Adduct of an amine and a cyclic siloxane compound

Patent metadata

Field	Value
Publication number	US-2017145149-A1
Application number	US-201615348151-A
Country	US
Kind code	A1
Filing date	Nov 10, 2016
Priority date	Nov 19, 2015
Publication date	May 25, 2017
Grant date	—

Abstract

A composition comprises an adduct produced by reacting an amine compound and a cyclic siloxane compound. The amine compound comprises two or more amine groups independently selected from the group consisting of primary amine groups and secondary amine groups. The cyclic siloxane compound comprises two or more first siloxane moieties that contain cyclic ether moieties. An epoxy composition is made by reacting an epoxy resin and the composition comprising the adduct.

First claim

What is claimed is:

1 . A composition comprising an adduct produced by reacting an amine compound and a cyclic siloxane compound, wherein (a) the amine compound comprises two or more amine groups independently selected from the group consisting of primary amine groups and secondary amine groups and (b) the cyclic siloxane compound comprises two or more first siloxane moieties, the first siloxane moieties being independently selected from the group consisting of moieties conforming to the structure of Formula (I)

where R 1 is selected from the group consisting of alkyl groups, substituted alkyl groups, cycloalkyl groups, substituted cycloalkyl groups, alkenyl groups, substituted alkenyl groups, cycloalkenyl groups, substituted cycloalkenyl groups, heterocyclyl groups, substituted heterocyclyl groups, aryl groups, substituted aryl groups, heteroaryl groups, and substituted heteroaryl groups, and R 2 is a group comprising a cyclic ether moiety.

2 . The composition of claim 1 , wherein R 2 comprises an epoxide moiety.

3 . The composition of claim 2 , wherein R 2 is selected from the group consisting of 5,6-epoxyhexyl and 2-(3,4-epoxycyclohexyl)ethyl.

4 . The composition of claim 2 , wherein R 2 is a group conforming to the structure —R 5 —O—R 6 , where R 5 is an alkanediyl group and R 6 is a group comprising an epoxide moiety.

5 . The composition of claim 4 , wherein R 5 is a propane-1,3-diyl group, and R 6 is a glycidyl group.

6 . The composition of claim 1 , wherein R 1 is selected from the group consisting of alkyl groups.

7 . The composition of claim 6 , wherein R 1 is a methyl group.

8 . The composition of claim 1 , wherein the cyclic siloxane compound comprises one or more second siloxane moieties, the second siloxane moieties being independently selected from the group consisting of moieties of Formula (X)

where R 10 is selected from the group consisting of alkyl groups, substituted alkyl groups, cycloalkyl groups, substituted cycloalkyl groups, alkenyl groups, substituted alkenyl groups, cycloalkenyl groups, substituted cycloalkenyl groups, heterocyclyl groups, substituted heterocyclyl groups, aryl groups, substituted aryl groups, heteroaryl groups, and substituted heteroaryl groups; R 11 is selected from the group consisting of alkanediyl groups and alkenediyl groups; and R 12 is selected from the group consisting of aryl groups, substituted aryl groups, heteroaryl groups, and substituted heteroaryl groups.

9 . The composition of claim 8 , wherein R 10 is an alkyl group, R 11 is an alkanediyl group, and R 12 is an aryl group.

10 . The composition of claim 9 , wherein R 10 is a methyl group, R 11 is a 2-methylethane-1,2-diyl group, and R 12 is a phenyl group.

11 . The composition of claim 8 , wherein the cyclic siloxane compound comprises two or more second siloxane moieties.

12 . The composition of claim 1 , wherein the cyclic siloxane compound comprises four to eight siloxane moieties.

13 . An epoxy composition produced by reacting an epoxy resin and the composition of claim 1 .

Assignees

• Milliken & Co

Inventors

• Christiano Steven P
• Hoy Olha V
• Hanssen Robbie W J M

Classifications

• C07F7/21 Primary

  Cyclic compounds having at least one ring containing silicon, but no carbon in the ring · CPC title

• C08G59/1477 Primary

  containing nitrogen · CPC title

• C07C211/36

  containing at least two amino groups bound to the carbon skeleton · CPC title

• C08G77/388

  containing nitrogen · CPC title

• C08L83/08

  containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen · CPC title