Method for producing polyether carbonate polyols

Patent metadata

Field	Value
Publication number	US-9815965-B2
Application number	US-201414908600-A
Country	US
Kind code	B2
Filing date	Jul 25, 2014
Priority date	Aug 2, 2013
Publication date	Nov 14, 2017
Grant date	Nov 14, 2017

Abstract

The invention relates to a method for producing polyether carbonate polyols, (i) one or more alkylene oxide(s) and carbon dioxide being added to one or more H-functional starter substance(s) in the presence of a double metal cyanide catalyst or in the presence of a metal complex catalyst based on the metals zinc and/or cobalt, a reaction mixture containing the polyether carbonate polyol being obtained, characterized in that (ii) at least one component K is added to the obtained reaction mixture containing the polyether carbonate polyol, wherein component K is selected from at least one compound that contains a phosphorus-oxygen bond or a compound of phosphorus that can form one or more P—O bonds by reaction with OH-functional compounds.

First claim

The invention claimed is:

1. A process for preparing polyether carbonate polyols, comprising
(i) adding one or more alkylene oxide(s) and carbon dioxide onto one or more H-functional starter substance(s) in the presence of a double metal cyanide catalyst to obtain a reaction mixture comprising the polyether carbonate polyol,
and
(ii) adding at least one component K to the reaction mixture comprising the polyether carbonate polyol obtained in (i), wherein component K is at least one compound containing a phosphorus-oxygen bond or a compound of phosphorus that can form one or more P—O bonds by reaction with one or more OH-functional compounds.

2. The process of claim 1 , wherein the content of volatile constituents in the polyether carbonate polyol from step (i) is reduced by thermal means at a temperature of 80° C. to 200° C. prior to step (ii).

3. The process of claim 1 , wherein
(iii) the content of volatile constituents in the reaction mixture from step (ii) is reduced by thermal means at a temperature of 80° C. to 200° C.

4. The process of claim 3 , comprising
(iv) adding at least one component K to the reaction mixture comprising the polyether carbonate polyol from step (iii).

5. The process of claim 4 , wherein in step (iv) component K is added in an amount of from 20 ppm to 1000 ppm.

6. The process of claim 1 , wherein in step (ii) component K is added in an amount of from 20 ppm to 1000 ppm.

7. The process of claim 1 , wherein component K is selected from at least one compound from the group consisting of phosphoric acid, phosphonic acid, phosphorous acid, phosphinic acid, phosphonous acid, phosphinous acid, phosphine oxides and salts, esters, halides and amides of phosphoric acid, phosphonic acid, phosphorous acid, phosphinic acid, phosphonous acid, phosphinous acid, phosphorus(V) sulfide, phosphorus tribromide, phosphorus trichloride and phosphorus triiodide.

8. The process of claim 1 , wherein component K is selected from at least one compound selected from the group consisting of phosphoric acid, mono-, di- or trialkyl esters of phosphoric acid, mono-, di- or triaryl esters of phosphoric acid, mono-, di- or trialkaryl esters of phosphoric acid, (NH 4 ) 2 HPO 4 , phosphonic acid, mono- or dialkyl esters of phosphonic acid, mono- or diaryl esters of phosphonic acid, mono- or dialkaryl esters of phosphonic acid, phosphorous acid, mono-, di- or trialkyl esters of phosphorous acid, mono-, di- or triaryl esters of phosphorous acid, mono-, di- or trialkaryl esters of phosphorous acid, phosphinic acid, phosphonous acid and phosphinous acid.

9. The process of claim 1 , wherein component K is at least one compound selected from the group consisting of phosphoric acid, dibutyl phosphate, triethyl phosphate, phosphonic acid and (NH 4 ) 2 HPO 4 .

10. The process of claim 1 , wherein the polyether carbonate polyol corresponds to formula (Ia)

wherein the ratio of e:f is from 2:1 to 1:20.

Assignees

• Covestro Deutschland Ag

Inventors

• Laemmerhold Kai
• Hofmann Jorg
• Nefzger Hartmut

Classifications

• C08G64/305

  and alcohols · CPC title

• C08G18/244

  tin salts of carboxylic acids · CPC title

• Y02P20/582

  Recycling of unreacted starting or intermediate materials · CPC title

• C08G18/1833

  having ether, acetal, or orthoester groups · CPC title

• C08G64/42 Primary

  Chemical after-treatment · CPC title