

3. The preparation method of claim 2 , further comprising step of:
subjecting the chemically reduced graphene oxide-sodium polyacrylate composite nanofiber to a two-step thermal treatment to obtain a pure graphene fiber.

4. The preparation method of claim 1 , wherein a mass ratio of the sodium polyacrylate (PAAS) to the graphene oxide in step (1) is 1:1.

5. The preparation method of claim 2 , wherein the step of chemically reducing is fumigating at 95° C. for 12 hours using hydroiodic acid.

6. The preparation method of claim 3 , wherein the thermal treatment is conducted in an inert atmosphere of 1000° C. and 2800° C. in turn for 1 hour.

Assignees

• Univ Zhejiang

Inventors

• Gao Chao
• Wang Jiaqing

Classifications

• Y02E60/13

  Energy storage using capacitors · CPC title

• D01F9/21 Primary

  from macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds · CPC title

• C01B32/192

  starting from graphitic oxides · CPC title

• D01F6/16

  from polymers of unsaturated carboxylic acids or unsaturated organic esters, e.g. polyacrylic esters, polyvinyl acetate · CPC title

• D01D5/003

  the material being a polymer solution or dispersion (D01D5/0053 takes precedence) · CPC title