Block copolymer compositions, prepregs, and laminates made therefrom

Patent metadata

Field	Value
Publication number	US-11401410-B2
Application number	US-202016864406-A
Country	US
Kind code	B2
Filing date	May 1, 2020
Priority date	May 3, 2019
Publication date	Aug 2, 2022
Grant date	Aug 2, 2022

Abstract

A resin composition that allows production of laminated sheets excellent in heat resistance and processability is disclosed. The resin composition comprises: a) a block copolymer, where the block copolymer comprises at least one polymer block comprising polymerized acyclic conjugated diene units, such as butadiene units, and at least one polymer block containing units like a conjugated cyclic diene such as 1,3-cyclohexadiene or monomer units characterized by unit Tg above 100° C., b) a curing initiator, and c) optionally diene-based polymer selected from a polybutadiene polymer and the copolymer of butadiene with styrene or other styrenic monomers, c) optional additives comprising but not limited to a multi-functional co-curable additive, a diene based rubber, a halogenated or non halogenated flame retardant, an inorganic or organic filler or fiber, an antioxidant, a adhesion promotor, a film forming.

First claim

The invention claimed is:

1. A curable resin composition comprising:
(a) 5 to 99 wt. % of a block copolymer, wherein the block copolymer contains at least an A block and at least one of B, B′, and C block;

wherein each A block is a non hydrogenated poly(acyclic conjugated diene) polymer comprising polymerized units of at least one acyclic conjugated diene;
each B block is a poly(1,3-cyclodiene) homopolymer with a GPC block molecular weight Mp of <25 kg/mol,
each B′ block is a poly(1,3-cyclodiene-co-monoalkenyl arene) copolymer with a GPC block molecular weight Mp of <30 kg/mol,
each C block is a poly(alkenyl arene) polymer or copolymer containing at least one high Tg alkenyl arene unit having a Tg of >100° C., and
the block copolymer has a GPC peak molecular weight Mp of <50 kg/mol before coupling;
the block copolymer has a GPC peak molecular weight Mp multiplied by the A block content weight fraction of >500 g/mol;
(b) from 0.1 to 10 wt. % of a cure initiator; and
c) up to 95 wt. % of one or more additives selected from a multi-functional co-curable additive, a diene based rubber, a halogenated or non halogenated flame retardant, an inorganic or organic filler or fiber, an antioxidant, a adhesion promotor, and a film forming polymer;

wherein the curable resin composition after curing has a gel content of >15%.

2. The curable resin composition of claim 1 , wherein the block copolymer has a GPC peak molecular weight Mp of <35 kg/mol before coupling.

3. The curable resin composition of claim 1 , wherein the block copolymer (a) contains less than 5 wt. % of atoms different from carbon and hydrogen.

4. The curable resin composition of claim 1 , wherein the block copolymer (a) has a DSC Tg>100° C.; and a solution viscosity at 25 wt. % in toluene at 25° C. of <2000 mPa·s.

5. The curable resin composition of claim 1 , wherein
each A block is a polybutadiene block with <50 wt. % of 1, 4 polymerized units;
the B and B′ blocks each independently has a GPC block molecular weight Mp of <9 kg/mol; and
the C block has a GPC block molecular weight Mp of <20 kg/mol.

6. The curable resin composition of claim 1 , wherein:
the cure initiator (b) is a peroxide having a 1-hour half-life temperature of >120° C.; and
the one or more additives is a multi-functional co-curable selected from DVB, BVPE, TAC, TAIC, vinyl functionalized PPE resin, bismaleimide resin, diene-based polymer in liquid state or solid state at room temperature;
wherein the diene-based polymer is selected from polybutadienes, polyisoprenes, butadiene-styrene copolymers, isoprene-styrene copolymers, tri-block copolymers of butadiene-styrene-methacrylate, butadiene-styrene-divinylbenzene, butadiene-styrene-acrylonitrile copolymers, butadiene-styrene-maleic anhydride copolymers and combinations thereof.

7. The curable resin composition of claim 1 , wherein the block copolymer (a) has a solution viscosity at 25° C. at 50 wt. % in xylene of less than 10,000 mPa·s, a dielectric constant Dk at 1 gigahertz of <2.6, and a dielectric loss factor Df at 1 gigahertz of <0.003.

8. The curable resin composition of claim 1 , further comprising up to 15 wt. % of an adhesion promoting polymer selected from a poly(arylene ether), a carboxy-functionalized poly(arylene ether), and a styrene-ethylene/butylene-styrene (SEBS) functionalized with maleic anhydride.

