Method for making spherical cobalt oxyhydroxide

Patent metadata

Field	Value
Publication number	US-2016167979-A1
Application number	US-201615053330-A
Country	US
Kind code	A1
Filing date	Feb 25, 2016
Priority date	Aug 27, 2013
Publication date	Jun 16, 2016
Grant date	—

Abstract

A method for making a spherical cobalt oxyhydroxide requires a controlled crystallization reactor. A buffer agent is put into the controlled crystallization reactor. The buffer agent is capable of controlling a reacting speed of reactants. A cobalt salt solution and an alkaline solution as the reactants are added into the buffer agent in the controlled crystallization reactor. The reactants react together in a controlled crystallization method, the reactants being agitated only at a bottom region of the container of the controlled crystallization reactor.

First claim

What is claimed is:

1 . A method for making a spherical cobalt oxyhydroxide comprising:
providing a controlled crystallization reactor; filling a buffer agent into the controlled crystallization reactor, wherein the buffer agent is capable of controlling a reacting speed of reactants; adding a cobalt salt solution and an alkaline solution as reactants into the buffer agent in the controlled crystallization reactor; reacting the reactants by using a controlled crystallization method while agitating the reactants only at a bottom region of a container of the controlled crystallization reactor.

2 . The method of claim 1 , wherein the bottom region is defined from the inner bottom of the container to a place having 1/10 to ⅓ depth of the container.

3 . The method of claim 1 , wherein the controlled crystallization reactor comprises the container, an agitating device, and a feeding device.

4 . The method of claim 3 , wherein the feeding device comprises a plurality of inlet tubes, the adding the cobalt salt solution and the alkaline solution is performed through respective inlet tubes.

5 . The method of claim 3 , the agitating device comprises a motor, a shaft, and at least one paddle, the shaft is connected to the motor, the at least one paddle is mounted only on an end of the shaft, the end of the shaft that has the at least one paddle mounted thereon is inserted into the container, and located in the bottom region in the container.

6 . The method of claim 5 , wherein the at least one paddle is located only in the bottom region in the container.

7 . The method of claim 5 , wherein the reacting the reactants by using the controlled crystallization method comprises rotating the at least one paddle, and a rotating speed of the at least one paddle is in a range from 900 rpm to 2000 rpm.

8 . The method of claim 1 , wherein at least ½ depth of the container is occupied by the reactants and the buffer agent.

9 . The method of claim 1 , wherein the cobalt salt solution is a water solution of a soluble cobalt salt, and the soluble cobalt salt is selected from the group consisting of cobalt chloride, cobalt sulfate, cobalt nitrate, and combinations thereof.

10 . The method of claim 1 , wherein the alkaline solution is selected from the group consisting of a water solution of potassium hydroxide, a water solution of sodium hydroxide, and a mixture thereof.

11 . The method of claim 1 , wherein a molar ratio between the cobalt salt and sodium hydroxide is about 12.

12 . The method of claim 1 , wherein in the adding the cobalt salt solution and the alkaline solution as the reactants into the buffer agent in the controlled crystallization reactor, a feeding amount per minutes of the reactants is in a range from 1/10000 to 1/300 of a volume of the container.

13 . The method of claim 1 , wherein the buffer agent is selected from the group consisting of ammonium hydroxide, ethylenediamine tetraacetic acid, lactic acid, and combinations thereof.

14 . The method of claim 1 , wherein the controlled crystallization reactor further comprises an overflow outlet located at an upper side of the container, when the spherical cobalt oxyhydroxide is thrown out the container from the overflow outlet.

15 . The method of claim 14 , wherein a diameter of the spherical cobalt oxyhydroxide is in a range from 5 μm to 20 μm.

16 . The method of claim 14 , wherein the adding of the cobalt salt solution and the alkaline solution and the agitating of the reactants in the controlled crystallization reactor are done at the same time and continuously performed, the spherical cobalt oxyhydroxide continuously overflows through the overflow outlet, and the cobalt salt solution and the alkaline solution are continuously added into the controlled crystallization reactor to maintain an amount of the reactants in the controlled crystallization reactor, thereby continuously forming the spherical cobalt oxyhydroxide.

Assignees

• Jiangsu Huadong Inst Of Li Ion Battery Co Ltd
• Univ Tsinghua

Inventors

• Fang Mou
• Wang yao-wu
• He xiang-ming
• Wang Li
• Shang yu-ming
• Gao Jian
• Guo Jian-Wei
• Mao zong-qiang

Classifications

• H01M4/48

  of inorganic oxides or hydroxides · CPC title

• H01M2220/30

  Batteries in portable systems, e.g. mobile phone, laptop · CPC title

• C01G51/04 Primary

  Oxides · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• C01P2004/32

  Spheres · CPC title