Processes for the production of ethylene oxide and ethylene glycol

Patent metadata

Field	Value
Publication number	US-11325877-B2
Application number	US-201816765647-A
Country	US
Kind code	B2
Filing date	Nov 20, 2018
Priority date	Nov 23, 2017
Publication date	May 10, 2022
Grant date	May 10, 2022

Abstract

A process for the recovery of ethylene glycol from an aqueous stream comprising ethylene glycol is disclosed. The process comprises (a) subjecting an aqueous stream 5 comprising ethylene glycol to an evaporation step in a multiple-effect evaporator to obtain a concentrated stream comprising ethylene glycol; (b) subjecting said concentrated stream comprising ethylene glycol to a first dehydration step in a first dehydrator 10 operating at an overhead pressure in the range of 0 barg (bar gauge) to 4 barg (bar gauge) to obtain a partially dehydrated ethylene glycol stream, and (c) subjecting said partially dehydrated ethylene glycol stream to a second dehydration step in a second dehydrator operating under 15 vacuum to obtain a dehydrated ethylene glycol stream.

First claim

That which is claimed is:

1. A process for the recovery of ethylene glycol from an aqueous stream comprising ethylene glycol, said process comprising
(a) subjecting said aqueous stream comprising ethylene glycol to an evaporation step in a multiple-effect evaporator to obtain a concentrated stream comprising ethylene glycol and a stream of collected condensates;
(b) subjecting said concentrated stream comprising ethylene glycol to a first dehydration step in a first dehydrator operating at an overhead pressure in the range of 0 barg (bar gauge) to 4 barg (bar gauge) to obtain a partially dehydrated ethylene glycol stream and a low pressure steam stream at a pressure in the range of 0 barg to 4 barg, and
(c) subjecting said partially dehydrated ethylene glycol stream to a second dehydration step in a second dehydrator operating under vacuum to obtain a dehydrated ethylene glycol stream,
wherein the collected condensates of the multiple-effect evaporator are flashed to produce flash steam and flash condensate, and wherein at least a portion of the flash condensate is recycled to an ethylene glycol reactor.

2. The process according to claim 1 , wherein said aqueous stream comprising ethylene glycol is produced by a process comprising manufacturing of ethylene oxide in an ethylene oxide section and hydrolysis of ethylene oxide in an ethylene glycol section, and wherein the ethylene oxide section or the ethylene glycol section comprise one or more low-pressure steam consumers and using at least a portion of the low pressure steam produced in the first dehydrator to drive the one or more low-pressure steam consumers in the ethylene oxide section or the ethylene glycol section.

3. The process according to claim 2 , wherein said low-pressure steam consumers comprise one or more chilling units.

4. The process according to claim 1 , wherein the multiple-effect evaporation step is performed in 2 to 6 stages.

5. The process according to claim 1 , wherein the first dehydrator is operated at a pressure in the range of 0.3-3 barg.

6. The process according to claim 1 , wherein the vaporous overhead from the last evaporator vessel in the multiple-effect evaporator is used as process steam, and wherein at least a portion of said process steam is used to provide heat to the first dehydrator.

7. The process according to claim 2 , wherein at least a portion of the condensate of the one or more low-pressure steam consumers is used to supply reflux to the first dehydrator.

8. The process according to claim 2 , wherein the ethylene oxide section comprises an ethylene oxide (EO) stripper, wherein said ethylene oxide stripper contains a first and an additional, second reboiler, and wherein heat is supplied to said second ethylene oxide stripper reboiler by low-pressure steam generated in a monoethylene glycol (MEG) purification column overhead condenser.

9. The process according to claim 2 , wherein the ethylene oxide section comprises an ethylene oxide stripper to which fat absorbent is supplied, and wherein one or more external process stream feeds are provided to the ethylene oxide stripper at a location above the fat absorbent feed.

10. The process according to claim 9 , wherein at least a portion of the fat absorbent stream from an ethylene oxide absorber bottom is used as the external process stream feed.

11. The process according to claim 9 , wherein the ethylene oxide section comprises a residual ethylene oxide absorber, wherein at least a portion of the fat absorbent stream from the residual absorber bottom is used as the external process stream feed.

12. The process according to claim 2 , wherein the ethylene oxide section comprises a residual ethylene oxide absorber, wherein at least a portion of the fat absorbent stream from an ethylene oxide absorber bottom is provided above the point where a feed comprising ethylene oxide is provided to said residual ethylene oxide absorber.

Assignees

• Shell Oil Co
• Shell Usa Inc

Inventors

• Bajaj Ram Paul
• Molenaar Peter

Classifications

• C07C29/80

  by distillation · CPC title

• C07C29/74 Primary

  Separation; Purification; Use of additives, e.g. for stabilisation · CPC title

• C07C29/78 Primary

  by condensation or crystallisation · CPC title

• C07C29/76 Primary

  by physical treatment · CPC title

• C07C31/202

  Ethylene glycol · CPC title