Method for oligomerizing olefins

Patent metadata

Field	Value
Publication number	US-11358913-B2
Application number	US-201816649916-A
Country	US
Kind code	B2
Filing date	Sep 10, 2018
Priority date	Nov 30, 2017
Publication date	Jun 14, 2022
Grant date	Jun 14, 2022

Abstract

The present invention relates to a method for oligomerizing olefins including the steps of: carrying out an oligomerization reaction of olefins by injecting an oligomerization transition metal catalyst, a cocatalyst, an olefin monomer and a solvent into a reactor; and injecting, into the reaction product of the oligomerization reaction, a catalyst inactivator including a gaseous inorganic material that contains oxygen.

First claim

The invention claimed is:

1. A method for oligomerizing olefins, the method comprising the steps of:
introducing an oligomerization transition metal catalyst, a cocatalyst, an olefin monomer, and a solvent into a reactor to perform an olefin oligomerization reaction and produce a reaction product comprising oligomers, wherein the transition metal catalyst is represented by ML 1 (L 2 ) p (X) q or M 2 X 1 2 (L 2 ) y (X) z , wherein M is a transition metal, L 1 is a heteroligand, L 2 is an organic ligand, X and X 1 are each independently a halogen, p is an integer of 0 or 1 or more, q is an integer of (oxidation number of M-p), y is an integer of 2 or more, and z is an integer of (2 x oxidation number of M) —y, and wherein 1-octene is included at 30% by weight or more, based on 100% by weight of linear alpha olefins in the reaction product of the oligomerization reactor;
introducing a catalyst inactivator, which includes an oxygen-containing inorganic material in a gas phase, to the reaction product of the oligomerization reaction, wherein the oxygen-containing inorganic material is O 2 , CO 2 , CO, H 2 O, NO x , SO X , or a mixture thereof; and
separating the oligomers from the reaction product of the oligomerization reaction.

2. The method of claim 1 , wherein the oxygen-containing inorganic material is in a gas phase at 25° C. and 1 atmospheric pressure (atm).

3. The method of claim 1 , wherein the oxygen-containing inorganic material is O 2 or CO 2 .

4. The method of claim 1 , wherein the catalyst inactivator includes 0.5 to 100% by weight of the oxygen-containing inorganic material.

5. The method of claim 1 , wherein the introducing of the catalyst inactivator is performed at 80° C. to 100° C.

6. The method of claim 1 , further comprising, after the introducing of the catalyst inactivator:
subjecting a gel- or solid-phase component including an inactivated catalyst to solid-liquid separation.

7. The method of claim 1 , further comprising, after the introducing of the catalyst inactivator:
separating an unreacted catalyst inactivator by distillation or adsorption.

8. The method of claim 1 , further comprising:
recirculating at least a portion of the reaction product including an unreacted olefin monomer present in the step of introducing of the catalyst inactivator, to the step of performing the oligomerization reaction.

9. The method of claim 8 , wherein, in the recirculating of at least a portion of the reaction product, the catalyst inactivator in the reaction product including the unreacted olefin monomer is removed by adsorption.

10. The method of claim 1 , wherein the cocatalyst is an aluminum compound, an organoaluminoxane, an organoboron compound, or a mixture thereof.

11. The method of claim 10 , wherein an amount of the introduced catalyst inactivator is such an amount that an amount of the oxygen-containing inorganic material in the catalyst inactivator is 1 to 50 times higher than the total number of moles of aluminum, boron, or a combination thereof in the cocatalyst based on the number of moles.

12. The method of claim 1 , wherein the olefin monomer is ethylene, and the oligomers include a mixture of C4-C40 linear alpha olefins.

Assignees

• Sk Innovation Co Ltd
• Sk Global Chemical Co Ltd

Inventors

• Jung Woosung
• Park Chansaem
• Park Hyoseung
• Son Sungreal
• Song Inhyoup

Classifications

• C07C7/20

  Use of additives, e.g. for stabilisation · CPC title

• C07C7/04

  by distillation · CPC title

• B01J31/24

  Phosphines {, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands} · CPC title

• C07C7/12

  by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers · CPC title

• C07C2/32 Primary

  as complexes, e.g. acetyl-acetonates {(complexes of salts of acids of halogen C07C2/20)} · CPC title