Acid gas absorbent, acid gas removal method, and acid gas removal device

Patent metadata

Field	Value
Publication number	US-9409119-B2
Application number	US-201113332018-A
Country	US
Kind code	B2
Filing date	Dec 20, 2011
Priority date	Dec 22, 2010
Publication date	Aug 9, 2016
Grant date	Aug 9, 2016

Abstract

An acid gas absorbent of which recovery amount of acid gas such as carbon dioxide is high, and an acid gas removal device and an acid gas removal method using the acid gas absorbent are provided. The acid gas absorbent of the embodiment comprising at least one type of tertiary amine compound represented by the following general formula (1).

(In the above-stated formula (1), either one of the R 1 , R 2 represents a substituted or non-substituted alkyl group of which carbon number is 2 to 5, and the other one represents a substituted or non-substituted alkyl group of which carbon number is 1 to 5. The R 3 represents a methyl group or an ethyl group, and the R 4 represents a hydroxyalkyl group. The R 1 , R 2 may either be the same or different, and they may be coupled to form a cyclic structure.)

First claim

What is claimed is:

1. An acid gas absorbent comprising at least one type of tertiary amine compound represented by the following general formula (1):

wherein
the R 3 represents a methyl group or an ethyl group, and the R 4 represents a hydroxyalkyl group;
R 1, R 2 are coupled to form a cyclopentyl group; and
wherein a content of the tertiary amine compound represented by the general formula (1) is 10 mass % to 55 mass %.

2. The acid gas absorbent according to claim 1 , wherein the R 4 is a 2-hydroxyethyl group in the tertiary amine compound represented by the general formula (1).

3. The acid gas absorbent according to claim 1 , further comprising
a reaction accelerator consisting of alkanolamines and/or a hetero cyclic amine compound represented by the following general formula (2), wherein a content of the reaction accelerator is 1 mass % to 20 mass %:

wherein the R 5 represents a hydrogen atom or a substituted or non-substituted alkyl group having a carbon number from 1 to 4,
the R 6 represents a substituted or non-substituted alkyl group having a carbon number from 1 to 4 coupled to a carbon atom;
the “n” represents an integer from 1 to 3, the “m” represents an integer from 1 to 4, and the “p” represents an integer from “0” (zero) to 12;
when the “n” is 2 to 3, the nitrogen atoms are not directly coupled with each other.

4. The acid gas absorbent according to claim 3 , wherein the alkanolamines are at least one type selected from a group consisting of 2-(isopropylamino)ethanol, 2-(ethylamino)ethanol, and 2-amino-2-methyl-1-propanol.

5. The acid gas absorbent according to claim 3 , wherein the hetero cyclic amine compound includes at least one type selected from a group of piperazines.

6. The acid gas absorbent according to claim 5 , wherein the piperazines are at least one type selected from a group consisting of piperazine, 2-methylpiperazine, 2,5-dimethylpiperazine, and 2,6-dimethylpiperazine.

7. An acid gas absorbent comprising at least one type of secondary amine compound represented by the following general formula (4):

wherein
the R 12 represents a hydroxyalkyl group;
the R 10 , R 11 are coupled to form a cyclopentyl group;
wherein a content of the secondary amine compound represented by the general formula (4) is 10 mass % to 55 mass %.

8. The acid gas absorbent according to claim 7 , wherein the R 12 is a 2-hydroxyethyl group in the secondary amine compound represented by the general formula (4).

9. The acid gas absorbent according to claim 7 , further comprising
a reaction accelerator consisting of alkanolamines and/or a hetero cyclic amine compound represented by the following general formula (2), wherein a content of the reaction accelerator is 1 mass % to 20 mass %:

wherein the R 5 represents a hydrogen atom or a substituted or non-substituted alkyl group having a carbon number from 1 to 4,
the R 6 represents a substituted or non-substituted alkyl group having a carbon number from 1 to 4 coupled to a carbon atom;
the “n” represents an integer from 1 to 3, and the “m” represents an integer from 1 to 4, and the “p” represents an integer from “0” (zero) to 12;
when the “n” is 2 to 3, the nitrogen atoms are not directly coupled with each other.

