Process for preparing a polymer/biological entities alloy

Patent metadata

Field	Value
Publication number	US-11370890-B2
Application number	US-202017038061-A
Country	US
Kind code	B2
Filing date	Sep 30, 2020
Priority date	Dec 20, 2011
Publication date	Jun 28, 2022
Grant date	Jun 28, 2022

Abstract

The present invention relates to a process for preparing a polymer/biological entities alloy, comprising a step of mixing a polymer and biological entities that degrade it, during a heat treatment, said heat treatment being performed at a temperature T above room temperature and said biological entities being resistant to said temperature T, characterized in that said biological entities are chosen from enzymes that degrade said polymer and microorganisms that degrade said polymer.

First claim

We claim:

1. A process for preparing a polymer and enzyme alloy, comprising:
a step of selecting a polymer from polyesteramides, vinyl polymers, poly(C 1 -C 6 hydroxyalkanoates), poly(butylene adipate-co-terephthalate), poly(butylene succinate), polyamides, polyvinyl chloride, polyethylene, polypropylene, polyethylene terephthalate, or poly(trimethylene terephthalate) and mixtures thereof;
a step of selecting enzymes that degrade said polymer; and
a step of mixing said enzymes and said polymer during extrusion at a temperature (T) corresponding to the melting point of said polymer, the extrusion being performed in a twin screw extruder.

2. The process as claimed in claim 1 , wherein the enzyme:polymer weight ratio is between about 0.1:100 and about 10:100.

3. The process as claimed in claim 1 , wherein the enzyme:polymer weight ratio is between about 1:100 and about 3:100.

4. The process as claimed in claim 1 , wherein the enzyme:polymer weight ratio is about 2:100.

5. The process as claimed in claim 1 , wherein the twin-screw extruder is a co-rotating extruder.

6. A polymer and enzyme alloy made by the process as claimed in claim 1 .

7. The process as claimed in claim 1 , wherein the polymer is selected from poly(butylene adipate-co-terephthalate) or poly(butylene succinate).

8. The process as claimed in claim 1 , wherein the polymer is polyethylene.

9. The process as claimed in claim 1 , wherein the polymer is polypropylene.

10. The process as claimed in claim 1 , wherein the polymer is polyethylene terephthalate.

Assignees

• Centre National De La Rech Scientifique—Cnrs
• Univ Poitiers
• Valagro Carbone Renouvelable Poitou Charentes

Inventors

• Ferreira Thierry
• Bataille Frederic
• Dever Cedric
• Barbier Jacques

Classifications

• C08J3/201

  Pre-melted polymers · CPC title

• C12N9/14

  Hydrolases (3) · CPC title

• C08J3/20 Primary

  Compounding polymers with additives, e.g. colouring · CPC title

• C12N11/096

  Polyesters; Polyamides · CPC title

• C08J2367/04

  Polyesters derived from hydroxy carboxylic acids, e.g. lactones (C08J2367/06 takes precedence) · CPC title