Silicon-containing oxide-coated aluminum nitride particle and method of manufacturing the same

Patent metadata

Field	Value
Publication number	US-11396602-B2
Application number	US-201917270202-A
Country	US
Kind code	B2
Filing date	Aug 23, 2019
Priority date	Aug 24, 2018
Publication date	Jul 26, 2022
Grant date	Jul 26, 2022

Abstract

A method of manufacturing a silicon-containing oxide-coated aluminum nitride particle; a method of manufacturing a heat dispersing resin composition containing the silicon-containing oxide-coated aluminum nitride particle; and the silicon-containing oxide-coated aluminum nitride particle. The method of manufacturing includes: a first step of covering the surface of the aluminum nitride particle with an organic silicone compound including a specific structure; and a second step of heating the aluminum nitride particle covered with the organic silicone compound at a temperature of 300° C. or more and less than 1000° C., wherein the content of carbon atoms in the silicon-containing oxide-coated aluminum nitride particle is less than 1000 ppm by mass.

First claim

The invention claimed is:

1. A method of manufacturing a silicon-containing oxide-coated aluminum nitride particle including an aluminum nitride particle and a silicon-containing oxide coating covering the surface of the aluminum nitride particle, the method comprising:
a first step of covering the surface of the aluminum nitride particle with an organic silicone compound including a structure represented by the following formula (1):

wherein in the formula (1), R is an alkyl group having a carbon number of 4 or less; and
a second step of heating the aluminum nitride particle covered with the organic silicone compound at a temperature of 300° C. or more and less than 1000° C.,
wherein the content of carbon atoms in the silicon-containing oxide-coated aluminum nitride particle is less than 1000 ppm by mass, and
wherein a coating amount of the organic silicone compound in the first step is 0.1 mg or more and 1.0 mg or less per m 2 of surface area calculated from the specific surface area (m 2 /g) of the aluminum nitride particle as determined by a BET method.

2. The method of manufacturing a silicon-containing oxide-coated aluminum nitride particle according to claim 1 , wherein the temperature of heating in the second step is 300° C. or more and 800° C. or less, and
the silicon-containing oxide coating is a silica coating, and the silicon-containing oxide-coated aluminum nitride particle is a silica-coated aluminum nitride particle.

3. The method of manufacturing a silicon-containing oxide-coated aluminum nitride particle according to claim 1 , wherein the first step is performed by a dry mixing method or a gas phase adsorption method.

4. The method of manufacturing a silicon-containing oxide-coated aluminum nitride particle according to claim 1 , wherein the first step is performed under an atmosphere including no oxygen gas.

5. The method of manufacturing a silicon-containing oxide-coated aluminum nitride particle according to claim 1 , wherein the organic silicone compound including a structure represented by the formula (1) includes at least one of a compound represented by the following formula (2) and a compound represented by the following formula (3):

wherein in the formula (2), R1 and R2 are each independently a hydrogen atom or a methyl group, and at least one of R1 and R2 is a hydrogen atom, and m is an integer of 0 to 10;

wherein in the formula (3), n is an integer of 3 to 6.

6. The method of manufacturing a silicon-containing oxide-coated aluminum nitride particle according to claim 1 , wherein the first step is performed under a temperature condition of 10° C. or more and 200° C. or less.

7. A method of manufacturing a heat dispersing resin composition, the method comprising a mixing step of mixing silicon-containing oxide-coated aluminum nitride particles manufactured by the method of manufacturing a silicon-containing oxide-coated aluminum nitride particle according to claim 1 with a resin.

Assignees

• Showa Denko Kk

Inventors

• Otsuka Yuki
• Okamoto Hidetoshi
• Minorikawa Naoki

Classifications

• C08K2003/282

  Binary compounds of nitrogen with aluminium · CPC title

• C08K9/10 Primary

  Encapsulated ingredients · CPC title

• C08K3/36

  Silica · CPC title

• C08K3/28 Primary

  Nitrogen-containing compounds · CPC title

• C08J2363/00

  Characterised by the use of epoxy resins; Derivatives of epoxy resins · CPC title