10. The acid gas absorbent according to claim 9 , wherein the alkanolamines are at least one type selected from a group consisting of 2-(isopropylamino)ethanol, 2-(ethylamino)ethanol, and 2-amino-2-methyl-1-propanol.

11. The acid gas absorbent according to claim 9 , wherein the hetero cyclic amine compound includes at least one type selected from a group of piperazines.

12. The acid gas absorbent according to claim 11 , wherein the piperazines are at least one type selected from a group consisting of piperazine, 2-methylpiperazine, 2,5-dimethylpiperazine, and 2,6-dimethylpiperazine.

13. An acid gas removal method, comprising:
bringing gas containing acid gas into contact with the acid gas absorbent according to claim 1 to remove the acid gas from the gas containing the acid gas.

14. An acid gas removal method, comprising:
bringing gas containing acid gas into contact with the acid gas absorbent according to claim 3 to remove the acid gas from the gas containing the acid gas.

15. An acid gas removal method, comprising:
bringing gas containing acid gas into contact with the acid gas absorbent according to claim 7 to remove the acid gas from the gas containing the acid gas.

16. An acid gas removal method, comprising:
bringing gas containing acid gas into contact with the acid gas absorbent according to claim 9 to remove the acid gas from the gas containing the acid gas.

17. An acid gas removal device removing acid gas from gas containing the acid gas, comprising:
an absorption tower bringing the gas containing the acid gas into contact with the acid gas absorbent according to claim 1 to remove the acid gas from the gas; and
a regeneration tower removing the acid gas from the acid gas absorbent absorbing the acid gas and regenerating the acid gas absorbent to be reused at the absorption tower.

18. An acid gas removal device removing acid gas from gas containing the acid gas, comprising:
an absorption tower bringing the gas containing the acid gas into contact with the acid gas absorbent according to claim 3 to remove the acid gas from the gas; and
a regeneration tower removing the acid gas from the acid gas absorbent absorbing the acid gas and regenerating the acid gas absorbent to be reused at the absorption tower.

19. An acid gas removal device removing acid gas from gas containing the acid gas, comprising:
an absorption tower bringing the gas containing the acid gas into contact with the acid gas absorbent according to claim 7 to remove the acid gas from the gas; and
a regeneration tower removing the acid gas from the acid gas absorbent absorbing the acid gas and regenerating the acid gas absorbent to be reused at the absorption tower.

20. An acid gas removal device removing acid gas from gas containing the acid gas, comprising:
an absorption tower bringing the gas containing the acid gas into contact with the acid gas absorbent according to claim 9 to remove the acid gas from the gas; and
a regeneration tower removing the acid gas from the acid gas absorbent absorbing the acid gas and regenerating the acid gas absorbent to be reused at the absorption tower.

Assignees

• Murai Shinji
• Maezawa Yukishige
• Kato Yasuhiro
• Muramatsu Takehiko
• Saito Satoshi
• Watando Hiroko
• Shida Naomi
• Yoshimura Reiko
• Kuboki Takashi
• Toshiba Kk

Inventors

• Murai Shinji
• Maezawa Yukishige
• Kato Yasuhiro
• Muramatsu Takehiko
• Saito Satoshi
• Watando Hiroko
• Shida Naomi
• Yoshimura Reiko
• Kuboki Takashi

Classifications

• B01D2252/20484

  with one hydroxyl group · CPC title

• B01D2252/20442

  containing a piperidine-ring · CPC title

• B01D53/1493 Primary

  Selection of liquid materials for use as absorbents · CPC title

• B01D2252/20426

  Secondary amines · CPC title

• B01D2252/20447

  containing a piperazine-ring · CPC title