Surfacing and/or joining method

Patent metadata

Field	Value
Publication number	US-11384266-B2
Application number	US-201514875133-A
Country	US
Kind code	B2
Filing date	Oct 5, 2015
Priority date	Feb 17, 2005
Publication date	Jul 12, 2022
Grant date	Jul 12, 2022

Abstract

A method for surfacing a polymeric composite article and/or for joining (for example, by bonding or by co-curing) the article and an adherend (for example, a second polymeric composite article) comprises(a) providing a cured or curable polymeric composite article;(b) providing a curable composition comprising(1) at least one thermosetting resin, and(2) at least one preformed, substantially non-functional, particulate modifier comprising at least one elastomer;and(c) directly or indirectly applying the composition to at least a portion of at least one surface of the article.

First claim

We claim:

1. A method comprising
(a) providing a first cured polymeric composite article;
wherein the first cured polymeric composite article comprises continuous reinforcing fibers in the form of a unidirectional array of individual continuous fibers, a woven fabric, a knitted fabric, a yarn, a roving, or a braided construction;
(b) providing a curable composition on a liner, wherein the curable composition comprises
(1) at least one thermosetting resin, and
(2) at least one preformed, substantially non-functional, particulate core-shell polymer modifier comprising at least one elastomer;

wherein the curable composition contains no liquid butadiene/nitrile rubber polymer;
wherein the curable composition is a solid adhesive film;
wherein the particulate core-shell polymer modifier has a crosslinked poly(butadiene/styrene) core with a poly(methyl methacrylate) shell;
(c) removing the liner from the curable composition,
(d) directly or indirectly applying said composition as a solid film to at least a portion of at least one surface of said first cured polymeric composite article, and
(e) joining the first cured polymeric composite article to an adherend by means of the curable composition;
wherein at least one of the first cured polymeric composite article or the adherend is wet,
wherein the curable composition comprises:
bisphenol A-based polyepoxide,
a polysulfone thermoplastic polymer flow modifier or an aramid fiber flow modifier,
dicyandiamide (1-cyanoguanidine),
a dicyclopentadiene-based polyepoxide, and
isophthaloyldihydrazide.

2. The method of claim 1 , wherein said modifier is in the form of microparticles.

3. The method of claim 1 , wherein said modifier is included in said curable composition in a concentration of about 2 to about 30 weight percent, based upon the total weight of said curable composition.

4. The method of claim 1 , wherein the step of joining the first cured polymeric composite article to the adherend comprises bringing at least a portion of at least one surface of the article and a surface of the adherend into contact with said composition in a manner such that said composition becomes sandwiched between said article and said adherend.

5. The method of claim 4 , wherein said adherend comprises at least one of a polymeric composite article, a protective article, a paint replacement system, and a lightning protection system.

6. The method of claim 5 , wherein said paint replacement system comprises a paint replacement applique and said lightning protection system comprises a lightning protection applique.

7. The method of claim 1 , wherein said method further comprises at least partially curing the composition.

8. The method of claim 1 , wherein said film comprises an embedded scrim.

9. The method of claim 1 , wherein the curable composition comprises polysulfone resin flow modifier.

10. The method of claim 1 , wherein the curable composition comprises aramid fiber flow modifier.

Assignees

• 3M Innovative Properties Co

Inventors

• Salnikov Dmitriy
• George Clayton A

Classifications

• Y10T428/31721

  Of polyimide · CPC title

• Y10T428/31511

  Of epoxy ether · CPC title

• C09J121/00

  Adhesives based on unspecified rubbers · CPC title

• C09J163/00 Primary

  Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins · CPC title

• C08J7/043

  Improving the adhesiveness of the coatings per se, e.g. forming primers (adhesives in the form of films or foils characterised by the primer layers between the polymer carriers and the adhesives C09J7/50) · CPC title