Production method for dispersion liquid of silica particle

Patent metadata

Field	Value
Publication number	US-11312634-B2
Application number	US-201816498433-A
Country	US
Kind code	B2
Filing date	Mar 29, 2018
Priority date	Mar 31, 2017
Publication date	Apr 26, 2022
Grant date	Apr 26, 2022

Abstract

A method for producing a dispersion liquid of silica particles, by simultaneously adding a liquid A containing silane alkoxide and a liquid B containing an alkali catalyst and water to a liquid I containing silica seed particles to cause the particles to grow, so as to produce silica particles; wherein the variation rate of the mole ratio of the alkali catalyst to silica components in the reaction system during a period from the start to the end of the addition relative to the initial mole ratio is 0.90 to 1.10; and the variation rate of the mole ratio of water to the silica components in the reaction system during a period from the start to the end of the addition relative to the initial mole ratio is 0.90 to 1.10.

First claim

The invention claimed is:

1. A method for producing a dispersion liquid of silica particles, comprising:
providing a liquid I containing silica seed particles having an average particle diameter of 3 to 100 nm in a container; and
simultaneously adding a liquid A containing silane alkoxide and a liquid B containing an alkali catalyst and water to the liquid I to grow the silica seed particles, so as to produce silica particles;
wherein a variation rate of a mole ratio of the alkali catalyst to silica components in a reaction system during a period from a start to an end of an addition relative to the initial mole ratio of the alkali catalyst to the silica components is 0.90 to 1.10; and
wherein a variation rate of a mole ratio of the water to the silica components in the reaction system during the period from the start to the end of the addition relative to the initial mole ratio of the water to the silica components is 0.90 to 1.10;
wherein an addition amount of the silane alkoxide is 10% by mass or more per minute with respect to the silica seed particles in the liquid I in terms of SiO 2 .

2. The method for producing a dispersion liquid of silica particles according to claim 1 , wherein the silica seed particle concentration in the liquid I is 1% by mass or more.

3. The method for producing a dispersion liquid of silica particles according to claim 1 , wherein a content of incompletely reacted materials in the liquid I is 200 ppm or less.

4. The method for producing a dispersion liquid of silica particles according to claim 1 , wherein the silica particles produced are irregular-shaped silica particles in which two or more primary particles are linked to each other.

5. The method for producing a dispersion liquid of silica particles according to claim 1 , wherein the concentration of the silica particles in the reaction system at the end of the addition is 5% by mass or more.

6. The method for producing a dispersion liquid of silica particles according to claim 1 , wherein the concentration of the incompletely reacted materials in the reaction system at the end of the addition is 200 ppm or less.

7. The method for producing a dispersion liquid of silica. particles according to claim 1 , wherein during the period from the start to the end of the addition, the mole ratio of the alkali catalyst to the silica components in the reaction system is always 0.20 or more and the mole ratio of the water to the silica components in the reaction system is always 2.0 or more.

8. The method for producing a dispersion liquid of silica particles according to claim 1 , wherein the temperature of the reaction system is 0 to 65° C.

9. A method for producing a dispersion liquid of silica particles, comprising:
providing a liquid I containing silica seed particles having an average particle diameter of 3 to 100 nm, a sphericity of the silica seed particles is 0.80 to 1.00, and a variation coefficient (CV value) of particle diameter is 10% or less in a container; and simultaneously adding a liquid A containing silane alkoxide and a liquid B containing an alkali catalyst and water to the liquid I to grow the silica seed particles, so as to produce silica particles;
wherein a variation rate of a mole ratio of the alkali catalyst to silica components in a reaction system during a period from a start to an end of an addition relative to the initial mole ratio of the alkali catalyst to the silica components is 0.90 to 1.10; and
wherein a variation rate of a mole ratio of the water to the silica components in the reaction system during the period from the start to the end of the addition relative to the initial mole ratio of the water to the silica components is 0.90 to 1.10.

10. The method for producing a dispersion liquid of silica particles according to claim 9 , wherein the silica seed particle concentration in the liquid I is 1% by mass or more.

11. The method for producing a dispersion liquid of silica particles according to claim 9 , wherein a content of incompletely reacted materials in the liquid I is 200 ppm or less.

12. The method for producing a dispersion liquid of silica particles according to claim 9 , wherein the silica particles produced are irregular-shaped silica particles in which two or more primary particles are linked to each other.

13. The method for producing a dispersion liquid of silica particles according to claim 9 , wherein the concentration of the silica particles in the reaction system at the end of the addition is 5% by mass or more.

14. The method for producing a dispersion liquid of silica particles according to claim 9 , wherein the concentration of the incompletely reacted materials in the reaction system at the end of the addition is 200 ppm or less.

15. The method for producing a dispersion liquid of silica particles according to claim 9 , wherein during the period from the start to the end of the addition, the mole ratio of the alkali catalyst to the silica components in the reaction system is always 0.20 or more and the mole ratio of the water to the silica components in the reaction system is always 2.0 or more.

16. The method for producing a dispersion liquid of silica particles according to claim 9 , wherein the temperature of the reaction system is 0 to 65° C.

Assignees

• Jgc Catalysts & Chemicals Ltd

Inventors

• Egami Miki
• Kumazawa Mitsuaki
• Arakane Hirotada
• Muraguchi Ryo
• Hirai Toshiharu

Classifications

• H10P52/00

  Grinding, lapping or polishing of wafers, substrates or parts of devices · CPC title

• C09G1/02

  containing abrasives or grinding agents {(abrasives as such C09K3/14; polishing of semi-conductors H10P52/40)} · CPC title

• C01B33/141 Primary

  Preparation of hydrosols or aqueous dispersions · CPC title

• B24B37/00

  Lapping machines or devices; Accessories (B24B3/00 takes precedence) · CPC title

• C01P2004/32

  Spheres · CPC title