Resin composition, and pre-preg, metal-clad laminate and printed circuit board prepared using the same

Patent metadata

Field	Value
Publication number	US-11339258-B2
Application number	US-201816009266-A
Country	US
Kind code	B2
Filing date	Jun 15, 2018
Priority date	Jan 3, 2018
Publication date	May 24, 2022
Grant date	May 24, 2022

Abstract

A resin composition is provided. The resin composition comprises the following components:(A) a halogen-free epoxy resin;(B) a hardener; and(C) a phosphorus-containing phenolic resin of the following formula (I):wherein m, n, l, R1, and R2 are as defined in the specification.

First claim

What is claimed is:

1. A resin composition, comprising:
(A) a halogen-free epoxy resin;
(B) a hardener; and
(C) a phosphorus-containing phenolic resin of formula (I):

in formula (I),
n is 0, m is 0, and l is an integer of 1 to 10; and
R 1 and R 2 are independently a residue of 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO), a residue of DOPO's derivative, a residue of amino triazine novolac (ATN) resin, or —O(CH 2 ) 3 CH 3 , with the proviso that at least one of R 1 and R 2 is a residue of DOPO or a residue of DOPO's derivative,
wherein the weight ratio of the hardener (B) to the phosphorus-containing phenolic resin (C) is from about 0.2:1 to about 0.9:1, and
wherein based on 100 parts by weight of the halogen-free epoxy resin (A), the amount of the hardener (B) is about 9 parts by weight to about 52 parts by weight and the amount of the phosphorus-containing phenolic resin (C) is about 19 parts by weight to about 50 parts by weight.

2. The resin composition of claim 1 , wherein in formula (I), R 1 and R 2 are independently a residue of DOPO, a residue of

or —O(CH 2 ) 3 CH 3 , with the proviso that at least one of R 1 and R 2 is a residue of DOPO.

3. The resin composition of claim 2 , further comprising a co-hardener selected from the group consisting of dicyandiamide (DICY), cyanate ester resin, phenolic resin (PN) other than the phosphorus-containing phenolic resin (C), diaminodiphenylmethane, poly(styrene-co-vinyl phenol), and combinations thereof.

4. The resin composition of claim 2 , further comprising a core/shell rubber.

5. The resin composition of claim 1 , wherein the hardener is selected from the group consisting of diaminodiphenyl sulfone (DDS), amino triazine novolac resin (ATN), bismaleimide resin (BMI), polyfunctional maleimide resin, styrene maleic anhydride (SMA), benzoxazine resin, and combinations thereof.

6. The resin composition of claim 5 , further comprising a co-hardener selected from the group consisting of dicyandiamide (DICY), cyanate ester resin, phenolic resin (PN) other than the phosphorus-containing phenolic resin (C), diaminodiphenylmethane, poly(styrene-co-vinyl phenol), and combinations thereof.

7. The resin composition of claim 5 , further comprising a core/shell rubber.

8. The resin composition of claim 1 , wherein the weight ratio of the hardener (B) to the phosphorus-containing phenolic resin (C) is from about 0.3:1 to about 0.9:1.

9. The resin composition of claim 1 , further comprising a co-hardener selected from the group consisting of dicyandiamide (DICY), cyanate ester resin, phenolic resin (PN) other than the phosphorus-containing phenolic resin (C), diaminodiphenylmethane, poly(styrene-co-vinyl phenol), and combinations thereof.

10. The resin composition of claim 1 , further comprising a core/shell rubber.

11. The resin composition of claim 1 , further comprising a component selected from the group consisting of a filler, a flame retardant, a catalyst, a dispersant agent, a toughener, and combinations thereof.

12. The resin composition of claim 11 , wherein the filler is selected from the group consisting of silicon dioxide, aluminum oxide, magnesium oxide, magnesium hydroxide, calcium carbonate, talc, clay, aluminum nitride, boron nitride, aluminum hydroxide, silicon aluminum carbide, silicon carbide, sodium carbonate, titanium dioxide, zinc oxide, zirconium oxide, quartzes, diamonds, diamond-like, graphite, calcined kaolin, pryan, mica, hydrotalcite, polytetrafluoroethylene (PTFE) powders, glass beads, ceramic whiskers, carbon nanotubes, nanosized inorganic powders, and combinations thereof.

13. A prepreg, which is prepared by impregnating a substrate with the resin composition of claim 1 or by coating the resin composition of claim 1 onto a substrate and drying the impregnated or coated substrate.

14. A metal-clad laminate, which is prepared by laminating the prepreg of claim 13 and a metal foil.

15. A printed circuit board, which is prepared from the metal-clad laminate of claim 14 .

16. A metal-clad laminate, which is prepared by coating the resin composition of claim 1 onto a metal foil and drying the coated metal foil.

17. A printed circuit board, which is prepared from the metal-clad laminate of claim 16 .

Assignees

• Taiwan Union Technology Corp

Inventors

• Liao Chih-Wei
• Tseng Guan-Syun
• Lin Tsung-Hsien
• Huang Ju-Ming
• Yu Chen-Hua

Classifications

• C09D163/00 Primary

  Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins · CPC title

• C08J5/249

  characterised by the additives used in the prepolymer mixture · CPC title

• C08J5/244

  using glass fibres · CPC title

• C09D5/18 Primary

  Fireproof paints {including high temperature resistant paints} · CPC title

• H05K2201/0227

  Insulating particles having an insulating coating · CPC title