Mixing and heat integration of melt tray liquids in a cryogenic distillation tower

Patent metadata

Field	Value
Publication number	US-11378332-B2
Application number	US-201916440030-A
Country	US
Kind code	B2
Filing date	Jun 13, 2019
Priority date	Jun 29, 2018
Publication date	Jul 5, 2022
Grant date	Jul 5, 2022

Abstract

A cryogenic distillation tower for separating a feed stream. The tower includes a distillation section. A controlled freeze zone section is situated above the distillation section and forms a solid from the feed stream. The controlled freeze zone section includes a spray assembly in an upper section and a melt tray assembly in a lower section. The melt tray assembly includes at least one vapor stream riser that directs the vapor from the distillation section into liquid retained by the melt tray assembly, and one or more draw-off openings positioned to permit a portion of the liquid to exit the controlled freeze zone section. The portion of the liquid indirectly exchanges heat with a heating fluid. One or more return inlets return the portion of the liquid to the melt tray assembly after it has been heated in the heat exchanger.

First claim

What is claimed is:

1. A cryogenic distillation tower for separating a feed stream, the distillation tower comprising:
a distillation section permitting vapor to rise upwardly therefrom;
one or more lines for directing the feed stream into the distillation tower;
a controlled freeze zone section situated above the distillation section, the controlled freeze zone constructed and arranged to form a solid from the feed stream, the controlled freeze zone section including
a spray assembly in an upper section of the controlled freeze zone, and
a melt tray assembly in a lower section of the controlled freeze zone, wherein the melt tray assembly includes
at least one vapor stream riser that directs the vapor from the distillation section into liquid retained by the melt tray assembly, and
one or more draw-off openings positioned to permit a portion of the liquid retained by the melt tray assembly to exit the controlled freeze zone section;

a heat exchanger arranged to heat the portion of the liquid through indirect heat exchange with a heating fluid; and
one or more return inlets that return the portion of the liquid to the melt tray assembly after the portion of the liquid has been heated in the heat exchanger.

2. The cryogenic distillation tower of claim 1 , wherein the heating fluid is the feed stream prior to the feed stream being directed into the distillation tower.

3. The cryogenic distillation tower of claim 2 , further comprising a bypass line configured to selectively permit the feed stream to bypass the heat exchanger.

4. The cryogenic distillation tower of claim 1 , wherein the heat exchanger is a first heat exchanger and the heating fluid is a first heating fluid, and further comprising a second heat exchanger arranged to heat the portion of the liquid through indirect heat exchange with a second heating fluid.

5. The cryogenic distillation tower of claim 4 , wherein the second heating fluid comprises one or more of ethane and propane.

6. The cryogenic distillation tower of claim 1 , further comprising a pump for pumping the portion of the liquid exiting the one or more draw-off openings.

7. The cryogenic distillation tower of claim 1 , wherein the one or more return inlets comprise two or more return inlets that are evenly distributed about a perimeter of the cryogenic distillation tower.

8. The cryogenic distillation tower of claim 1 , wherein the melt tray assembly includes a heating element to heat the liquid retained in the melt tray assembly.

9. A method of cryogenically separating contaminants from a feed stream in a distillation tower, the method comprising:
directing the feed stream into the distillation tower;
permitting vapor to rise upwardly from a distillation section of the distillation tower;
forming a solid in a controlled freeze zone section of the distillation tower, the controlled freeze zone section being situated above the distillation section, wherein the solid comprises contaminants in the feed stream;
directing the vapor from the distillation section into liquid retained by a melt tray assembly using at least one vapor stream riser;
melting the solid using the liquid retained by the melt tray assembly;
permitting a portion of the liquid retained by the melt tray assembly to exit the controlled freeze zone section;
heating the portion of the liquid through indirect heat exchange with a heating fluid in a heat exchanger; and
returning the portion of the liquid to the melt tray assembly after the liquid has been heated in the heat exchanger.

10. The method of claim 9 , wherein the heating fluid is the feed stream prior to the feed stream being directed into the distillation tower.

11. The method of claim 10 , further comprising: selectively permitting the feed stream to bypass the heat exchanger.

12. The method of claim 9 , wherein the heat exchanger is a first heat exchanger and the heating fluid is a first heating fluid, and further comprising:
heating the portion of the liquid through indirect heat exchange with a second heating fluid in a second heat exchanger.

13. The method of claim 12 , wherein the second heating fluid comprises one or more of ethane and propane.

14. The method of claim 9 , further comprising:
pumping the portion of the liquid exiting the one or more draw-off openings.

15. The method of claim 9 , wherein the one or more return inlets comprise two or more return inlets that are evenly distributed about a perimeter of the tower.

16. The method of claim 9 , further comprising: heating the liquid retained in the melt tray assembly using a heating element.

17. The method of claim 9 , wherein the feed gas comprises less than 30 mol % carbon dioxide.

18. The method of claim 9 , wherein the solid comprises carbon dioxide.

Assignees

• Exxonmobil Upstream Res Co

Inventors

• Valencia Jaime A
• Mart Charles J
• Smith Ransdall K
• Maher David W

Classifications

• F25J3/0266

  separation of carbon dioxide (production of carbon dioxide in general C01B32/00) · CPC title

• F25J2280/40

  Control of freezing of components · CPC title

• F25J2205/20

  using solidification of components · CPC title

• B01D3/20

  Bubble caps; Risers for vapour; Discharge pipes for liquid · CPC title

• C10G2300/207

  Acid gases, e.g. H2S, COS, SO2, HCN · CPC title