Method of producing liquid fuel from carbonaceous feedstock through gasification and recycling of downstream products

Patent metadata

Field	Value
Publication number	US-11370982-B2
Application number	US-201916512750-A
Country	US
Kind code	B2
Filing date	Jul 16, 2019
Priority date	Aug 30, 2016
Publication date	Jun 28, 2022
Grant date	Jun 28, 2022

Abstract

A feedstock delivery system transfers a carbonaceous material, such as municipal solid waste, into a product gas generation system. The feedstock delivery system includes a splitter for splitting bulk carbonaceous material into a plurality of carbonaceous material streams. Each stream is processed using a weighing system for gauging the quantity of carbonaceous material, a densification system for forming plugs of carbonaceous material, a de-densification system for breaking up the plugs of carbonaceous material, and a gas and carbonaceous material mixing system for forming a carbonaceous material and gas mixture. A pressure of the mixing gas is reduced prior to mixing with the carbonaceous material, and the carbonaceous material to gas weight ratio is monitored. A transport assembly conveys the carbonaceous material and gas mixture to a first reactor where at least the carbonaceous material within the mixture is subject to thermochemical reactions to form the product gas.

First claim

What is claimed is:

1. A method of producing jet fuel and/or diesel fuel from carbonaceous material, the method comprising:
(a) providing a source of carbonaceous material;
(b) after step (a), introducing the carbonaceous material into a fluidized bed reactor having particulate heat transfer material therein;
(c) after step (b), reacting the carbonaceous material with steam in the presence of said particulate heat transfer material, in an endothermic reaction to produce a product gas which includes at least some carbon dioxide,
(d1) after step (c), removing a mixture of solids including particulate heat transfer material from the fluidized bed reactor into a classifier, introducing a classifier gas to separate the particulate heat transfer material from a remainder of said solids, recycling the separated particulate heat transfer material to produce additional product gas, and discarding the remainder of said solids;
(d2) also after step (c), cooling the product gas in a heat exchanger;
(e) after step (d2), scrubbing the product gas in a scrubber;
(f) after step (e), compressing the product gas;
(g) after step (f), removing carbon dioxide from the product gas, and recycling at least a portion of the removed carbon dioxide for use as the classifier gas in step (d1);
(h) after step (g), reacting the product gas with a catalyst to produce one or more Fischer Tropsch products including tail gas;
(i) after step (h), upgrading the one or more Fischer Tropsch products to produce said jet fuel and/or diesel fuel plus naphtha; and
recycling at least a portion of the tail gas produced in step (h) as a fuel source to create heat for the endothermic reaction in step (c), and/or recycling at least a portion of the naphtha produced in step (i) as a fuel source to create heat for the endothermic reaction in step (c).

2. The method according to claim 1 , comprising:
recycling both tail gas produced in step (h) and naphtha produced in step (i), as fuel sources to create heat for the endothermic reaction in step (c).

3. The method according to claim 1 , comprising:
in step (c), reacting the carbonaceous material with both steam and carbon dioxide, to produce the product gas;
reducing a pressure of the at least a portion of the carbon dioxide removed in step (g) to form a reduced-pressure carbon dioxide; and
mixing the reduced-pressure carbon dioxide with the carbonaceous material at a carbonaceous material to carbon dioxide weight ratio that is less than about 50:1, prior to reacting in step (c).

4. The method according to claim 3 , comprising:
in step (c), reacting the steam with the carbonaceous material in the presence of the carbon dioxide at a carbon dioxide to carbonaceous material weight ratio ranging from greater than 0:1 to less than 1:1.

5. The method according to claim 3 , comprising:
in step (c), providing indirect heat for the endothermic reaction by heating the particulate heat transfer material, the carbonaceous material, steam, and carbon dioxide with a heat exchanger.

6. The method according to claim 5 , comprising:
combusting a fuel source in the heat exchanger to thereby indirectly heat the particulate heat transfer material, the carbonaceous material, steam and carbon dioxide.

