Polyarylene sulfide resin composition and formed article

Patent metadata

Field	Value
Publication number	US-11370915-B2
Application number	US-201916661976-A
Country	US
Kind code	B2
Filing date	Oct 23, 2019
Priority date	Sep 19, 2012
Publication date	Jun 28, 2022
Grant date	Jun 28, 2022

Abstract

The present invention relates to a polyarylene sulfide resin composition having good processability and showing excellent properties due to its more improved miscibility with other polymer materials or fillers, and a formed article. Such polyarylene sulfide resin composition includes a polyarylene sulfide including a disulfide repeating unit in the repeating units of the main chain; and at least one component selected from the group consisting of a thermoplastic resin, a thermoplastic elastomer, and a filler.

First claim

The invention claimed is:

1. A polyarylene sulfide resin composition, including a polyarylene sulfide including a disulfide repeating unit in the repeating units of the main chain and having a target viscosity; and at least one component selected from the group consisting of a thermoplastic resin, a thermoplastic elastomer, and a filler,
wherein the polyarylene sulfide includes carboxyl group (—COOH) bonded to at least part of end groups of the main chain,
wherein the polyarylene sulfide is prepared by a method comprising the steps of: (a) melt-polymerizing a reactant comprising a diiodoaromatic compound and elemental sulfur while adding a polymerization inhibitor, and (b) adding a compound having a carboxyl group only when a degree of polymerization of the melt-polymerizing step as determined by a ratio of present viscosity to the target viscosity is at least about 90% to 95%; and
wherein an FT-IR spectrum of the polyarylene sulfide shows a first peak between 1400 cm and 1600 cm −1 and a second peak between 1600 cm and 1800 cm −1 , wherein a height intensity of the second peak is between about 0.5% and about 10% of a height intensity of the first peak.

2. The polyarylene sulfide resin composition according to claim 1 , wherein the disulfide repeating unit is included in the amount of 3 weight % or less, based on the whole polyarylene sulfide.

3. A method of preparing a formed article, including the step of extruding the resin composition of claim 2 .

4. A method of preparing a formed article, including the step of injection molding the resin composition of claim 2 .

5. The method according to claim 4 , wherein the injection molding is performed in a mold having a temperature of 50° C.

6. The polyarylene sulfide resin composition according to claim 1 , wherein the thermoplastic resin is one or more selected from the group consisting of polyvinylalcohol-based resins, vinylchloride-based resins, polyamide-based resins, polyolefin-based resins, and polyester-based resins.

7. The polyarylene sulfide resin composition according to claim 1 , wherein the thermoplastic elastomer is one or more selected from the group consisting of polyvinylchloride-based elastomers, polyolefin-based elastomers, polyurethane-based elastomers, polyester-based elastomers, polyamide-based elastomers, and polybutadiene-based elastomers.

8. The polyarylene sulfide resin composition according to claim 1 , wherein the filler is a fiber type, a bead type, a flake type, or a powder type of organic or inorganic filler.

9. The polyarylene sulfide resin composition according to claim 1 , wherein the filler is one or more selected from the group consisting of glass fiber, carbon fiber, boron fiber, glass bead, glass flake, talc, and calcium carbonate.

10. The polyarylene sulfide resin composition according to claim 1 , wherein the number average molecular weight of the polyarylene sulfide is 5,000 to 50,000.

11. The polyarylene sulfide resin composition according to claim 1 , including 5 to 95 weight % of the polyarylene sulfide and 5 to 95 weight % of one or more components selected from the group consisting of thermoplastic resins, thermoplastic elastomers, and fillers.

12. The polyarylene sulfide resin composition according to claim 1 , further including an oxidation stabilizer, a photo stabilizer, a plasticizer, a lubricant, a nucleating agent, and an impact reinforcement.

13. A method of preparing a formed article, including the step of extruding the resin composition of claim 1 .

14. The method according to claim 13 , the extrusion is carried out with a twin screw extruder.

15. A formed article, including the polyarylene sulfide resin composition according to claim 1 .

16. The formed article according to claim 15 , which is a form of film, sheet, or fiber.

17. The formed article according to claim 15 , which is used for car interior parts, car exterior parts, electric parts, electronic parts, or industrial materials.

18. A method of preparing a formed article, including the step of injection molding the resin composition of claim 1 .

19. The method according to claim 18 , wherein the injection molding is performed in a mold having a temperature of 50° C.

Assignees

• Sk Chemicals Co Ltd
• Hdc Polyall Co Ltd

Inventors

• Lee Se-Ho
• Kim Sung-Gi

Classifications

• C08G75/14

  Polysulfides · CPC title

• C08G75/0213

  containing elements other than carbon, hydrogen or sulfur · CPC title

• C08J2375/02

  Polyureas · CPC title

• C08G75/02 Primary

  Polythioethers · CPC title

• C08G75/029

  Modification with organic compounds · CPC title