Rechargeable metal halide battery

Patent metadata

Field	Value
Publication number	US-11335908-B2
Application number	US-201916525642-A
Country	US
Kind code	B2
Filing date	Jul 30, 2019
Priority date	Jul 30, 2019
Publication date	May 17, 2022
Grant date	May 17, 2022

Abstract

A battery includes an anode, an electrolyte including a solvent and at least one ion conducting salt, and a cathode including a metal halide salt incorporated into an electrically conductive material. The electrolyte is in contact with the anode, the cathode, and an oxidizing gas.

First claim

What is claimed is:

1. A battery, comprising:
an anode;
an electrolyte comprising a solvent and at least one ion conducting salt; and
a cathode comprising a metal halide salt incorporated into an electrically conductive material, wherein the electrolyte is in contact with the anode, the cathode, and an oxidizing gas.

2. The battery of claim 1 , wherein the total amount of the metal halide salt in the cathode exceeds the amount of the metal halide salt that is dissolvable in the electrolyte.

3. The battery of claim 1 , wherein the total amount of the metal halide salt in the cathode is greater than twice the amount of the metal halide salt that is dissolvable in the electrolyte.

4. The battery of claim 1 , wherein the electrically conductive material comprises porous carbon selected from the group consisting of carbon black, carbon nanotubes, carbon nanofibers, activated carbon, amorphous carbon, graphite, graphene, and mixtures and combinations thereof.

5. The battery of claim 1 , wherein the electrically conductive material comprises a porous material, and the metal halide is incorporated into a plurality of pores of the porous material.

6. The battery of claim 5 , wherein the metal halide salt is interspersed within the electrically conductive material.

7. The battery of claim 5 , wherein the metal halide salt is adsorbed onto the electrically conductive material.

8. The battery of claim 1 , wherein the cathode comprises a halogen diatomic molecule selected from the group consisting of I2, Br2, Cl2, and F2.

9. The battery of claim 1 , wherein the cathode comprises a polymeric binder.

10. The battery of claim 9 , wherein the polymeric binder is selected from the group consisting of polytrifluoroethylene (PTFE), polyvinylidene fluoride (PVDF), and mixtures and combinations thereof.

11. The battery of claim 1 , further comprising a separator between the anode and the cathode.

12. The battery of claim 1 , wherein the oxidizing gas is selected from the group consisting of oxygen, air, nitric oxide, nitrogen dioxide, and mixtures and combinations thereof.

13. The battery of claim 1 , wherein the electrolyte is non-aqueous.

14. The battery of claim 1 , wherein the solvent in the electrolyte is selected from the group consisting of tetrahydrofuran, tetrahydropyran, tetrahydrothiophene, oxathiolane, oxolane, dioxolane, succinimide, oxazolidone, γ-butyrolactone, γ-caprolactone, ε-caprolactone, γ-valerolactone, pyrrolidine, imidazolidine, sulfolane, thiane, valeronitrile, nonanenitrile, hexanenitrile, acetonitrile, propionitrile, glutaronitrile, methoxyacetonitrile, methoxybenzonitrile, methoxypropionitrile, methylglutaronitrile, butoxypropionitrile, butoxybenzonitrile, and mixtures and combinations thereof.

15. The battery of claim 14 , wherein the solvent in the electrolyte comprises a heterocyclic compound selected from the group consisting of cyclic ethers, cyclic esters, and mixtures and combinations thereof.

16. The battery of claim 14 , wherein the solvent in the electrolyte comprises a nitrile compound.

17. The battery of claim 1 , wherein the ion conducting salt comprises (i) a metal ion selected from the group consisting of Li, Mg, Zn, Al and Na, and mixtures and combinations thereof and (ii) an anion selected from the group consisting of nitrate (NO3-), hexafluorophosphate (PF6-), tetrafluoroborate (BF4-), bisoxalato borate (BOB-), and difluorooxalato borate (DFOB-), trifluoromethanesulfonate (TF-), trifluorosulfonylimide (TFSI-), and mixtures and combinations thereof.

18. The battery of claim 1 , wherein the anode is made from a material selected from the group consisting of metals, metalloids, nonmetals and mixtures and combinations thereof.

19. The battery of claim 18 , wherein the anode is a metal selected from the group consisting of Li, Mg, Zn, Al, Na, and mixtures and combinations thereof.

20. The battery of claim 18 , wherein the anode is a metalloid selected from the group consisting of Si, Ge, Sb, and mixtures and combinations thereof.

21. The battery of claim 18 , wherein the nonmetal comprises carbon.

22. The battery of claim 1 , wherein the metal halide salt comprises (i) an ion of at least one of I, Br, Cl, and F, and (ii) the metal ion comprises an ion of at least one of Li, Mg, Zn, Al and Na.

23. The battery of claim 1 , further comprising an anode current collector contacting the anode, wherein the anode current collector is selected from the group consisting of copper, copper oxide, zinc, zinc oxide, nickel oxide, and mixtures and combinations thereof.

24. The battery of claim 1 , further comprising a cathode current collector contacting the cathode, wherein the cathode current collector is selected from the group consisting of aluminum, titanium, molybdenum, chromium, iron, nickel, stainless steel, and mixtures and combinations thereof.

Assignees

• IBM

Inventors

• Kim Jangwoo
• Na Young-Hye
• Allen Robert D

Classifications

• H01M4/136

  Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy · CPC title

• H01M2300/0028

  characterised by the solvent · CPC title

• H01M4/625

  Carbon or graphite · CPC title

• H01M10/0569

  characterised by the solvents · CPC title

• H01M4/582 Primary

  Halogenides · CPC title