Chemical reaction device and particle production method using chemical reaction device

Patent metadata

Field	Value
Publication number	US-11305243-B2
Application number	US-201716308062-A
Country	US
Kind code	B2
Filing date	Jun 12, 2017
Priority date	Jun 14, 2016
Publication date	Apr 19, 2022
Grant date	Apr 19, 2022

Abstract

A chemical reaction device that supplies a raw material liquid into a solution and causes particles to precipitate in the solution is provided. The chemical reaction device includes an agitation tank configured to accommodate the solution, an impeller configured to agitate the solution, and a plurality of discharge parts configured to discharge the raw material liquid into the solution.

First claim

The invention claimed is:

1. A particle production method that is performed with a chemical reaction device including an agitation tank; an impeller; a baffle protruding from an inner peripheral surface of the agitation tank; and a plurality of discharge parts disposed radially inward with respect to the baffle in top view, the particle production method comprising:
accommodating an aqueous solution in the agitation tank;
agitating, by the impeller, the solution in the agitation tank where the baffle is provided;
while discharging a raw material liquid including a nickel salt by the discharge parts into the solution, precipitating particles made of a nickel-containing hydroxide in the solution; and
in the precipitating the particles, forming a first highly supersaturated region where a molar concentration of the nickel-containing hydroxide dissolved in the aqueous solution is greater than or equal to 5.0 mol/m 3 near a discharge part of the plurality of discharge parts, a volume fraction of the first highly supersaturated region in the aqueous solution being less than 0.100%.

2. The particle production method according to claim 1 , wherein a distance between the plurality of discharge parts is set up so that a plurality of the first highly supersaturated regions that are formed near the plurality of discharge parts do not overlap with each other.

3. The particle production method according to claim 1 , wherein the plurality of discharge parts are set apart from one another on a bottom portion of the agitation tank and are configured to discharge the raw material liquid upward.

4. The particle production method according to claim 3 , wherein the plurality of discharge parts are disposed radially outward with respect to the impeller in top view.

5. A particle production method that is performed with a chemical reaction device including an agitation tank; an impeller; a baffle protruding from an inner peripheral surface of the agitation tank; and a plurality of discharge parts disposed radially inward with respect to the baffle in top view, the particle production method comprising:
accommodating an aqueous solution in the agitation tank;
agitating, by the impeller, the solution in the agitation tank where the baffle is provided;
while discharging a raw material liquid including a nickel salt by the discharge parts into the solution, precipitating particles made of a nickel-containing hydroxide in the solution;
in the precipitating the particles, forming a second highly supersaturated region where a molar concentration of the nickel-containing hydroxide dissolved in the reaction aqueous solution is greater than or equal to 1.7 mol/m 3 near a discharge part of the plurality of discharge parts, a volume fraction of the second highly supersaturated region in the aqueous solution being less than 0.624%.

6. The particle production method according to claim 5 , wherein a distance between the plurality of discharge parts is set up so that a plurality of the second highly supersaturated regions that are formed near the plurality of discharge parts do not overlap with each other.

Assignees

• Sumitomo Metal Mining Co

Inventors

• Nakakura Shuhei
• Tsuchioka Kazuhiko
• Maki Koichiro
• Saruwatari Motoaki
• Ryoshi Kazuomi
• Yoshida Masafumi

Classifications

• C01G53/82

  Compounds containing nickel, with or without oxygen or hydrogen, and containing two or more other elements · CPC title

• H01M4/505

  of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy · CPC title

• C01G53/42

  containing alkali metals, e.g. LiNiO2 · CPC title

• C01G53/00

  Compounds of nickel · CPC title

• B01F27/808

  with stirrers driven from the bottom of the receptacle · CPC title