Ethylene oligomerization process

Patent metadata

Field	Value
Publication number	US-9598329-B2
Application number	US-201313891607-A
Country	US
Kind code	B2
Filing date	May 10, 2013
Priority date	May 11, 2012
Publication date	Mar 21, 2017
Grant date	Mar 21, 2017

Abstract

An ethylene oligomerization system is useful for creating 1-butene from ethylene in the presence of an ethylene oligomerization catalyst. The ethylene oligomerization system includes an internal baffle single pass reactor, a separation system and an exterior motion driver. The exterior motion driver is operable to induce unsteadiness in the flow of the process fluid contained in the internal baffle single pass reactor by transferring motion into the process fluid. An ethylene oligomerization process is useful for creating a refined 1-butene product from ethylene using the ethylene oligomerization system.

First claim

What is claimed is:

1. An ethylene oligomerization process for creating a refined 1-butene product from ethylene using an ethylene oligomerization system, the ethylene oligomerization process comprising the steps of:
introducing a reaction solution into a process fluid contained in an internal fluid conduit of an internal baffle single pass reactor at about a proximal end of the reactor such that the process fluid traverses an operative length of the reactor by flowing along a process fluid flow pathway;
introducing ethylene, an oligomerization pre-catalyst and a co-catalyst separately into the process fluid proximate to an oligomerization reaction zone such that the ethylene, the oligomerization pre-catalyst and the co-catalyst are distributed in the process fluid;
introducing a catalyst inhibitor into the process fluid in a catalyst deactivation zone disposed in the internal baffle single pass reactor by way of a catalyst inhibitor injection port in fluid communication with the internal fluid conduit to terminate all oligomerization and side-reactions, the catalyst deactivation zone extending along the operable length of the internal baffle single pass reactor from about the catalyst inhibitor injection port to a distal end of the internal baffle single pass reactor, such that the catalyst inhibitor is distributed in the process fluid;
passing unused catalyst inhibitor from the distal end of the internal baffle single pass reactor to avoid buildup of unused catalyst inhibitor in the internal baffle single pass reactor; and
operating the ethylene oligomerization system such that
an oligomerization catalyst forms in the process fluid from the reaction of the oligomerization pre-catalyst and the co-catalyst in the oligomerization reaction zone,
1-butene forms in the process fluid from an oligomerization reaction of ethylene in the presence of the oligomerization catalyst in the oligomerization reaction zone,
a deactivated oligomerization catalyst forms in the process fluid from the reaction of the oligomerization catalyst and the catalyst inhibitor in the catalyst deactivation zone,
an external motion driver having a process fluid oscillator moves an oscillator head in a back-and-forth linear direction to induce unsteadiness in the flow of the process fluid,
a crude product passes into a separation system, the crude product comprising the 1-butene, unreacted ethylene from the ethylene oligomerization, and the deactivated oligomerization catalyst, and
the separation system removes the deactivated oligomerization catalyst, the unreacted ethylene and the 1-butene separately from the crude product such that a refined 1-butene product is produced;

where the ethylene oligomerization system comprises the internal baffle single pass reactor, the separation system and the external motion driver, where the internal baffle single pass reactor has the oligomerization reaction zone and the catalyst deactivation zone and where the catalyst deactivation zone is positioned downstream of the oligomerization reaction zone.

2. The process of claim 1 where the reaction solution comprises 1-butene.

3. The process of claim 2 where the reaction solution consists essentially of 1-butene.

4. The process of claim 1 where the oligomerization pre-catalyst includes a transition metal and the co-catalyst is an alkyl of a Group 1-3 or a Group 11-13 metal according to the IUPAC Periodic Table of Elements.

5. The process of claim 1 further comprising the step of introducing a catalyst additive that includes a Group 14-17 element according to the IUPAC Periodic Table of Elements into the process fluid proximate to the oligomerization reaction zone such that the catalyst additive is distributed in the process fluid.

6. The process of claim 1 further comprising the step of operating the ethylene oligomerization system such that the temperature of the process fluid within the internal baffle single pass reactor is maintained in a range of from about 30° C. to about 110° C.

7. The process of claim 1 further comprising the step of operating the ethylene oligomerization system such that the pressure of the process fluid within the internal baffle single pass reactor is maintained in a range of from about 1 bar to about 50 bars gauge.

8. The process of claim 1 further comprising the step of operating the ethylene oligomerization system such that the residence time of the oligomerization catalyst in the internal baffle single pass reactor is maintained in a range of from about 0.01 to about 2 hours.

9. The process of claim 1 further comprising the steps of operating the ethylene oligomerization system such that 1-hexene forms in the process fluid from the oligomerization reaction of ethylene in the presence of the oligomerization catalyst in the oligomerization reaction zone, wherein the crude product further comprises the 1-hexene and such that the separation system separates 1-hexene from the crude product such that a refined 1-hexene product is produced.

10. The process of claim 1 further comprising the steps of operating the ethylene oligomerization system such that 1-octene forms in the process fluid from the oligomerization reaction of ethylene in the presence of the oligomerization catalyst in the oligomerization reaction zone, wherein the crude product further comprises the 1-octene and such that the separation system separates 1-octene from the crude product such that a refined 1-octene product is produced.

11. The process of claim 1 further comprising the steps of operating the ethylene oligomerization system such that 1-decene forms in the process fluid from the oligomerization reaction of ethylene in the presence of the oligomerization catalyst in the oligomerization reaction zone, wherein the crude product further comprises the 1-decene and such that the separation system separates 1-decene from the crude product such that a refined 1-decene product is produced.

12. The process of claim 1 further comprising the step of operating the ethylene oligomerization system such that at least a portion of the refined 1-butene product is recycled from the separation system and is introduced into the process fluid of the internal baffle single pass reactor.

13. The process of claim 1 further comprising the step of operating the ethylene oligomerization system such that the unreacted ethylene that is separated from the crude product is recycled from the separation system and is introduced into the process fluid of the internal baffle single pass reactor.

14. The process of claim 1 where the ethylene oligomerization system has more than one ethylene oligomerization reaction zone, the process further comprising the step of introducing ethylene into the process fluid proximate to each oligomerization reaction zone such that the ethylene is distributed into the process fluid in each oligomerization reaction zone.

Assignees

• Saudi Arabian Oil Co

Inventors

• Shaik Kareemuddin Mahaboob
• Xu Wei

Classifications

• B01J2219/00108

  involving reactant vapours · CPC title

• C07C2/30

  containing metal-to-carbon bond; Metal hydrides · CPC title

• B01J19/241 Primary

  of the pulsating type · CPC title

• B01J19/2415

  Tubular reactors · CPC title

• B01J2219/00777

  horizontal · CPC title