Divalent cation removal from rich monoethylene glycol (MEG) feed streams by ion exchange

Patent metadata

Field	Value
Publication number	US-9433875-B2
Application number	US-201213593734-A
Country	US
Kind code	B2
Filing date	Aug 24, 2012
Priority date	Aug 24, 2012
Publication date	Sep 6, 2016
Grant date	Sep 6, 2016

Abstract

A system and process for removing divalent cations from a rich MEG feed stream is presented. An ion exchange bed containing a cation exchange resin adsorbs the divalent cations in the rich MEG feed stream as it flows through the ion exchange bed. After the divalent ions have been removed, the feed stream flows through a flash separator and a distillation column to reclaim MEG. Alternatively, the feed stream flows through a distillation column to regenerate MEG. The spent cation exchange resin may be regenerated in place using a regeneration brine comprised of sodium chloride and water. After use, the regeneration brine may be disposed as waste or recycled to the brine storage tank and re-used to regenerate the cation exchange resin.

First claim

What is claimed is:

1. A process for removing divalent cations from a rich MEG feed stream, the process comprising the steps of:
passing the rich MEG feed stream through an ion exchange bed containing a cation exchange resin where the divalent cations are adsorbed by the cation exchange resin;
passing the rich MEG feed stream from the ion exchange bed through a flash separator which separates the feed stream into sodium chloride and water/MEG vapor; and
passing the water/MEG vapor from the flash separator through a distillation column which separates the water/MEG vapor into distilled water and lean MEG.

2. A process according to claim 1 further comprising the step of regenerating the cation exchange resin by passing a regeneration brine through the ion exchange bed in a direction opposite that of the rich MEG feed stream.

3. A process according to claim 2 wherein the regeneration brine is held in a brine storage tank before it flows through the ion exchange bed.

4. A process according to claim 1 wherein the regeneration brine is comprised of sodium chloride produced as the rich MEG feed stream is treated in the flash separator.

5. A process according to claim 1 wherein the regeneration brine is comprised of water produced as the rich MEG feed stream is treated in the distillation column.

6. A process according to claim 3 further comprising the step of routing the regeneration brine to the brine storage tank after it has flowed through the ion exchange bed and re-using it to regenerate the cation exchange resin.

Assignees

• Phelps Daniel W
• Fernandez Luis Eduardo Caires
• Cameron Int Corp

Inventors

• Phelps Daniel W
• Fernandez Luis Eduardo Caires

Classifications

• B01D15/00 Primary

  Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor · CPC title

• C07C29/80 Primary

  by distillation · CPC title

• C07C29/74

  Separation; Purification; Use of additives, e.g. for stabilisation · CPC title

• B01D15/362 Primary

  Cation-exchange · CPC title

• B01D15/36

  involving ionic interaction, e.g. ion-exchange, ion-pair, ion-suppression or ion-exclusion · CPC title