Neutral color antireflective glass substrate and method for manufacturing the same

Patent metadata

Field	Value
Publication number	US-11339089-B2
Application number	US-201716092395-A
Country	US
Kind code	B2
Filing date	Mar 13, 2017
Priority date	Apr 12, 2016
Publication date	May 24, 2022
Grant date	May 24, 2022

Abstract

A method for manufacturing neutral color antireflective glass substrates by ion implantation, the method including ionizing a N 2 source gas so as to form a mixture of single charge and multicharge ions of N, forming a beam of single charge and multicharge ions of N by accelerating with an acceleration voltage A between 20 kV and 25 kV and setting the ion dosage at a value between 6×10 16 ions/cm 2 and −5.00×10 15 ×A/kV+2.00×10 17 ions/cm 2 . A neutral color antireflective glass substrates including an area treated by ion implantation with a mixture of simple charge and multicharge ions according to the method.

First claim

The invention claimed is:

1. A method for producing a neutral color antireflective glass substrate, the method comprising:
a) providing a N2 source gas;
b) ionizing the N2 source gas so as to form a mixture of single charge ions and multicharge ions of N;
c) accelerating the mixture of single charge ions and multicharge ions of N with an acceleration voltage A so as to form a beam of single charge ions and multicharge ions, wherein the acceleration voltage A is comprised between 20 kV and 25 kV and an ion dosage D is comprised between 7.5×10 16 ions/cm 2 and −5.00×10 15 ×A/kV+2.00×10 17 ions/cm 2 ;
d) providing a glass substrate; and
e) positioning the glass substrate in a trajectory of the beam of single charge and multicharge ions of N,
wherein the glass substrate has a neutral color reflectance such that the reflectance is −1≤a*≤1 and −1≤b≤1 as measured under illuminant D65 using 10° observer angle on a side of the substrate that is treated as specified by the International Commission on Illumination after the mixture of single charge ions and multicharge ions of N has been implanted in the glass substrate.

2. The method for producing a neutral color antireflective glass substrate according to claim 1 , wherein the glass substrate comprises the following composition ranges expressed as weight percentage of the total weight of the glass:

SiO 2
35-85%, 

Al 2 O 3
0-30%,

P 2 O 5
0-20%,

B 2 O 3
0-20%,

Na 2 O
0-25%,

CaO
0-20%,

MgO
0-20%,

K 2 O
      0-20%, and

BaO
0-20%.

3. The method for producing a neutral color antireflective glass substrate according to claim 2 , wherein the glass substrate is selected from the group consisting of a soda-lime glass sheet, a borosilicate glass sheet and an aluminosilicate glass sheet.

4. A method, comprising employing a mixture of single charge and multicharge ions of N to decrease the reflectance of a glass substrate and at the same time keep a color in reflectance neutral, the mixture of single charge and multicharge ions being implanted in the glass substrate with an ion dosage D and an acceleration voltage A effective to reduce the reflectance of the glass substrate and at the same time keep the color in reflectance neutral,
wherein the acceleration voltage A is between 20 kV and 25 kV and the ion dosage D is between 7.5×10 16 ions/cm 2 and −5.00×10 15 ×A/kV+2.00×10 17 ions/cm 2 wherein the glass substrate has a neutral color in reflectance such that the reflectance is −1<a*<1 and −1<b*<1 as measured under illuminant D65 using 10° observer angle on a side of the substrate that is treated as specified by the International Commission on Illumination after the mixture of single charge ions and multicharge ions of N has been implanted in the glass substrate.

5. The method according to claim 4 , wherein the mixture of single charge and multicharge ions is being implanted in the glass substrate with an ion dosage and an acceleration voltage effective to reduce the reflectance of the glass substrate to at most 6.5%.

6. The method according to claim 5 , wherein the mixture of single charge and multicharge ions is being implanted in the glass substrate with an ion dosage and an acceleration voltage effective to reduce the reflectance of the glass substrate to at most 6.5% and at the same time keep the color in reflectance neutral such that −0.3≤a*≤0.3 and −0.3≤b*≤0.3.

7. The method of claim 1 , wherein said antireflective glass substrate is frosted, printed or screen process printed.

8. The method of claim 1 , wherein said substrate is tinted, tempered, reinforced, bent, folded or ultraviolet filtering.

9. The method for producing a neutral color antireflective glass substrate according to claim 3 , wherein the glass substrate is a soda-lime glass sheet.

10. The method for producing a neutral color antireflective glass substrate according to claim 1 , wherein the ions are implanted to an implantation depth of from 01. μm to 1 μm.

11. The method for producing a neutral color antireflective glass substrate according to claim 1 , wherein the glass substrate has a neutral color in reflectance such that −0.3≤a*≤0.3 and −0.3≤b*≤0.3 after the mixture of single charge ions and multicharge ions of N has been implanted in the glass substrate.

12. The method for producing a neutral color antireflective glass substrate according to claim 4 , wherein the glass substrate comprises the following composition ranges expressed as weight percentage of the total weight of the glass:

SiO 2
35-85%,

Al 2 O 2
 0-30%,

P 2 O 5
 0-20%,

B 2 O 3
 0-20%,

Na 2 O
 0-25%,

CaO
 0-20%,

MgO
 0-20%,

K 2 O
 0-20%, and

BaO
 0-20%.

13. The method for producing a neutral color antireflective glass substrate according to claim 12 , wherein the glass substrate is a soda-lime glass sheet.

14. The method for producing a neutral color antireflective glass substrate according to claim 4 , wherein the ions are implanted to an implantation depth of from 01. μm to 1 μm.

15. The method for producing a neutral color antireflective glass substrate according to claim 1 , wherein the acceleration voltage A is between 20 kV and 25 kV and the dosage D is between 8×10 16 ions/cm 2 and −5.00×10 15 ×A/kV+2.00×10 1

Assignees

• Agc Glass Europe
• Agc Glass Company North America
• Agc Inc
• Quertech Ingenierie

Inventors

• Navet Benjamine
• Boulanger Pierre
• Busardo Denis

Classifications

• C23C14/48

  Ion implantation · CPC title

• C03C23/0055 Primary

  by ion implantation · CPC title

• C03C3/097

  containing phosphorus, niobium or tantalum · CPC title

• C03C4/02

  for coloured glass · CPC title

• B32B2315/08

  Glass · CPC title