Viscoelastic, solid surfactant composition

Patent metadata

Field	Value
Publication number	US-11396641-B2
Application number	US-201916714255-A
Country	US
Kind code	B2
Filing date	Dec 13, 2019
Priority date	Jun 16, 2017
Publication date	Jul 26, 2022
Grant date	Jul 26, 2022

Abstract

A viscoelastic, solid surfactant composition, containing, (i) a total amount of 0.1 to 70 wt % of at least one surfactant, (ii) a total amount of more than 1 wt % of at least one benzylidene alditol compound of formula (I), and (iii) water, is a readily soluble, aesthetically pleasing and storage-stable form of a solid composition for providing surfactant-containing liquors.

First claim

What is claimed is:

1. A viscoelastic, solid surfactant composition comprising, based on the total weight thereof,
(i) a total amount of from 0.1 to 70 wt. % of at least one surfactant, and
(ii) a total amount of more than 1 wt. % of at least one benzylidene alditol compound of formula (I)

in which
*- represents a covalent single bond between an oxygen atom of the alditol backbone and the provided functional group,
n represents 0 or 1,
m represents 0 or 1,
R 1 , R 2 and R 3 represent, independently of one another, a hydrogen atom, a halogen atom, a C 1 -C 4 alkyl group, a cyano group, a nitro group, an amino group, a carboxyl group, a hydroxy group, a —C(═O)—NH—NH 2 group, a —NH—C(═O)—(C 2 -C 4 -alkyl) group, a C 1 -C 4 alkoxy group, a C 1 -C 4 alkoxy C 2 -C 4 alkyl group, with two of the functional groups forming together with the remainder of the molecule a 5-membered or 6-membered ring,
R 4 , R 5 and R 6 represent, independently of one another, a hydrogen atom, a halogen atom, a C 1 -C 4 alkyl group, a cyano group, a nitro group, an amino group, a carboxyl group, a hydroxy group, a —C(═O)—NH—NH 2 group, a —NH—C(═O)—(C 2 -C 4 -alkyl) group, a C 1 -C 4 alkoxy group, a C 1 -C 4 alkoxy C 2 -C 4 alkyl group, with two of the functional groups forming together with the remainder of the molecule a 5-membered or 6-membered ring,
(iii) water,
(iv) at least one stabilizer selected from the group consisting of magnesium sulfate, zinc acetate, calcium acetate, acetamide monoethanolamine, hexamethylenetetramine, guanidine, polypropylene glycol ether, salt of amino acids, or mixtures thereof,
wherein the surfactant composition is a viscoelastic solid.

2. The composition according to claim 1 , wherein the surfactant composition has a storage modulus of between 10 3 Pa and 10 8 Pa and a loss modulus (at 20° C., with a deformation of 0.1% and a frequency of 1 Hz), and the storage modulus in the frequency range between 10′ Hz and 10 Hz is at least twice as great as the loss modulus.

3. The composition according to claim 1 , wherein it comprises at least one anionic surfactant.

4. The composition according to claim 3 , wherein at least one anionic surfactant selected from the group consisting of C 8-18 alkylbenzene sulfonates, olefin sulfonates, C 12-18 alkane sulfonates, ester sulfonates, alkyl sulfates, alkenyl sulfates, fatty alcohol ether sulfates and mixtures thereof.

5. The composition according to claim 1 , comprising at least one compound of formula (T1)

in which
R′ and R″ are, independently of one another, H or alkyl, and together comprise 9 to 19 C atoms, and Y + is a monovalent cation or the nth part of an n-valent cation.

6. The composition according to claim 1 , wherein it comprises at least one non-ionic surfactant.

7. The composition according to claim 1 , wherein the alditol backbone according to formula (I) is derived from D-glucitol, D-mannitol, D-arabinitol, D-ribitol, D-xylitol, L-glucitol, L-mannitol, L-arabinitol, L-ribitol, or L-xylitol.

8. The composition according to claim 1 , wherein R 1 , R 2 , R 3 , R 4 , R 5 and R 6 are, independently of one another, a hydrogen atom, methyl, ethyl, chlorine, fluorine, or methoxy.

9. The composition according to claim 1 , wherein it comprises as a benzylidene alditol compound of formula (I) at least one compound of formula (I-1)

10. The composition according to claim 1 , wherein the benzylidene alditol compound of formula (I) is selected from 1,3:2,4-di-O-benzylidene-D- sorbitol; 1,3:2,4-di-O-(p-methylbenzylidene)-D-sorbitol; 1,3:2,4-di-O-(p-chlorobenzylidene)-D-sorbitol; 1,3:2,4-di-O-(2,4-dimethylbenzylidene)-D-sorbitol; 1,3:2,4-di-O-(p-ethylbenzylidene)-D-sorbitol; 1,3:2,4-di-O-(3,4-dimethylbenzylidene)-D-sorbitol or mixtures thereof.

11. The composition according to claim 1 , wherein the benzylidene alditol compound of formula (I) comprises a total amount of more than 1.5 wt. %.

12. The composition according to claim 1 , wherein water comprises a total amount of 20 wt. % or less.

13. The composition according to claim 1 , wherein it additionally comprises at least one organic solvent having at least one hydroxyl group, no amino group and having a molecular weight of at most 500 g/mol.

14. The composition according to claim 1 , further comprising at least one polyalkylene oxide compound having a weight-average molar mass M w of at least 4,000 g/mol.

15. A method for treating substrates, comprising the following method steps
(a) providing an aqueous liquor by mixing from 0.5 L to 40.0 L of water with from 0.5 to 100 g of a composition according to claim 1 , and
(b) bringing a substrate into contact with the aqueous liquor prepared according to (a).

16. The composition according to claim 2 , wherein the surfactant composition has a storage modulus of between 10 4 Pa and 10 8 Pa.

17. The composition according to claim 2 , wherein the storage modulus of the surfactant composition is at least five times as great as the loss modulus.

18. The composition according to claim 2 , wherein the storage modulus of the surfactant composition is at least ten times as great as the loss modulus.

19. The composition according to claim 5 , wherein R′ and R″ together contain 9 to 15 C atoms.

20. The composition according to claim 5 , wherein R′ and R″ together contain 9 to 13 C atoms.

Assignees

• Henkel Ag & Co Kgaa

Inventors

• Schmiedel Peter
• Yapici Filiz
• Klemmer Anna
• Sunder Matthias
• Kurth Oliver

Classifications

• C11D17/0008

  aqueous liquid non soap compositions (C11D3/0015, C11D3/3947, C11D3/3956 take precedence) · CPC title

• C11D3/2068 Primary

  Ethers · CPC title

• C11D3/24

  containing halogen {(C11D3/162, C11D3/164, C11D3/166, C11D3/168 take precedence)} · CPC title

• C11D3/2096 Primary

  Heterocyclic compounds · CPC title

• C11D1/28

  Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides · CPC title