7. The method according to claim 6 , wherein:
the fuel source includes natural gas.

8. The method according to claim 6 , wherein:
the fuel source includes syngas.

9. The method according to claim 1 , comprising:
introducing at least a portion of the tail gas produced in step (h) along with an oxygen-containing gas, into at least one heat exchanger;
combusting the tail gas and the oxygen-containing gas within the heat exchanger to form a combustion stream; and
indirectly transferring heat from the combustion stream to the reactants in step (c) to effectuate said endothermic thermochemical reaction.

10. The method according to claim 1 , comprising:
introducing at least a portion of the naphtha produced in step (i) along with an oxygen-containing gas, into at least one heat exchanger;
combusting the naphtha and the oxygen-containing gas within the heat exchanger to form a combustion stream; and
indirectly transferring heat from the combustion stream to the reactants in step (c) to effectuate said endothermic thermochemical reaction.

11. The method according to claim 1 , comprising:
in step (c), reacting the steam with the carbonaceous material at a steam to carbonaceous material weight ratio in the range of about 0.125:1 to about 3:1.

12. The method according to claim 1 , comprising:
in step (c), reacting the steam with the carbonaceous material in the presence of an oxygen-containing gas at an oxygen-containing gas to carbonaceous material weight ratio in the range of greater than 0:1 to less than 0.5:1.

13. The method according to claim 1 , comprising:
in step (c), reacting the steam with the carbonaceous material at a velocity range between 0.6 ft/s to about 1.2 ft/s to produce the product gas.

14. The method according to claim 1 , comprising:
in step (c), converting carbon in the carbonaceous material at a carbon conversion rate between 50% to 99%, when reacting the steam with the carbonaceous material to produce the product gas.

15. The method according to claim 1 , comprising:
in step (c), reacting the steam with between 104 tons per day to 625 tons per day of carbonaceous material.

16. The method according to claim 15 , comprising:
in step (b), introducing the carbonaceous material into the fluidized bed reactor via a plurality of streams of carbonaceous material and gas mixture.

17. The method according to claim 1 , wherein:
the product gas produced in step (c) includes one or more from the group consisting of benzene, toluene, phenol, styrene, xylene and cresol; and
the method comprises:
in step (e), scrubbing the product gas to remove at least one from the group consisting of benzene, toluene, phenol, styrene, xylene and cresol.

18. The method according to claim 1 , comprising:
mixing at least a portion of the carbon dioxide removed in step (g) with the carbonaceous material, after step (a) and before step (b).

19. The method according to claim 1 , comprising:
after step (a) and before step (b), densifying the carbonaceous material; and then
shredding the carbonaceous material, prior to introducing the carbonaceous material into the fluidized bed reactor.

20. The method according to claim 19 , comprising:
removing dust and/or airborne particle solids from the carbonaceous material, prior to introducing the carbonaceous material to the fluidized bed reactor.

21. The method according to claim 1 , comprising:
after step (a) and before step (b), analyzing the carbonaceous material to obtain an energy content of the carbonaceous material.

22. The method according to claim 21 , comprising:
analyzing the carbonaceous material while the carbonaceous material is on a conveyor belt and/or in a screw conveyor.

23. The method according to claim 1 , comprising:
after step (a) and before step (b), analyzing the carbonaceous material with Raman spectroscopy.

24. The method according to claim 1 , comprising:
after step (a) and before step (b), analyzing the carbonaceous material using Near Infrared (NIR) technology.

25. The method according to claim 1 , comprising:
after step (a) and before step (b), analyzing an ultimate analysis and/or a proximate analysis of the

Assignees

• Thermochem Recovery Int Inc

Inventors

• Chandran Ravi
• Burciaga Daniel A
• Leo Daniel Michael
• Freitas Shawn Robert
• Newport Dave G
• Miller Justin Kevin
• Harrington Kaitlin Emily
• Attwood Brian Christopher

Classifications

• C10G5/06

  by cooling or compressing · CPC title

• C01B2203/062

  Hydrocarbon production, e.g. Fischer-Tropsch process · CPC title

• C10J3/723

  Controlling or regulating the gasification process · CPC title

• C10L5/46

  on sewage, house, or town refuse {(C10L5/403, C10L5/406 take precedence)} · CPC title

• C10L2290/54

  Specific separation steps for separating fractions, components or impurities during preparation or upgrading of a fuel · CPC title