Cap for closing a sample container for microwave treatment and a method and sample assembly for performing microwave treatment

Patent metadata

Field	Value
Publication number	US-11305285-B2
Application number	US-201916508800-A
Country	US
Kind code	B2
Filing date	Jul 11, 2019
Priority date	Jul 20, 2018
Publication date	Apr 19, 2022
Grant date	Apr 19, 2022

Abstract

A cap closes a sample vessel for the microwave treatment of samples. The cap contains a closure body for closing the sample vessel. The closure body is fitted to the sample vessel and closes the sample vessel at a sealing surface. A spring-loaded pressure relief valve and a vent duct are provided. The vent duct, the pressure relief valve and the closure body are configured in such a manner that the vent duct connects the closure body via the pressure relief valve to the surrounding area such that when a defined first pressure level is exceeded at the closure body excess pressure can escape through the vent duct into the area surrounding the cap. A reservoir is provided. The reservoir and the vent duct are configured such that condensate precipitating in the vent duct accumulates in the reservoir when the cap is in the state fitted to the sample vessel.

First claim

The invention claimed is:

1. A cap for closing a sample vessel for a microwave treatment, the cap comprising:
a closure body for closing the sample vessel and having a sealing surface, said closure body being fitted to the sample vessel and closes the sample vessel by said sealing surface when the cap is in a state fitted to the sample vessel;
a spring-loaded pressure relief valve;
at least one vent duct, said vent duct, said spring-loaded pressure relief valve and said closure body are configured in such a manner that said vent duct connects said closure body via said spring-loaded pressure relief valve to a surrounding area in such a manner that when a defined first pressure level is exceeded at said closure body excess pressure can escape through said vent duct into the area surrounding the cap; and
a reservoir, wherein said reservoir and said vent duct are configured in such a manner that condensate precipitating in said vent duct accumulates in said reservoir when the cap is in the state fitted to the sample vessel.

2. The cap according to claim 1 , wherein said vent duct has a length of between 20 and 40 mm.

3. The cap according to claim 1 , wherein said vent duct has a plurality of partial ducts.

4. The cap according to claim 1 , wherein:
said closure body has a vent hole formed therein, said vent hole connecting an inside of the sample vessel to said spring-loaded pressure relief valve when the cap is in the state fitted to the sample vessel; and
said spring-loaded pressure relief valve has a spring-loaded sealing body which is configured in such a manner that said spring-loaded sealing body closes said vent hole when there is a defined sealing force applied by said spring-loaded pressure relief valve on said spring-loaded sealing body.

5. The cap according to claim 1 , wherein said reservoir in said closure body is formed by an annular catchment groove and said annular catchment groove is disposed concentrically to said vent hole.

6. The cap according to claim 3 , wherein the cap has a rotationally symmetrical design and said vent duct and/or said partial ducts are configured as cylindrical bores.

7. The cap according to claim 6 , wherein said partial ducts configured as said cylindrical bores are formed in an end face of the cap and connect said reservoir to the area surrounding of the cap, wherein said partial ducts run straight and are disposed distributed uniformly over said end face of the cap on a same radius.

8. The cap according to claim 1 , wherein:
said closure body has a lip seal or a conical seal; and
the sample vessel is sealed by said lip seal or said conical seal when the cap is in the state fitted to the sample vessel.

9. The cap according to claim 3 , wherein said vent duct has at least 8 said partial ducts and said partial ducts have a diameter of at least 3 mm.

10. The cap according to claim 3 , wherein said vent duct and/or said partial ducts have a total surface area of 8,000 mm 2 .

11. The cap according to claim 1 , further comprising a screw thread with which the cap can be screwed onto the sample vessel.

12. The cap according to claim 1 , wherein said vent duct has a length which at least corresponds to a condensation path of a gaseous fluid contained in an inside of the sample vessel, wherein the gaseous fluid is a vapor containing one of the following chemical compounds or mixtures thereof: HNO 3 , HCl, aqua regia, inverse aqua regia, H 2 SO 4 , HF, H 3 PO 4 , HClO 4 , H 2 O 2 , solvents or other fluids used for decomposition and/or synthesis of samples.

13. The cap according to claim 1 , wherein the cap is made of a material which is microwave-compatible and/or acid-resistant and/or solvent-resistant.

14. The cap according to claim 1 , wherein at least one of said closure body or the cap is configured in such a manner that between an inside of the sample vessel and said closure body, a thermal coupling can be produced when the cap is in the state fitted to the sample vessel.

15. The cap according to claim 1 , wherein at least one of said closure body or the cap has at least one secondary vent duct which is configured and disposed in such a manner that a region of said closure body behind said sealing surface is connected to the area surrounding the cap so that excess pressure existing behind said sealing surface can escape via said secondary vent duct into the surrounding area.

16. The cap according to claim 4 , wherein said closure body has a wall with a reinforcement for absorbing compressive forces in a region of said pressure relief valve, wherein said reinforcement has a rotationally symmetrical metallic material which is disposed concentrically about said vent hole.

17. A sample assembly, comprising:
a sample vessel;
a cap closing said sample vessel, said cap containing:
a closure body for closing said sample vessel and having a sealing surface, said closure body being fitted to said sample vessel and closes said sample vessel by said sealing surface when said cap is in a state fitted to said sample vessel;
a spring-loaded pressure relief valve;
at least one vent duct, said vent duct, said spring-loaded pressure relief valve and said closure body are configured in such a manner that said vent duct connects said closure body via said spring-loaded pressure relief valve to a surrounding area in such a manner that when a defined first pressure level is exceeded at said closure body excess pressure can escape through said vent duct into the area surrounding said cap; and
a reservoir, wherein said reservoir and said vent duct are configured in such a manner that condensate precipitating in said vent duct accumulates in said reservoir when said cap is in the state fitted to said sample vessel.

18. The sample assembly according to claim 17 , wherein at least one of said cap or said sample vessel are flexibly configured in such a manner that when a second pressure level is exceeded in said sample vessel, at least one of said cap or said sample vessel are elastically deformable in such a manner that said closure body of said cap lifts partially from said sample vessel and excess pressure escapes from an inside of a vessel interior via said vent duct into the surrounding area, wherein when it again drops below the pressure level in said vessel interior, said closure body closes said sample vessel once again.

19. The sample assembly according to claim 17 , wherein said sample assembly has a supporting structure, said supporting structure is configured in such a manner that said supporting structure absorbs forces acting along an axis of said cap, and wherein said cap can be pressed onto said sample vessel by said supporting structure.

Assignees

• Anton Paar Gmbh

Inventors

• Zentner Rainer

Classifications

• B01J3/03

  Pressure vessels, or vacuum vessels, having closure members or seals specially adapted therefor · CPC title

• B01L2300/0832

  cylindrical, tube shaped · CPC title

• B01L2300/042

  Caps; Plugs · CPC title

• B01L2200/0689

  Sealing · CPC title

• B01J3/04 Primary

  Pressure vessels, e.g. autoclaves · CPC title