Polyarylene sulfide and a preparation method thereof

Patent metadata

Field	Value
Publication number	US-10875966-B2
Application number	US-201816175485-A
Country	US
Kind code	B2
Filing date	Oct 30, 2018
Priority date	Aug 7, 2012
Publication date	Dec 29, 2020
Grant date	Dec 29, 2020

Abstract

The present invention relates to a polyarylene sulfide having more improved miscibility with other polymer materials or fillers, and a method of preparing the same. At least part of end groups of the main chain of the polyarylene sulfide is carboxyl group (—COOH) or amine group (—NH2).

First claim

The invention claimed is:

1. A polyarylene sulfide of which at least part of end groups of the main chain is carboxyl group (—COOH), and the remainder of the end groups is iodine group or unsubstituted aryl group,
wherein the polyarylene sulfide is prepared by a method including the steps of:
melt-polymerizing a reactant including a diiodoaromatic compound and elemental sulfur; and
adding a compound having carboxyl group while carrying out the melt-polymerization step, wherein the compound having carboxyl group includes one or more compounds selected from the group consisting of 2-iodobenzoic acid, 3-iodobenzoic acid, 4-iodobenzoic acid, and 2,2′-dithiobenzoic acid,
wherein an FT-IR spectrum of the polyarylene sulfide shows a first peak between 1400 and 1600 cm −1 and a second peak between 1600 and 1800 cm −1 , wherein a height intensity of the second peak is between about 0.5% and about 10% of a height intensity of the first peak, and
wherein the compound having carboxyl group is added thereto when the degree of the polymerization reaction is progressed 90% or more, wherein the degree of polymerization reaction is determined by the ratio of present viscosity to target viscosity.

2. The polyarylene sulfide according to claim 1 , wherein the melting temperature is 265 to 290° C.

3. The polyarylene sulfide according to claim 1 , wherein the number average molecular weight is 5,000 to 50,000.

4. The polyarylene sulfide according to claim 1 , wherein the melt viscosity measured with a rotational viscometer at 300° C. is 10 to 50,000 poise.

5. The polyarylene sulfide according to claim 1 , wherein the tensile strength measured according to ASTM D 638 is 100 to 900 kgf/cm 2 .

6. The polyarylene sulfide according to claim 1 , wherein the elongation measured according to ASTM D 638 is 1 to 10%.

7. The polyarylene sulfide according to claim 1 , wherein the flexural strength measured according to ASTM D 790 is 100 to 2,000 kgf/cm 2 .

8. The polyarylene sulfide according to claim 1 , wherein the impact strength measured according to ASTM D 256 is 1 to 100 J/m.

9. The polyarylene sulfide according to claim 1 , wherein the compound having carboxyl group is added thereto in the amount of 0.0001 to 5 parts by weight, based on 100 parts by weight of the diiodoaromatic compound.

10. The polyarylene sulfide according to claim 1 , wherein the diiodoaromatic compound is one more compounds selected from the group consisting of diiodobenzene, diiodonaphthalene, diiodobiphenyl, diiodobisphenol, and diiodobenzophenone.

11. The polyarylene sulfide according to claim 1 , wherein polymerizing step is carried out for 1 to 30 hours by varying the temperature and pressure from the initial reaction condition of 180 to 250° C. and 50 to 450 torr to the final reaction condition of 270 to 350° C. and 0.001 to 20 torr.

12. The polyarylene sulfide according to claim 1 , wherein the method further includes the step of melt-mixing the reactant including the diiodoaromatic compound and sulfur element, before the polymerizing step.

13. A shaped article, including the polyarylene sulfide according to claim 1 .

14. The shaped article according to claim 13 , which is a form of film, sheet, or fiber.

Assignees

• Sk Chemicals Co Ltd

Inventors

• Lee Se-Ho
• Kim Sung-Gi

Classifications

• D01F6/765

  from polyarylene sulfides · CPC title

• C08L81/02

  Polythioethers; Polythioether-ethers · CPC title

• C08J2375/02

  Polyureas · CPC title

• C08G75/029

  Modification with organic compounds · CPC title

• C08G75/02 Primary

  Polythioethers · CPC title