Method and system for separating fluids in a distillation tower

Patent metadata

Field	Value
Publication number	US-9739529-B2
Application number	US-201514700993-A
Country	US
Kind code	B2
Filing date	Apr 30, 2015
Priority date	Jul 8, 2014
Publication date	Aug 22, 2017
Grant date	Aug 22, 2017

Abstract

A method and system for separating fluids in a distillation tower. The method may include feeding a stream to the distillation tower, wherein the stream includes carbon dioxide, reducing a carbon dioxide concentration of the stream received by the rectifier section by feeding a first cryogenic fluid to the controlled freeze zone section and accumulating rectifier section stream in at least one of a holding vessel and a sump of the rectifier section, and terminating reducing the carbon dioxide concentration when the carbon dioxide concentration of the stream travelling from the controlled freeze zone section to the rectifier section is less than or equal to a maximum carbon dioxide concentration. The first cryogenic fluid may comprise a substantially carbon-dioxide-free fluid.

First claim

What is claimed is:

1. A method for separating fluids in a distillation tower, the method comprising:
providing a distillation tower comprising a controlled freeze zone section and a rectifier section, wherein the controlled freeze zone section and rectifier section are configured such that a vapor stream rises up from the controlled freeze zone section to the rectifier section;
maintaining the rectifier section in the distillation tower;
maintaining the controlled freeze zone section in the distillation tower, wherein the controlled freeze zone section forms solids from carbon dioxide within the distillation tower;
feeding a stream to the distillation tower, wherein the stream comprises the carbon dioxide;
reducing a carbon dioxide concentration of the vapor stream received by the rectifier section by:
feeding a first cryogenic fluid to the controlled freeze zone section, wherein the first cryogenic fluid comprises a substantially carbon-dioxide-free fluid; and
accumulating a rectifier section stream in at least one of a holding vessel and a sump of the rectifier section; and

terminating reducing the carbon dioxide concentration when the carbon dioxide concentration of the vapor stream travelling from the controlled freeze zone section to the rectifier section is less than or equal to a maximum carbon dioxide concentration.

2. The method of claim 1 , wherein feeding the first cryogenic fluid comprises feeding the first cryogenic fluid from a cryogenic fluid storage container to a cryogenic fluid pump, then feeding the first cryogenic fluid from the cryogenic fluid pump to a cryogenic heat exchanger, and then feeding the first cryogenic fluid from the cryogenic heat exchanger to the controlled freeze zone section.

3. The method of claim 2 , wherein feeding the first cryogenic fluid from the cryogenic heat exchanger to the controlled freeze zone section comprises spraying the first cryogenic fluid into the controlled freeze zone section.

4. The method of claim 3 , wherein spraying the first cryogenic fluid comprises spraying the first cryogenic fluid via a controlled freeze zone section spray assembly of the controlled freeze zone section.

5. The method of claim 4 , wherein the first cryogenic fluid comprises liquid natural gas.

6. The method of claim 3 , wherein spraying the first cryogenic fluid comprises spraying the first cryogenic fluid via a cryogenic fluid spray assembly of the controlled freeze zone section and spraying a liquid stream from the rectifier section via a controlled freeze zone section spray assembly of the controlled freeze zone section.

7. The method of claim 6 , wherein the first cryogenic fluid comprises liquid nitrogen.

8. The method of claim 1 , wherein the maximum carbon dioxide concentration within the vapor stream comprises less than or equal to 6 percent of the stream.

9. The method of claim 1 , further comprising directly feeding a rectifier section cryogenic fluid to the rectifier section.

10. The method of claim 9 , wherein the first cryogenic fluid comprises a same cryogenic fluid as the rectifier section cryogenic fluid.

11. The method of claim 9 , wherein the rectifier section cryogenic fluid comprises a substantially carbon dioxide free fluid.

12. The method of claim 9 , wherein feeding the rectifier section cryogenic fluid comprises feeding the rectifier section cryogenic fluid from a cryogenic fluid storage container to a rectifier section cryogenic fluid pump, then feeding the rectifier section cryogenic fluid from the rectifier section cryogenic fluid pump to a rectifier section cryogenic heat exchanger and then feeding the rectifier section cryogenic fluid from the rectifier section cryogenic heat exchanger to the rectifier section.

13. The method of claim 1 , further comprising feeding the rectifier section stream to a controlled freeze zone section spray assembly of the controlled freeze zone section when the carbon dioxide concentration travelling from the controlled freeze zone section to the rectifier section is less than or equal to the maximum carbon dioxide concentration.

14. The method of claim 6 , further comprising reducing the carbon dioxide concentration of the stream received by the rectifier section by feeding a second cryogenic fluid to the controlled freeze zone section, wherein the second cryogenic fluid comprises a substantially carbon dioxide free fluid.

15. The method of claim 14 , wherein feeding the second cryogenic fluid comprises feeding the second cryogenic fluid to a second cryogenic fluid pump, then feeding the second cryogenic fluid from the second cryogenic fluid pump to the controlled freeze zone section.

16. The method of claim 15 , wherein feeding the second cryogenic fluid from the second cryogenic fluid pump to the controlled freeze zone section comprises spraying the second cryogenic fluid into the controlled freeze zone section.

17. The method of claim 14 , wherein feeding the second cryogenic fluid comprises feeding the second cryogenic fluid to a second cryogenic fluid pump, then feeding the second cryogenic fluid from the second cryogenic fluid pump to a second cryogenic heat exchanger, and then feeding the second cryogenic fluid from the second cryogenic heat exchanger to the controlled freeze zone section.

18. The method of claim 17 , wherein feeding the second cryogenic fluid from the second cryogenic heat exchanger to the controlled freeze zone section comprises spraying the second cryogenic fluid into the controlled freeze zone section.

19. The method of claim 16 , wherein spraying the second cryogenic fluid comprises spraying the second cryogenic fluid via the controlled freeze zone section spray assembly.

20. The method of claim 14 , wherein the second cryogenic fluid comprise liquid natural gas.

21. The method of claim 1 , further comprising feeding a rectifier section stream portion of the rectifier section stream to a cryogenic fluid storage container.

22. The method of claim 21 , wherein the rectifier section stream portion comprises at least one of the first cryogenic fluid, a second cryogenic fluid, a rectifier section cryogenic fluid and the solids.

23. The method of claim 22 , further comprising separating the at least one of the first cryogenic fluid, the rectifier section cryogenic fluid and the second cryogenic fluid in the rectifier section stream portion from the solids in the rectifier section stream portion.

24. The method of claim 23 , further comprising feeding the at least one of the first cryogenic fluid, the rectifier section cryogenic fluid and the second cryogenic fluid to at least one of a cryogenic fluid storage container and a sales pipeline.

25. The method of claim 23 , further comprising collecting the solids at a cryogenic fluid storage container bottom of the cryogenic fluid storage container.

Assignees

• Northrop P Scott
• Valencia Jaime A
• Exxonmobil Upstream Res Co

Inventors

• Northrop P Scott
• Valencia Jaime A

Classifications

• F25J2200/02

  in a single pressure main column system · CPC title

• F25J3/0295

  Start-up or control of the process; Details of the apparatus used, e.g. sieve plates, packings · CPC title

• Y02C10/12

  Cross-Sectional Technologies · mapped topic

• F25J2200/30

  using a side column in a single pressure column system · CPC title

• F25J2210/62

  Liquefied natural gas [LNG]; Natural gas liquids [NGL]; Liquefied petroleum gas [LPG] · CPC title