Silicon particles for battery electrodes

Patent metadata

Field	Value
Publication number	US-9553303-B2
Application number	US-201313799405-A
Country	US
Kind code	B2
Filing date	Mar 13, 2013
Priority date	Jan 18, 2010
Publication date	Jan 24, 2017
Grant date	Jan 24, 2017

Abstract

Silicon particles for active materials and electro-chemical cells are provided. The active materials comprising silicon particles described herein can be utilized as an electrode material for a battery. In certain embodiments, the composite material includes greater than 0% and less than about 90% by weight of silicon particles. The silicon particles have an average particle size between about 0.1 μm and about 30 μm and a surface including nanometer-sized features. The composite material also includes greater than 0% and less than about 90% by weight of one or more types of carbon phases. At least one of the one or more types of carbon phases is a substantially continuous phase.

First claim

What is claimed is:

1. A method of forming a composite material, the method comprising:
providing a byproduct of a Fluidized Bed Reactor, wherein the byproduct comprises a plurality of silicon particles having an average particle size between about 0.1 μm and about 30 μm and a surface comprising nanometer-sized features;
forming a mixture comprising a precursor and the plurality of silicon particles; and
pyrolysing the precursor to convert the precursor into one or more types of carbon phases to form the composite material, wherein the one or more types of carbon phases is a substantially continuous phase comprising hard carbon and holding the composite material together.

2. The method of claim 1 , wherein providing the byproduct comprises:
providing silicon material; and
synthesizing the silicon material to form the plurality of silicon particles comprising an average particle size between about 0.1 μm and about 30 μm and a surface comprising the nanometer-sized features.

3. The method of claim 2 , wherein synthesizing the silicon material comprises growing metal silicon on a surface of the silicon material.

4. The method of claim 3 , wherein the silicon particles exit a top of the Fluidized Bed Reactor or deposit on a wall of the Fluidized Bed Reactor.

5. The method of claim 2 , wherein the silicon material is a plurality of granular silicon.

6. The method of claim 1 , wherein the byproduct comprises metal silicon grown on the surface of the silicon particles.

7. The method of claim 1 , wherein the silicon particles exited a top of the Fluidized Bed Reactor or deposited on a wall of the Fluidized Bed Reactor.

8. The method of claim 1 , wherein the composite material comprises:
greater than 0% and less than about 90% by weight of the silicon particles; and
greater than 0% and less than about 90% by weight of the one or more types of carbon phases.

9. The method of claim 1 , wherein the features comprise silicon.

10. The method of claim 1 , wherein the nanometer-sized features comprise an average feature size between about 1 nm and about 1 μm.

11. The method of claim 1 , wherein the average particle size of the silicon particles is between about 1μm and about 20 μm.

12. The method of claim 11 , wherein the average particle size of the silicon particles is between about 5 μm and about 20 μm.

13. The method of claim 11 , wherein the average particle size of the silicon particles is between about 1 μm and about 10 μm.

14. The method of claim 1 , wherein the average particle size of the silicon particles is between about 0.5 μm and about 2 μm.

15. The method of claim 1 , wherein the silicon particles further comprise an average surface area per unit mass between about 1 m 2 /g and about 30 m 2 /g.

16. The method of claim 1 , wherein the silicon particles further comprise a purity of above 99.9999%.

17. The method of claim 1 , further comprising forming a battery electrode from the composite material.

18. The method of claim 17 , wherein the electrode is an anode.

Assignees

• Enevate Corp

Inventors

• Park Benjamin Yong
• Teixidor Genis Turon
• Houghton Heidi L
• Browne Ian R

Classifications

• C04B2235/87

  Grain boundary phases intentionally being absent · CPC title

• H01M4/0416

  involving impregnation with a solution, dispersion, paste or dry powder (H01M4/0438 takes precedence) · CPC title

• H01M2004/027

  Negative electrodes · CPC title

• C01B32/05

  Preparation or purification of carbon not covered by groups C01B32/15, C01B32/20, C01B32/25, C01B32/30 · CPC title

• C01B33/021

  Preparation (chemical coating from the vapour phase C23C16/00) · CPC title