Acidic gas absorbent, acidic gas removal method and acidic gas removal apparatus

Patent metadata

Field	Value
Publication number	US-11358092-B2
Application number	US-202017014796-A
Country	US
Kind code	B2
Filing date	Sep 8, 2020
Priority date	Mar 18, 2020
Publication date	Jun 14, 2022
Grant date	Jun 14, 2022

Abstract

The embodiments provide an acidic gas absorbent kept from deterioration, an acidic gas removal method using the absorbent, and an acidic gas removal apparatus using the same. The acidic gas absorbent contains an amine compound and water, and further contains superfine bubble containing inert gas wherein an average diameter of said superfine bubble is 150 nm or less. The acidic gas removal method provided here employs that absorbent. The acidic gas removal apparatus is equipped with a unit for introducing the superfine bubbles into the absorbent.

First claim

The invention claimed is:

1. An acidic gas absorbent containing an amine compound, water and superfine bubble containing inert gas wherein an average diameter of said superfine bubble is 150 nm or less.

2. The acidic gas absorbent according to claim 1 , wherein said inert gas is selected from the group consisting of nitrogen, helium, neon and argon.

3. The acidic gas absorbent according to claim 1 , wherein said superfine bubbles are contained in an amount of 1×10 7 to 1×10 12 bubbles per 1 mL.

4. The acidic gas absorbent according to claim 1 , wherein said amine compound is selected from the group consisting of primary amines, secondary amines, tertiary amines and quaternary ammoniums.

5. The acidic gas absorbent according to claim 1 , wherein said amine compound is contained in an amount of 3 to 80 mass % based on the total mass of the acidic gas absorbent.

6. The acidic gas absorbent according to claim 1 , which further contains at least one additive agent selected from the group consisting of oxidation inhibitors, pH adjusters, defoaming agents, and anticorrosive agents.

7. An acidic gas removal method in which
a gas containing an acidic gas is brought into contact with the acidic gas absorbent according to claim 1 so as to remove the acidic gas from the acidic gas-containing gas.

8. An acidic gas removal apparatus comprising:
an absorption unit in which a gas containing an acidic gas is brought into contact with an acidic gas absorbent containing an amine compound and water, so that the absorbent absorbs the acidic gas to remove it from the acidic gas-containing gas;
a superfine bubble-introducing unit in which superfine bubble containing inert gas wherein an average diameter of said superfine bubble is 150 nm or less are introduced into said acidic gas absorbent; and
a regeneration unit in which the absorbent holding the acidic gas is made to release the acidic gas so as to be regenerated;
so that the absorbent regenerated in the regeneration unit is reused in the absorption unit.

Assignees

• Toshiba Kk
• Toshiba Energy Systems & Solutions Corp

Inventors

• Suzuki Akiko
• Nakano Yoshihiko
• Yoshimura Reiko
• Imada Toshihiro
• Kuboki Takashi
• Sano Kenji
• Udatsu Mitsuru

Classifications

• B01D53/1475 Primary

  Removing carbon dioxide · CPC title

• B01D2252/20489

  with two or more hydroxyl groups · CPC title

• B01D2252/20447

  containing a piperazine-ring · CPC title

• B01D53/1425

  Regeneration of liquid absorbents · CPC title

• B01D2252/504

  Mixtures of two or more absorbents · CPC title