Polyurethane foams based on polyethercarbonate polyols

Patent metadata

Field	Value
Publication number	US-11345775-B2
Application number	US-201615781941-A
Country	US
Kind code	B2
Filing date	Dec 6, 2016
Priority date	Dec 9, 2015
Publication date	May 31, 2022
Grant date	May 31, 2022

Abstract

The present invention relates to a method for producing polyurethane foams by reacting an isocyanate component with an isocyanate-reactive component comprising at least one polyethercarbonate polyol, the reaction taking place in the presence of a component K selected from one or more compounds from the group consisting of K1 esters of mono- or polybasic carboxylic acids whose (first) dissociation has a pKa of 0.5 to 4.0, K2 mono-, di- and polysulfonates of mono- and polyfunctional alcohols, and K3 one or more compounds from the group consisting of K 3.1 esters of phosphoric acid, phosphonic acid, phosphorous acid, phosphinic acid, phosphonous acid and phosphinous acid, these esters each containing no P—OH group, K3.2 oligomeric alkyl phosphates of the general formula (II), where a is an integer from 1 to 10, b is an integer from 1 to 10, R1, R2, R3 and R4 are alkyl groups having at least one carbon, and R1, R2, R3 and R4 are alike or, independently of one another, different, and R5 is a linear alkylene group having at least two carbons or is a branched alkylene group having at least three carbons, and K3.3 comprises oligomeric alkyl phosphates of the general formula (III), where a is an integer from 1 to 10, b is an integer from 1 to 10, R1, R4 and R5 are linear alkylene groups having at least two carbons or are branched alkylene groups having at least three carbons, and R1, R4 and R5 are alike or, independently of one another, different, and R2 and R3 are alkyl groups having at least one carbon, and R2 and R3 are alike or, independently of one another, different. The invention also relates to polyurethane foams produced by the method of the invention and to the use thereof.

First claim

The invention claimed is:

1. A process for producing polyurethane foams comprising reacting
a component A comprising A1 a polyethercarbonate polyol having a hydroxyl number in accordance with DIN 53240 of from ≥20 mg KOH/g to ≤120 mg KOH/g, and optionally, A2 one or more polyether polyols having a hydroxyl number in accordance with DIN 53240 of from ≥20 mg KOH/g to ≤250 mg KOH/g and a content of oxyethylene units of from ≥0 to ≤60% by weight, with said polyether polyols A2 being free of carbonate units,
with
a component D comprising one or more diisocyanates and/or polyisocyanates,
wherein the reaction is carried out at an isocyanate index of from ≥90 to ≤120, and in the presence of an optional component B, a component C, and a component K, wherein optional component B comprises B1) a catalyst, and/or B2) auxiliaries and additives; component C comprises water and/or physical blowing agents; and component K comprising a reaction product of phosphoric acid with ethylene oxide,
and component K is present in an amount of from ≥1.0 to ≤5.0 parts by weight, where all parts by weight for component K are based on the sum of the parts by weight of the components A1+A2=100 parts by weight.

2. The process as claimed in claim 1 , wherein component A comprises:
A1 from ≥40 to ≤100 parts by weight of one or more polyether carbonate polyols having a hydroxyl number in accordance with DIN 53240 of from ≥20 mg KOH/g to ≤120 mg KOH/g,
A2 from ≤60 to ≥0 parts by weight of one or more polyether polyols having a hydroxyl number in accordance with DIN 53240 of from ≥20 mg KOH/g to ≤250 mg KOH/g and a content of oxyethylene units of from ≥0 to ≤60% by weight, with said polyether polyols A2 being free of carbonate units,
A3 from ≤20 to ≥0 parts by weight, based on the sum of the parts by weight of the components A1 and A2, of one or more polyether polyols having a hydroxyl number in accordance with DIN 53240 of from ≥20 mg KOH/g to ≤250 mg KOH/g and a content of oxyethylene units of ≥60% by weight, with said polyether polyols A3 being free of carbonate units,
A4 from ≤40 to ≥0 parts by weight, based on the sum of the parts by weight of the components A1 and A2, of one or more polymer polyols, PUD polyols and/or PIPA polyols,
A5 from ≤40 to ≥0 parts by weight, based on the sum of the parts by weight of the components A1 and A2, of polyols which do not come under the definition of the components A1 to A4,
wherein all parts by weight for components A1, A2, A3, A4 and A5 are normalized so that the sum of the parts by weight of A1+A2 in the composition equals 100 parts by weight.

3. The process as claimed in claim 1 , wherein component K is present in an amount of from ≥2.0 to ≤5.0 parts by weight, where all parts by weight for the component K are based on the sum of the parts by weight of the components A1+A2=100 parts by weight.

