Method for producing metal oxide particles, method for producing dispersion of metal oxide particles, and method for producing infrared shielding film

Patent metadata

Field	Value
Publication number	US-11365129-B2
Application number	US-201816482804-A
Country	US
Kind code	B2
Filing date	Jan 26, 2018
Priority date	Feb 6, 2017
Publication date	Jun 21, 2022
Grant date	Jun 21, 2022

Abstract

Production method for metal oxide fine particles includes: a step of mixing a fatty acid represented by CnH2nO2 (n=5 to 14) and a metal source consisting of a metal, metal oxide, or metal hydroxide of at least two metal elements selected from the group consisting of Zn, In, Sn, and Sb to obtain a mixture; a step of heating the mixture at a temperature that is equal to or higher than a melting temperature of the fatty acid and lower than a decomposition temperature of the fatty acid to obtain a metal soap which is a precursor of metal oxide fine particles; and a step of heating the precursor at a temperature that is equal to or higher than a melting temperature of the precursor and lower than a decomposition temperature of the precursor to obtain metal oxide fine particles having an average particle diameter of 80 nm or less.

First claim

The invention claimed is:

1. A method for producing metal oxide fine particles, the method comprising:
a step of mixing a fatty acid represented by C n H 2n O 2 (n=5 to 14) and a metal source consisting of a metal, metal oxide, or metal hydroxide of at least two metal elements selected from the group consisting of Zn, In, Sn, and Sb to obtain a mixture;
a step of heating the mixture at a temperature that is equal to or higher than the melting temperature of the fatty acid and lower than the decomposition temperature of the fatty acid to obtain a metal soap which is a precursor of metal oxide fine particles; and
a step of heating the precursor at a temperature that is equal to or higher than the melting temperature of the precursor and lower than the decomposition temperature of the precursor to obtain metal oxide fine particles having an average particle diameter of 80 nm or less.

2. The method for producing metal oxide fine particles according to claim 1 , wherein the heating temperature for the mixture is set to be in a range of 130° C. to 250° C., and the heating temperature for the precursor is set to be in a range of 200° C. to 350° C.

3. A method for producing a dispersion of metal oxide fine particles, the method comprising:
a step of mixing the metal oxide fine particles produced by the method according to claim 1 and a hydrophobic solvent to obtain a dispersion of the metal oxide fine particles.

4. A method for producing an infrared shielding film, the method comprising:
a step of applying the dispersion of the metal oxide fine particles produced by the method according to claim 3 to a substrate to obtain an infrared shielding film.

5. A method for producing a dispersion of metal oxide fine particles, the method comprising:
a step of mixing the metal oxide fine particles produced by the method according to claim 2 and a hydrophobic solvent to obtain a dispersion of the metal oxide fine particles.

6. A method for producing an infrared shielding film, the method comprising:
a step of applying the dispersion of the metal oxide fine particles produced by the method according to claim 5 to a substrate to obtain an infrared shielding film.

Assignees

• Mitsubishi Materials Corp

Inventors

• Higano Satoko
• Yamasaki Kazuhiko

Classifications

• C01P2002/54

  one element only · CPC title

• C01G30/02 Primary

  Antimonates; Antimonites {(C01G30/001 takes precedence)} · CPC title

• C01P2002/01

  depicted by a TEM-image · CPC title

• C01G9/02

  Oxides; Hydroxides · CPC title

• C01G19/00 Primary

  Compounds of tin · CPC title