Electrochemical reduction of carbon dioxide to upgrade hydrocarbon feedstocks

Patent metadata

Field	Value
Publication number	US-11339109-B2
Application number	US-202117158237-A
Country	US
Kind code	B2
Filing date	Jan 26, 2021
Priority date	Dec 6, 2019
Publication date	May 24, 2022
Grant date	May 24, 2022

Abstract

A system and method with a solid oxide electrolysis cell (SOEC), including feeding carbon dioxide and an olefin to the SOEC and discharging carbon monoxide and an olefin oxide from the SOEC, wherein the olefin oxide corresponds to the olefin.

First claim

What is claimed is:

1. A method of operating a system having a solid oxide electrolysis cell (SOEC), comprising:
feeding carbon dioxide and an olefin to the SOEC;
electrochemically reducing the carbon dioxide at a cathode of the SOEC into carbon monoxide, wherein electrochemically reducing the carbon dioxide generates oxygen ions;
diffusing the oxygen ions through a solid electrolyte of the SOEC to an anode of the SOEC; and
oxidizing the olefin at the anode into an olefin oxide via the oxygen ions at an operating temperature in a range of 500° C. to 950° C., wherein the olefin oxide corresponds to the olefin.

2. The method of claim 1 , comprising discharging carbon monoxide from the SOEC, wherein the operating temperature is in a range of 700° C. to 900° C.

3. The method of claim 1 , comprising modulating an amount of the olefin fed to the SOEC.

4. The method of claim 1 , comprising supplying electric current to the cathode.

5. The method of claim 4 , comprising modulating an amount of the electric current supplied to the cathode.

6. The method of claim 1 , comprising:
feeding water (H 2 O) to the SOEC;
electrochemically reducing the water at the cathode into hydrogen (H 2 ), wherein electrochemically reducing the water generates oxygen ions; and
discharging the hydrogen from the SOEC.

7. The method of claim 1 , comprising discharging the olefin oxide from the SOEC, wherein an adequate number of oxygen ions are generated at the cathode for oxidizing the olefin fed to the SOEC, wherein oxidizing the olefin at the anode comprises utilizing one oxygen ion of the oxygen ions generated at the cathode per olefin molecule of the olefin fed to the SOEC and converted into the olefin oxide discharged from the SOEC.

8. The method of claim 7 , comprising:
discharging the olefin oxide from the SOEC; and
converting the olefin oxide via a catalytic reactor into at least one of acrylic acid, an alcohol, an ether, or an ester, wherein discharging the olefin oxide from the SOEC comprises discharging the olefin oxide to the catalytic reactor.

9. The method of claim 8 , wherein the catalytic reactor comprises a series of catalytic reactors, and wherein the olefin oxide is converted into acrylic acid.

10. The method of claim 9 , and wherein converting the olefin oxide comprises converting the olefin oxide via the catalytic reactor into the acrylic acid, and wherein the olefin oxide comprises ethylene oxide.

11. A method of operating a system having a solid oxide electrolysis cell (SOEC), comprising:
receiving electric current at a cathode of the SOEC;
electrochemically reducing carbon dioxide at the cathode via electrons of the electric current to generate carbon monoxide and oxygen ions;
diffusing the oxygen ions through a solid electrolyte comprising a solid oxide to an anode of the SOEC; and
oxidizing an olefin at the anode via the oxygen ions into an olefin oxide at an operating temperature in a range of 500° C. to 950° C.

12. The method of claim 11 , comprising providing the carbon dioxide and the olefin to the SOEC, wherein the operating temperature of the SOEC is in a range of 700° C. to 900° C., and wherein oxidizing the olefin at the anode into the olefin oxide comprises utilizing one oxygen ion of the oxygen ions generated at the cathode per olefin molecule of the olefin provided to the SOEC.

13. The method of claim 12 , wherein providing the carbon dioxide to the SOEC comprises providing the carbon dioxide to a cathode side of the SOEC.

14. The method of claim 12 , wherein providing the olefin to the SOEC comprises providing the olefin to an anode side of the SOEC.

15. The method of claim 12 , comprising modulating an amount of the olefin provided to the SOEC.

16. The method of claim 11 , comprising electrochemically reducing water at the cathode via electrons of the electric current to generate hydrogen and oxygen ions.

17. The method of claim 11 , comprising discharging the olefin oxide from an anode side of the SOEC to a catalytic reactor and converting the olefin oxide via the catalytic reactor into acrylic acid.

18. The method of claim 17 , wherein the olefin comprises ethylene, and wherein the olefin oxide comprises ethylene oxide.

19. The method of claim 17 , wherein the catalytic reactor comprises a first reactor in a series of catalytic reactors.

20. The method of claim 17 , wherein the catalytic reactor comprises a series of catalytic reactors.

Assignees

• Saudi Arabian Oil Co

Inventors

• Hammad Ahmad D
• Fadhel Bandar A
• Amr Issam T
• Al Sadat Wajdi Issam

Classifications

• C25B3/23

  Oxidation (halogenation C25B3/27) · CPC title

• C25B1/23 Primary

  Carbon monoxide or syngas · CPC title

• C07C51/12 Primary

  on an oxygen-containing group in organic compounds, e.g. alcohols · CPC title

• C25B15/081

  Supplying products to non-electrochemical reactors that are combined with the electrochemical cell, e.g. Sabatier reactor · CPC title

• C25B13/07

  based on ceramics · CPC title