Method for producing perfluoropolyether acyl fluoride
US-10508171-B2 · Dec 17, 2019 · US
US11326007B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11326007-B2 |
| Application number | US-201917267853-A |
| Country | US |
| Kind code | B2 |
| Filing date | Aug 27, 2019 |
| Priority date | Aug 30, 2018 |
| Publication date | May 10, 2022 |
| Grant date | May 10, 2022 |
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Described herein is method of making branched perfluorinated compounds, specifically (CF 3 ) 2 CFCF(CF 3 )OCF(CF 3 )C(═O)F and (CF 3 ) 2 CFCF(CF 3 )OCF═CF 2 . Also disclosed herein is a fluoropolymer derived from the branched perfluorovinyl ether monomer and methods of making the fluoropolymer.
Opening claim text (preview).
What is claimed is: 1. A fluoropolymer, wherein the fluoropolymer is derived from a composition comprising a vinyl ether compound of the formula (CF 3 ) 2 CFCF(CF 3 )OCF═CF 2 . 2. The fluoropolymer of claim 1 , wherein the fluoropolymer is further derived from a polymerizable fluorinated olefinic monomer. 3. The fluoropolymer of claim 2 , wherein the polymerizable fluorinated olefinic monomer comprises at least one of tetrafluoroethylene, hexafluoropropylene, vinyl fluoride, vinylidene fluoride, chlorotrifluoroethylene, fluorinated vinyl ether, fluorinated allyl ether, and combinations thereof. 4. The fluoropolymer of claim 1 , wherein the fluoropolymer has a viscosity of less than 10,000 poise as measured by a Brookfield viscometer in accordance with ASTM D 2196-05 at 80° C. 5. The fluoropolymer of claim 1 , wherein the fluoropolymer is perfluorinated. 6. The fluoropolymer of claim 1 , wherein the fluoropolymer is derived from less than 5 mole % of (CF 3 ) 2 CFCF(CF 3 )OCF═CF 2 versus the total moles of monomers used to derive the fluoropolymer. 7. The fluoropolymer of claim 1 , wherein the fluoropolymer is derived from at least 5, mole % (CF 3 ) 2 CFCF(CF 3 )OCF═CF 2 and at most 60 mole % of (CF 3 ) 2 CFCF(CF 3 )OCF═CF 2 versus the total moles of monomers used to derive the fluoropolymer. 8. The fluoropolymer of claim 1 , wherein the fluoropolymer is derived from at least 40 mole % (CF 3 ) 2 CFCF(CF 3 )OCF═CF 2 and at most 95 mole % of (CF 3 ) 2 CFCF(CF 3 )OCF═CF 2 versus the total moles of monomers used to derive the fluoropolymer. 9. The fluoropolymer of claim 1 , wherein the fluoropolymer is partially fluorinated.
containing halogen outside the carboxyl halide group · CPC title
containing halogen · CPC title
Preparation of carboxylic acid halides · CPC title
Monomers containing halogen · CPC title
with fluorinated vinyl ethers · CPC title
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