Method of controlling kinematic viscosity of polyalphaolefin

Patent metadata

Field	Value
Publication number	US-11370987-B2
Application number	US-202117229088-A
Country	US
Kind code	B2
Filing date	Apr 13, 2021
Priority date	Apr 14, 2020
Publication date	Jun 28, 2022
Grant date	Jun 28, 2022

Abstract

The invention relates to a method of the oligomerization of C6 and above olefin monomer whereby, at a fixed monomer/Al halide mole ratio, polyalphaolefins having desirable kinematic viscosities are prepared by controlling the oligomerization temperature. The oligomerization is carried out in presence of an oligomerizing catalyst comprising of aluminum halide and a promoter, and oligomerizing temperatures of about 10° C. to about 120° C.

First claim

We claim:

1. A process for controlling kinematic viscosity of a polyalphaolefin in a range of 1-70 centistokes at 100° C., the process comprising:
oligomerizing C6 and above olefin monomers in presence of an aluminium halide, a promoter, and a solvent to obtain the polyalphaolefin; wherein the promoter is water, an alcohol, a ketone, an ether, or any combination thereof;
wherein the kinematic viscosity of the polyalphaolefin is controlled by adjusting oligomerization temperature at a fixed mole ratio of olefin monomer and the aluminium halide, and wherein the mole ratio of the olefin monomer to the aluminium halide is from 10 to 500.

2. The process as claimed in claim 1 , wherein the olefin monomer is selected from the group consisting of 1-decene, 1-dodecene, 1-octene and a mixture thereof.

3. The process as claimed in claim 1 , wherein a mole ratio of the aluminium halide to the promoter is from 1 to 10.

4. The process as claimed in claim 1 , wherein the promoter is iso-butyl alcohol.

5. The process as claimed in claim 1 , wherein the olefin monomers and the solvent have a moisture content less than 20 ppm.

6. The process as claimed in claim 1 , wherein an oligomerization temperature is in a range from 10° C. to 150° C.

7. The process as claimed in claim 1 , wherein the oligomerization temperature is in a range of 25° C. and 90° C.

8. The process as claimed in claim 1 , wherein a residence time during the oligomerization is in a range of 0.5 to 8 hours.

9. The process as claimed in claim 1 , wherein the solvent is selected from C5 to C19 paraffinic hydrocarbons.

10. The process as claimed in claim 1 , wherein a conversion from the monomer to the polyalphaolefin is in a range of 95% to 98%.

11. The process as claimed in claim 1 , wherein the oligomerizing C6 and above olefin monomers produces C20-24 dimers, C30-36 trimers, C40-48 tetramers, C50-60 pentamers, and C60+ heavies.

Assignees

• Indian Oil Corp Ltd

Inventors

• Kaur Sukhdeep
• Sahoo Usharani
• Singh Gurmeet
• Pappu Naresh
• Pandey Jai Narayan
• Kumhar Shobhashankar
• Kapur Gurpreet Singh
• Saxena Deepak
• RAMAKUMAR Sankara Sri Venkata

Classifications

• C10M107/10 Primary

  containing aliphatic monomer having more than 4 carbon atoms · CPC title

• C07C2/22

  Metal halides; Complexes thereof with organic compounds · CPC title

• C07C2/06

  of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond · CPC title

• C10N2020/02

  Viscosity; Viscosity index · CPC title

• C10M2205/0285

  used as base material · CPC title