9. A prepreg formed by:
(A) coating a substrate with a solution obtained by dissolving from 5 wt. % to up to 90 wt. % of the curable resin composition to of claim 1 in a solvent, and evaporating the solvent forming a coated substrate;
or
(B) impregnating the curable resin composition of claim 1 , into a substrate forming an impregnated substrate, and heat-pressing the impregnated substrate with or without additional curable resin composition; and
forming the prepreg.

10. The prepreg of claim 9 , wherein in the step (A) the solvent is selected from toluene, xylene, MEK, and mixtures thereof, and wherein the solvent is evaporated from the coated substrate at a temperatures below the activating temperature of the cure initiator (b) in the curable resin composition, or for a sufficient amount of time to limit the curing at a level not reaching gel time, forming the coated substrate.

11. A laminated sheet prepared by layering the prepreg of claim 9 with at least a layer of copper foil on at least a surface of the prepreg under heat-pressing conditions.

12. A copper clad laminate comprising the laminated sheet of claim 11 .

13. A printed circuit board comprising the copper clad laminate of claim 12 .

14. A product comprising the curable resin of claim 1 .

15. A curable resin composition comprising:
(a) 5 to 99 wt. % of a block copolymer, wherein the block copolymer contains at least an A block and at least one of B, B′, and C block;

wherein each A block is a non hydrogenated poly(acyclic conjugated diene) polymer comprising polymerized units of at least one acyclic conjugated diene;
each B block is a poly(1,3-cyclodiene) homopolymer with a GPC block molecular weight Mp of <25 kg/mol,
each B′ block is a poly(1,3-cyclodiene-co-monoalkenyl arene) copolymer with a GPC block molecular weight Mp of <30 kg/mol,
each C block is a poly(alkenyl arene) polymer or copolymer containing at least one high Tg alkenyl arene unit having a Tg of >100° C., and
the block copolymer has a GPC peak molecular weight Mp of <50 kg/mol before coupling;
the block copolymer has a GPC peak molecular weight Mp multiplied by the A block content weight fraction of >500 g/mol;
(b) from 0.1 to 10 wt. % of a cure initiator; and
(c) up to 95 wt. % of one or more additives selected from a multi-functional co-curable additive, a diene based rubber, a halogenated or non halogenated flame retardant, an inorganic or organic filler or fiber, an antioxidant, a adhesion promotor, and a film forming polymer;

wherein the block copolymer has a structure selected from any of: A-B, (A-B-) n X, A-B′, (A-B′-) n X, A-B-A, A-B′-A, A-B-C, A-B′-C, A-C-B, A-C-B′, (B-A-) n X, (B′-A-) n X, B-A-B, B′-A-B′, (A-C-B-) n X, (A-C-B′-) n X, A-C-B-A, A-C-B′-A, A-C, A-C-A, and (A-C-) n X;
n is an integer from 2 to 50 and X is a coupling agent residue.

16. A circuit subassembly, comprising:
a conductive metal layer,
a substrate coated with a curable resin composition, wherein the curable resin composition comprises:
(a) 5 to 99 wt. % of a block copolymer, wherein the block copolymer contains at least an A block and at least one of B or B′ or C block;

wherein each A block is a non hydrogenated poly(acyclic conjugated diene) polymer comprising polymerized units of at least one acyclic conjugated diene;
each B block is a poly(1,3-cyclodiene) homopolymer with a GPC block molecular weight Mp of <25 kg/mol,
each B′ block is a poly(1,3-cyclodiene-co-monoalkenyl arene) copolymer with a GPC block molecular weight Mp of <30 kg/mol,
each C block is a poly(alkenyl arene) polymer or copolymer containing at least one high Tg alkenyl arene unit having a Tg of >100° C., and
the block copolymer has a GPC peak molecular weight Mp of <50 kg/mol before coupling;
the block copolymer has a GPC peak molecular weight Mp multiplied by the A block content weight fraction of >500 g/mol;
(b) from 0.1 to 10 wt. % of a cure initiator; and
(c) up to 95 wt. % of one or more additives selected from a multi-functional co-curable additive, a diene based rubber, a halogenated or non halogenated flame retardant, an inorganic or organic filler or fiber, an antioxidant, a adhesion promotor, and a film forming polymer;

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Assignees

• Kraton Polymers Llc

Inventors

• Ding Ruidong
• Niu Yaming
• Yang Bing
• Muyldermans Xavier
• De Wit Frank
• Yang Huixian

Classifications

• C08L53/00 Primary

  Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers · CPC title

• H05K1/0366

  reinforced, e.g. by fibres, fabrics (H05K1/036 takes precedence) · CPC title

• B32B2260/046

  Synthetic resin · CPC title

• C08F297/02

  using a catalyst of the anionic type · CPC title

• B29B15/125

  by dipping · CPC title