4. The process as claimed in claim 1 , wherein the reaction occurs in the presence of component B which comprises
B1 a catalyst comprising at least one of
a) aliphatic tertiary amines, cycloaliphatic tertiary amines, aliphatic amino ethers, cycloaliphatic amino ethers, aliphatic amidines, cycloaliphatic amidines, urea, and derivatives of urea
and/or
b) tin(II) salts of carboxylic acids
and
B2 optionally auxiliaries and additives.

5. The process as claimed in claim 1 , wherein the reaction occurs in the presence of component B which comprises at least one of
B1 a catalyst,
and
B2 auxiliaries and additives,
wherein B1 said catalyst comprises
B1.1 from ≥0.05 to ≤1.5 parts by weight, based on the sum of the parts by weight of the components A1 and A2, of urea and/or derivatives of urea.

6. The process as claimed in claim 2 , wherein component A is free of components A3 and/or A4.

7. The process as claimed in claim 1 , wherein component A comprises:
A1 from ≥65 to ≤75 parts by weight of one or more polyether carbonate polyols having a hydroxyl number in accordance with DIN 53240 of from ≥20 mg KOH/g to ≤120 mg KOH/g,
and
A2 from ≤35 to ≥25 parts by weight of one or more polyether polyols having a hydroxyl number in accordance with DIN 53240 of from ≥20 mg KOH/g to ≤250 mg KOH/g and a content of ethylene oxide of from ≥0 to ≤60% by weight, with the polyether polyols A2 being free of carbonate units.

8. The process as claimed in claim 1 , wherein component A1 comprises a polyether carbonate polyol which is obtainable by copolymerization of carbon dioxide and one or more alkylene oxides in the presence of one or more H-functional starter molecules, with the polyether carbonate polyol having a CO 2 content of from 15 to 25% by weight.

9. The process as claimed in claim 4 , wherein B1 said catalyst comprises b) at least one tin(II) salt corresponding to the formula (IX)
Sn(C x H 2x+1 COO) 2   (IX)

wherein x represents an integer from 8 to 24.

10. The process as claimed in claim 1 , wherein component D said one or more diisocyanates and/or polyisocyanates comprise 2,4- and/or 2,6-TDI.

11. A polyurethane foam obtained by the process as claimed in claim 1 .

12. The polyurethane foam as claimed in claim 11 , wherein the polyurethane foam is a flexible polyurethane foam.

13. A furniture article, a textile insert, bedding or automotive article comprising the polyurethane foam of claim 11 .

14. The process as claimed in claim 9 , wherein x represents an integer from 10 to 20.

15. The process as claimed in claim 9 , wherein x represents an integer from 12 to 18.

16. The process as claimed in claim 1 , wherein component K further comprises one or more of:
K1 an ester of one or more of a monobasic and polybasic carboxylic acid whose first dissociation has a pKa of from 0.5 to 4.0,
K2 one or more of a monosulfonate, disulfonate or polysulfonate of a monofunctional and/or polyfunctional alcohol,
or
K3 one or more compounds comprising
K 3.1 an ester of one or more of phosphoric acid, phosphonic acid, phosphorous acid, phosphinic acid, phosphonous acid or phosphinous acid, wherein the ester does not contain a P—OH group and is different from the reaction product of phosphoric acid with ethylene oxide,
K3.2 an oligomeric alkyl phosphate corresponding to the general formula (II),

wherein
a represents an integer from 1 to 10,
b represents an integer from 1 to 10,
R1, R2, R3, R4 each represent an alkyl group having at least one carbon atom, wherein R1, R2, R3, R4 are identical or different from one another, and
R5 represents a linear alkylene group having at least two carbon atoms or a branched alkylene group having at least three carbon atoms,

and

K3.3 an oligomeric alkyl phosphate corresponding to the general formula (III),

wherein
a represents an integer from 1 to 10,
b represents an integer from 1 to 10,
R1, R4, R5 each represent a linear alkylene group having at least two carbon atoms or a branched alkylene group having at least three carbon atoms, wherein R1, R4, R5 are identical or different from one another,
and
R2, R3 each represent an alkyl group having at least one carbon atom, wherein
R2 and R3 are identical or different from one another.

Assignees

• Covestro Deutschland Ag

Inventors

• Klesczewski Bert
• Hofmann Jörg
• Malsch Karsten
• Welsch Nicole
• Lorenz Klaus
• Nefzger Hartmut
• Laemmerhold Kai

Classifications

• C08J9/0033

  containing sulfur · CPC title

• C08J2203/10

  Water or water-releasing compounds · CPC title

• C08J2205/06

  Flexible foams · CPC title

• C08G64/183

  containing polyether sequences · CPC title

• C08G18/40

  High-molecular-weight compounds {(C08G18/2805 takes precedence)} · CPC title