Method for operating an iron- or steelmaking- plant

Patent metadata

Field	Value
Publication number	US-11377700-B2
Application number	US-201816628171-A
Country	US
Kind code	B2
Filing date	Jul 2, 2018
Priority date	Jul 3, 2017
Publication date	Jul 5, 2022
Grant date	Jul 5, 2022

Abstract

A method of operating an ironmaking or steelmaking plant with low CO2-emissions is provided. Hydrogen and oxygen are generated by water decomposition and at least part of the generated hydrogen is injected as a reducing gas into one or more ironmaking furnaces with off-gas decarbonation and reinjection into the furnaces of at least a significant part of the decarbonated off-gas and at least part of the generated oxygen is injected as an oxidizing gas in the one or more ironmaking.

First claim

The invention claimed is:

1. A method of operating an ironmaking or steelmaking plant comprising an ironmaking furnace set comprising one or more furnaces in which iron ore is transformed into liquid hot metal by means of a process which includes iron ore reduction, melting and off-gas generation, the ironmaking or steelmaking plant, the method comprising the steps of:
a. charging the ironmaking furnace set with iron ore and coke,
b. injecting oxidizing gas into the ironmaking furnace set,
c. producing an off-gas and decarbonating the off-gas downstream of the ironmaking furnace set thereby obtaining a CO 2 -enriched tail gas stream and a decarbonated off-gas stream containing not more than 10% vol CO 2 ,
d. injecting at least 50% of the decarbonated off-gas stream back into the ironmaking furnace set as a reducing gas recycle stream,
e. generating hydrogen and oxygen by means of water decomposition,
f. injecting at least part of the hydrogen generated in step in step (e) combined with at least a part of the decarbonated off-gas into the ironmaking furnace set, and
g. injecting at least part of the generated oxygen into the ironmaking furnace set and/or a converter as oxidizing gas.

2. The method according to claim 1 , whereby at least part of the hydrogen generated in step (e) which is injected into the ironmaking furnace set is mixed with the reducing gas recycle stream before the gas mixture so obtained is injected into the ironmaking furnace set.

3. The method according to claim 1 , wherein:
h. the gas recycle stream or the mixture of hydrogen generated in step (e) with the gas recycle stream is heated upstream of the ironmaking furnace set to a temperature between 700° C. and 1300° C.

4. The method according to claim 3 , wherein:
i. a low-heating-value gaseous fuel having a heating value of from 2.8 to 7.0 MJ/Nm 3 is produced containing (i) at least a portion of the tail gas stream and (ii) a second part of the hydrogen generated in step (e), said low-heating-value gaseous fuel being used to heat hot stoves used for heating the gas recycle stream.

5. The method according to claim 1 , whereby a ratio between:
(i) the hydrogen generated in step (e) and injected into the ironmaking furnace set and
(ii) the oxygen generated in step (e) and injected into the ironmaking furnace set and/or the converter in step (g) is between 1.50 and 2.50.

6. The method according to claim 1 , whereby a ratio between:
(i) the hydrogen generated in step (e) and injected into the ironmaking furnace set and
(ii) the oxygen generated in step (e) and injected into the ironmaking furnace set in step (g) is between 1.75 and 2.25.

7. The method according to claim 1 , wherein pulverized coal and/or another organic combustible substance is injected into the blast furnace by means of tuyeres.

8. The method according to claim 1 , wherein all or part of the generated hydrogen which is injected into the ironmaking furnace set is injected into the ironmaking furnace set via tuyeres.

9. The method according to claim 1 , wherein all or part of the oxygen generated in step (e) is mixed with oxygen-containing gas not generated in step (e) so as to obtain a mixture which is injected as oxidizing gas into the ironmaking furnace set.

10. The method according to claim 1 , wherein the oxidizing gas which is injected into the ironmaking furnace set in step (b) consists of oxygen generated in step (e).

11. The method according to claim 1 , wherein in step (e), hydrogen and oxygen are generated by biological and/or electrolytic water decomposition.

12. The method of claim 11 , wherein in step (e), hydrogen and oxygen are generated by electrolytic water decomposition at a pressure above atmospheric pressure and/or at a temperature above ambient temperature.

13. The method according to claim 1 , wherein the reducing gas is injected into the ironmaking furnace set via tuyeres.

14. The method according to claim 1 , wherein the ironmaking furnace set comprises one or more blast furnaces.

15. The method according to claim 1 , wherein the hydrogen generated in step (e) consists of at least 70% vol of H 2 molecules.

Assignees

• Air Liquide

Inventors

• Blostein Philippe
• Grant Mike

Classifications

• C21B5/06 Primary

  using top gas in the blast furnace process · CPC title

• F27D7/02

  Supplying steam, vapour, gases or liquids · CPC title

• C21B2100/40

  Gas purification of exhaust gases to be recirculated or used in other metallurgical processes · CPC title

• F27B1/16

  Arrangements of tuyeres · CPC title

• F27B1/10

  Details, accessories or equipment specially adapted for furnaces of these types · CPC title