Nitrogen oxide storage catalyst

Patent metadata

Field	Value
Publication number	US-11376550-B2
Application number	US-201917271276-A
Country	US
Kind code	B2
Filing date	Aug 22, 2019
Priority date	Aug 28, 2018
Publication date	Jul 5, 2022
Grant date	Jul 5, 2022

Abstract

The present invention relates to a catalyst which comprises a carrier substrate of length L, which extends between a first end face a and a second end face b, and catalytically active material zones A, B and C of different composition, wherein—material zone A comprises palladium or palladium and platinum with a weight ratio of Pd:Pt>1, and cerium oxide, —material zone B comprises platinum or platinum and palladium with a weight ratio of Pt:Pd>1, and cerium oxide and/or cerium/zirconium mixed oxide, and—material zone C comprises platinum or platinum and palladium with a weight ratio of Pt:Pd>1, and a carrier oxide, and wherein—material zone B is arranged above material zone A, and—material zone C is arranged above material zone B, and, starting from the second end face b of the carrier substrate, extends over a length of up to 60% of the length L. The invention also relates to a catalyst arrangement containing said catalyst.

First claim

The invention claimed is:

1. Catalyst comprising a carrier substrate of length L which extends between a first end face a and a second end face b, and catalytically active material zones A, B, and C of different compositions, wherein
material zone A comprises palladium or palladium and platinum with a weight ratio of Pd:Pt>1, and cerium oxide,
material zone B comprises platinum or platinum and palladium with a weight ratio of Pt:Pd>1, and cerium oxide and/or cerium/zirconium mixed oxide and
material zone C comprises platinum or platinum and palladium with a weight ratio of Pt:Pd>1, and a carrier oxide, and
wherein
material zone B is arranged over material zone A and
material zone C is arranged over material zone B and extends starting from the second end face b of the carrier substrate over a length of 20 to 60% of the length L.

2. Catalyst according to claim 1 , characterized in that material zone A comprises palladium and no platinum.

3. Catalyst according to claim 1 , characterized in that material zone A comprises palladium and platinum with a weight ratio of Pd:Pt of 20:1 to 1.1:1.

4. Catalyst according to claim 1 , characterized in that material zone A contains an alkaline earth oxide.

5. Catalyst according to claim 4 , characterized in that the alkaline earth oxide is magnesium oxide, strontium oxide, and barium oxide.

6. Catalyst according to claim 1 , characterized in that material zone B comprises platinum and no palladium.

7. Catalyst according to claim 1 , characterized in that material zone B comprises platinum and palladium with a weight ratio of Pt:Pd of 20:1 to 1.1:1.

8. Catalyst according to claim 1 characterized in that material zone C comprises platinum and no palladium.

9. Catalyst according to claim 1 characterized in that material zone C comprises platinum and palladium with a weight ratio of Pt:Pd of 20:1 to 1.1:1.

10. Catalyst according to claim 1 , characterized in that both material zone A and material zone B extend between the end faces a and b over the entire length L of the support body.

11. Catalyst according to claim 1 , characterized in that the material zone A lies directly on the support body, material zone B directly on material zone A, and material zone C directly on material zone B.

12. Catalyst arrangement comprising
a) a catalyst which comprises a carrier substrate of length L which extends between a first end face a and a second end face b, and catalytically active material zones A, B, and C of different compositions, wherein
material zone A comprises palladium or palladium and platinum with a weight ratio of Pd:Pt>1, and cerium oxide,
material zone B comprises platinum or platinum and palladium with a weight ratio of Pt:Pd>1, and cerium oxide and/or cerium/zirconium mixed oxide and
material zone C comprises platinum or platinum and palladium with a weight ratio of Pt:Pd>1, and a carrier oxide, and
wherein
material zone B is arranged over material zone A and
material zone C is arranged over material zone B and extends starting from the second end face b of the carrier substrate over a length of 20 to 60% of the length L; and
b) an SCR catalyst.

13. Catalyst arrangement according to claim 12 , characterized in that the SCR catalyst is a zeolite belonging to structure type BEA, AEI, CHA, KFI, ERI, LEV, MER, or DDR and is exchanged with cobalt, iron, copper, or mixtures of two or three of these metals.

14. Catalyst arrangement according to claim 12 , characterized in that a first part of the SCR catalyst is present as a coating on a wall-flow filter and a second part as a coating on a flowthrough substrate.

15. Catalyst arrangement according to claim 12 further comprising an ammonia blocking catalyst which follows the SCR catalyst.

16. Method for purifying exhaust gases from motor vehicles that are operated using lean-burn engines, characterized in that the exhaust gas is conducted through a catalyst arrangement according to claim 15 , wherein the exhaust gas is guided in such a way that it first flows through the catalyst having material zones A, B and C, then through the SCR catalyst, and then through the ammonia blocking catalyst.

Assignees

• Umicore Ag & Co Kg

Inventors

• Woerz Anke
• Hoyer Ruediger
• Betz Benjamin

Classifications

• B01J35/40

  characterised by dimensions, e.g. grain size (in a colloidal state B01J35/23; crystallite size B01J35/77) · CPC title

• B01J21/04

  Alumina · CPC title

• B01J21/066

  Zirconium or hafnium; Oxides or hydroxides thereof · CPC title

• B01D2255/1021

  Platinum · CPC title

• B01D2255/91

  NOx-storage component incorporated in the catalyst · CPC title