Photocurable compositions for stereolithography, method of forming the compositions, stereolithography methods using the compositions, polymer components formed by the stereolithography methods, and a device including the polymer components

Patent metadata

Field	Value
Publication number	US-11401353-B2
Application number	US-202016887320-A
Country	US
Kind code	B2
Filing date	May 29, 2020
Priority date	May 30, 2019
Publication date	Aug 2, 2022
Grant date	Aug 2, 2022

Abstract

A photocurable composition for stereolithographic three-dimensional printing, wherein the photocurable composition comprises a photoreactive oligomer component comprising a hydrophobic oligomer comprising a photoreactive end group, a photoreactive monomer component comprising a photoreactive monomer having a photoreactive end group, and a photoinitiation composition comprising a photoinitiator; the photocurable composition has a viscosity of 250 to 10,000 centipoise at 22° C., determined using a Brookfield viscometer; and the photocured composition has a dielectric loss of less than 0.010, preferably less than 0.008, more preferably less than 0.006, most preferably less than 0.004, each determined by split-post dielectric resonator testing at 10 gigahertz at 23° C.

First claim

What is claimed is:

1. A photocurable composition for stereolithographic three-dimensional printing, wherein
the photocurable composition comprises
a photoreactive oligomer component comprising a hydrophobic oligomer comprising a photoreactive end group,
a photoreactive monomer component comprising a photoreactive monomer having a photoreactive end group, wherein the photoreactive monomer component comprises at least 50% by weight of a methacrylate-functional monomer, and
a photoinitiation composition comprising a photoinitiator;

the photocurable composition has a viscosity of 250 to 10,000 centipoise at 22° C., determined using a Brookfield viscometer; and
the photocured composition has a dielectric loss of less than 0.010 determined by split-post dielectric resonator testing at 10 gigahertz at 23° C.

2. The photocurable composition of claim 1 , comprising
35 to 85 weight percent of the photoreactive oligomer component,
15 to 65 weight percent of the photoreactive monomer component, and
0.01 to 15 weight percent of the photoinitiation composition,

wherein each weight percent is based on the total weight of the photoreactive oligomer component, the photoreactive monomer component, and the photoinitiation composition, and totals 100 weight percent.

3. The photocurable composition of claim 1 , wherein the hydrophobic oligomer of the photoreactive oligomer component comprises a (meth)acrylate end group.

4. The photocurable composition of claim 1 , wherein the hydrophobic oligomer of the photoreactive oligomer component is a (meth)acrylate-derivatized polyester, a (meth)acrylate urethane-derivatized polybutadiene oligomer, or a combination thereof.

5. The photocurable composition of claim 1 , wherein the hydrophobic oligomer of the photoreactive oligomer component comprises a urethane (meth)acrylate-derivatized polybutadiene oligomer having a number average molecular weight of 500 to 5,000 grams per mole.

6. The photocurable composition of claim 1 , wherein the photoreactive monomer comprises a methacrylate end group.

7. The photocurable composition of claim 6 , wherein a monomer having an acrylate end group is present in an amount of 20 weight percent or less, based on the total weight of the photoreactive oligomer component and the photoreactive monomer component.

8. The photocurable composition of claim 7 ,
wherein the photoreactive monomer component comprises a combination of ethylene glycol dimethacrylate, trimethylol propane trimethacrylate, and isobornyl methacrylate.

9. The photocurable composition of claim 1 , further comprising a particulate filler in an amount of 5 to 60 vol % based on the total volume of the photocurable composition.

10. The photocurable composition of claim 9 ,
wherein the particulate filler comprises silica, alumina, calcium titanate, strontium titanate, barium titanate, barium nonatitanate, boron nitride, aluminum nitride, or a combination thereof.

11. The photocurable composition of claim 1 , wherein the photoinitiation composition further comprises an ultraviolet light-absorbing agent in an amount of 0.01 to 10 weight percent, based on the total weight of the photoreactive oligomer component, the photoreactive monomer component, and the photoinitiation composition, which totals 100 weight percent.

12. The photocurable composition of claim 1 , wherein the photoinitiation composition further comprises scintillating agent in an amount of 0.01 to 2 weight percent, based on the total weight of the photoreactive oligomer component, the photoreactive monomer component, and the photoinitiation composition and totals 100 weight percent.

13. The photocurable composition of claim 1 , having a relative permittivity of 2 to 12 at 10 gigahertz.

14. A three-dimensional structure comprising a photocured product of the composition of claim 1 .

15. The three-dimensional structure of claim 14 , having a dielectric loss of less than 0.004 at 10 GHz as determined by split-post dielectric resonator testing at 10 gigahertz at a temperature of 23° C.

16. The three-dimensional structure of claim 14 , wherein the structure is porous.

17. An electronic device comprising the three-dimensional structure of claim 14 .

18. The electronic device of claim 17 , wherein the device is an impedance-matching layer, a dielectric waveguide, a lens, a reflective array, an antenna matching structure, a superstrate, a coupler, a divider, a radome, or a dielectric antenna, wherein at least one electrical conductor is disposed on or in contact with the photocured product.

19. A stereolithographic method of manufacture of a three-dimensional polymer structure, the method comprising:
providing a volume comprising the photocurable composition of claim 1 ;
irradiating a portion of the composition with activating radiation in a pattern to form a photocured layer of the structure;
contacting the layer with the photocurable composition;
irradiating the photocurable composition with activating radiation in a pattern to form a second photocured layer on the first layer; and
repeating the contacting and irradiating to form the three-dimensional polymer structure.

20. The method of claim 19 , further comprising thermally curing the three-dimensional structure.

21. A three-dimensional structure made by the method of claim 19 wherein the structure is porous.

22. An electronic device comprising the three-dimensional structure of claim 21 , wherein the device is an impedance-matching layer, a dielectric waveguide, a lens, a reflective array, an antenna matching structure, a superstrate, a coupler, a divider, a radome, or a dielectric antenna.

23. The photocurable composition of claim 1 , having a dielectric loss of less than 0.004.

24. The photocurable composition of claim 3 , wherein the hydrophobic oligomer of the photoreactive oligomer component comprises two or more methacrylate end groups.

25. The photocurable composition of claim 6 , wherein the photoreactive monomer comprises two or more methacrylate end groups.

26. The photocurable composition of claim 9 , comprising the particulate filler in an amount of 10 to 50 vol %, based on the total volume of the photocurable composition.

27. The photocurable composition of claim 10 , wherein the particulate filler comprises alumina, barium nonatitanate, or combination thereof.

28. The photocurable composition of claim 1 , wherein the photoreactive monomer component comprises at least 60% by weight of the methacrylate-functional monomer.

29. The photocurable composition of claim 1 , wherein the photoreactive monomer component comprises at least 70% by weight of the methacrylate-functional monomer.

Assignees

• Rogers Corp

Inventors

• Polidore Trevor
• Baars Dirk
• Koes Thomas A
• Fitts Bruce
• Sethumadhavan Murali

Classifications

• G03F7/027 Primary

  Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds (G03F7/075 takes precedence) · CPC title

• C08F279/02 Primary

  on to polymers of conjugated dienes · CPC title

• C08F2/50 Primary

  with sensitising agents · CPC title

• G03F7/0037

  Production of three-dimensional images · CPC title

• C08F22/1006

  of polyhydric alcohols or polyhydric phenols, e.g. ethylene glycol dimethacrylate · CPC title