Separating agent
US-2015343420-A1 · Dec 3, 2015 · US
US11325100B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11325100-B2 |
| Application number | US-201816178488-A |
| Country | US |
| Kind code | B2 |
| Filing date | Nov 1, 2018 |
| Priority date | Nov 6, 2017 |
| Publication date | May 10, 2022 |
| Grant date | May 10, 2022 |
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Official abstract text for this publication.
The invention relates to strong hydrogen-bond acidic sorbents. The sorbents may be provided in a form that limits or eliminates intramolecular bonding of the hydrogen-bond acidic site between neighboring sorbent molecules, for example, by providing steric groups adjacent to the hydrogen-bond acidic site. The hydrogen bond site may be a phenolic structure based on a bisphenol architecture. The sorbents of the invention may be used in methods for trapping or detecting hazardous chemicals or explosives.
Opening claim text (preview).
What is claimed: 1. A bisphenol sorbent comprising a compound selected from the group consisting of 2. A bisphenol sorbent comprising a compound of formula II where R 1 is selected from the group consisting of prop-1-en-2-yl; dimethyl(phenyl)silyl; trimethylsilyl; diphenylmethyl; methylthio; prop-2-enyl; benzyl; ethylthio; cyclopropyl; 2-(trimethylsilyl)ethyl; 2,2-dimethylpropyl; 2-methylpropyl; phenylethyl; propyl; butyl; sec-butyl; pentyl; heptyl; propan-2-yl; cyclopentyl; cyclohexyl; cyclobutyl; 3-ethylpentan-3-yl; ethyl; 1,1-dimethylpropyl; (trimethylsilyl)methyl; trifluoromethyl; and fluoro; and R 2 is selected from the group consisting of hydrogen, methyl; tert-butyl; prop-1-en-2-yl; dimethyl(phenyl)silyl; trimethylsilyl; diphenylmethyl; methylthio; prop-2-enyl; benzyl; ethylthio; cyclopropyl; 2-(trimethylsilyl)ethyl; 2,2-dimethylpropyl; 2-methylpropyl; phenylethyl; propyl; butyl; sec-butyl; pentyl; heptyl; propan-2-yl; cyclopentyl; cyclohexyl; cyclobutyl; 3-ethylpentan-3-yl; ethyl; 1,1-dimethylpropyl; (trimethylsilyl)methyl; trifluoromethyl; and fluoro. 3. The bisphenol sorbent of claim 2 , where the sorbent is selected from the group consisting of
Phases chemically bonded to a substrate, e.g. to silica or to polymers · CPC title
derived from phenols · CPC title
Polycondensates containing more than one epoxy group per molecule (low-molecular-weight polyepoxy compounds C07); Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups · CPC title
containing halogens · CPC title
Sorbents specially adapted for preparative, analytical or investigative chromatography · CPC title
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