Methods for fabricating silicon-based electrodes comprising naturally occurring carbonaceous filaments and battery cells utilizing the same

Patent metadata

Field	Value
Publication number	US-11316142-B2
Application number	US-201916572789-A
Country	US
Kind code	B2
Filing date	Sep 17, 2019
Priority date	Sep 17, 2019
Publication date	Apr 26, 2022
Grant date	Apr 26, 2022

Abstract

Methods for fabricating electrodes include coating a current collector with a slurry to form a coated current collector. The slurry includes a dry fraction, including silicon particles, polymeric binders, and one or more types of naturally occurring carbonaceous filaments, and one or more solvents. The coated current collector is heat treated to produce the electrode having a layer of silicon-based host material. The one or more naturally occurring carbonaceous filaments can include animal fibers, chitin, alginate, cellulose, keratin, and chitosan, and can have an average length of 1 μm to 50 μm and an average diameter of 1 nm to 500 nm. The dry fraction can include 5 wt. % to 95 wt. % silicon particles, 0.1 wt. % to 15 wt. % polymeric binders, and 1 wt. % to 20 wt. % naturally occurring carbonaceous filaments. The method can include assembling a battery cell by disposing the electrode and a positive electrode in electrolyte.

First claim

What is claimed is:

1. A method for fabricating an electrode, the method comprising:
coating a current collector with a slurry to form a coated current collector, wherein the slurry includes:
a dry fraction comprising:
silicon particles,
one or more polymeric binders,
one or more types of naturally occurring carbonaceous filaments,
one or more solvents, and
one or more synthetic carbonaceous filaments, wherein the one or more synthetic carbonaceous filaments include nylon, modacrylic, olefin, acrylic, polyester, rayon, vinyon, polyethylene, polyether-polyurea copolymers, vinalon, aramids, polybenzimidazole, polyhydroquinone-diimidazopyridine, thermoset liquid-crystalline polyoxazoles, aromatic polyesters, and derclon; and

heat treating the coated current collector to produce the electrode comprising an electroactive material layer comprising a silicon-based host material on the current collector.

2. The method of claim 1 , wherein the one or more naturally occurring carbonaceous filaments comprise animal fibers, chitin, alginate, cellulose, keratin, and chitosan.

3. The method of claim 1 , wherein the one or more naturally occurring carbonaceous filaments are selected from the group consisting of animal fibers, chitin, alginate, cellulose, keratin, and chitosan.

4. The method of claim 1 , wherein the one or more naturally occurring carbonaceous filaments comprises an average length of about 1 μm to about 50 μm and an average diameter of about 1 nm to about 500 nm.

5. The method of claim 1 , wherein the carbon present in the silicon-based host material consists of carbon derived from the one or more polymeric binders and the one or more naturally occurring carbonaceous filaments, and optionally carbon contributed from the current collector.

6. The method of claim 1 , wherein the dry fraction further comprises conductive carbon.

7. The method of claim 6 , wherein the dry fraction comprises up to about 10 wt. % conductive carbon.

8. The method of claim 1 , wherein the dry fraction comprises about 5 wt. % to about 95 wt. % silicon particles, about 0.1 wt. % to about 15 wt. % polymeric binders, and about 1 wt. % to about 20 wt. % naturally occurring carbonaceous filaments.

9. The method of claim 1 , wherein heat treating comprises heating the coated current collector to a temperature between about 250° C. to about 1200° C.

10. The method of claim 9 , wherein heat treating occurs in an atmosphere substantially free of oxygenated gases.

11. A method for fabricating a battery cell, the method comprising:
coating a current collector with a slurry to form a coated current collector, wherein the slurry includes:
a dry fraction comprising:
silicon particles,
one or more polymeric binders,
one or more types of naturally occurring carbonaceous filaments, wherein the one or more naturally occurring carbonaceous filaments comprises an average length of about 1 μm to about 50 μm and an average diameter of about 1 nm to about 500 nm,
one or more solvents, and
one or more synthetic carbonaceous filaments, wherein the one or more synthetic carbonaceous filaments include nylon, modacrylic, olefin, acrylic, polyester, rayon, vinyon, polyethylene, polyether-polyurea copolymers, vinalon, aramids, polybenzimidazole, polyhydroquinone-diimidazopyridine, thermoset liquid-crystalline polyoxazoles, aromatic polyesters, and derclon; and

heat treating the coated current collector in an atmosphere substantially free of oxygenated gases to produce a negative electrode comprising an electroactive material layer comprising a silicon-based host material on the current collector; and
subsequently assembling the battery cell by disposing the negative electrode and a positive electrode in an electrolyte.

12. The method of claim 11 , wherein the thickness of the electroactive material layer is about 20 μm to about 50 μm.

13. The method of claim 11 , wherein the one or more naturally occurring carbonaceous filaments comprise animal fibers, chitin, alginate, cellulose, keratin, and chitosan.

14. The method of claim 11 , wherein the one or more naturally occurring carbonaceous filaments are selected from the group consisting of animal fibers, chitin, alginate, cellulose, keratin, and chitosan.

15. The method of claim 11 , wherein the carbon present in the silicon-based host material consists of carbon derived from the one or more polymeric binders and the one or more naturally occurring carbonaceous filaments, and optionally carbon contributed from the current collector.

16. The method of claim 11 , wherein the dry fraction comprises about 5 wt. % to about 95 wt. % silicon particles, about 0.1 wt. % to about 15 wt. % polymeric binders, about 1 wt. % to about 20 wt. % naturally occurring carbonaceous filaments.

17. The method of claim 11 , wherein the dry fraction further comprises up to about 10 wt. % conductive carbon.

Assignees

• Gm Global Tech Operations Llc

Inventors

• Jiang Meng
• K Raghunathan
• Halalay Ion C
• Verbrugge Mark W

Classifications

• H01M4/1395

  of electrodes based on metals, Si or alloys · CPC title

• H01M4/622

  being polymers · CPC title

• H01M4/0404 Primary

  by coating on electrode collectors · CPC title

• H01M4/386

  Silicon or alloys based on silicon · CPC title

• H01M4/134 Primary

  Electrodes based on metals, Si or alloys · CPC title