Tungsten carbide powder and production method therefor

Patent metadata

Field	Value
Publication number	US-11396451-B2
Application number	US-202017601431-A
Country	US
Kind code	B2
Filing date	Apr 21, 2020
Priority date	May 13, 2019
Publication date	Jul 26, 2022
Grant date	Jul 26, 2022

Abstract

A tungsten carbide powder contains tungsten carbide as a main component and chromium, in which, when mass concentrations of tungsten and chromium are measured at 100 or more analysis points randomly selected from a field of view of SEM observation of the tungsten carbide powder, a standard deviation σ of distribution of the ratio by percentage of the concentration of chromium to the total concentration of tungsten and chromium is 0.5 or less.

First claim

The invention claimed is:

1. A tungsten carbide powder comprising tungsten carbide as a main component and chromium,
wherein, when mass concentrations of tungsten and chromium are measured at 100 or more analysis points randomly selected from a field of view of SEM observation of the tungsten carbide powder, a standard deviation a of distribution of the ratio by percentage of the concentration of chromium to the total concentration of tungsten and chromium is 0.5 or less.

2. The tungsten carbide powder according to claim 1 , wherein the ratio of the concentration of chromium to the total concentration of tungsten and chromium contained in the entire tungsten carbide powder is 0.1% by mass or more and 7.0% by mass or less.

3. The tungsten carbide powder according to claim 1 , wherein the tungsten carbide powder has an average particle size of 1.0 μm or less.

4. A method for producing a tungsten carbide powder comprising:
a step of obtaining a mixed dry powder by mixing a tungsten oxide and a chromium-containing solution, followed by drying under stirring;
a step of obtaining a calcined powder by calcining the dry powder in the air atmosphere;
a step of obtaining a mixed powder by mixing the calcined powder and a carbon source powder; and
a step of obtaining a tungsten carbide powder by reducing the mixed powder by heat treatment in a hydrogen gas-containing atmosphere and carburizing the mixed powder at a temperature of 1,000° C. or higher.

Assignees

• Sumitomo Electric Industries

Inventors

• Michiuchi Masato
• Onoki Takamasa
• Okamura Katsumi
• Fudo Takayuki
• Hayashi Takehiko

Classifications

• C04B2235/96

  Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance · CPC title

• C04B2235/785

  Submicron sized grains, i.e. from 0,1 to 1 micron · CPC title

• C04B2235/77

  Density · CPC title

• C04B2235/3241

  Chromium oxides, chromates, or oxide-forming salts thereof · CPC title

• C04B35/62695

  Granulation or pelletising (devices for shaping artificial aggregates from ceramic mixtures B28B1/004) · CPC title