Single-layer and multilayer graphene, method of manufacturing the same, object including the same, and electric device including the same

Patent metadata

Field	Value
Publication number	US-11296322-B2
Application number	US-202016862651-A
Country	US
Kind code	B2
Filing date	Apr 30, 2020
Priority date	Jun 3, 2011
Publication date	Apr 5, 2022
Grant date	Apr 5, 2022

Abstract

Graphene is formed with a practically uniform thickness on an uneven object. The object is immersed in a graphene oxide solution, and then taken out of the solution and dried; alternatively, the object and an electrode are immersed therein and voltage is applied between the electrode and the object used as an anode. Graphene oxide is negatively charged, and thus is drawn to and deposited on a surface of the object, with a practically uniform thickness. After that, the object is heated in vacuum or a reducing atmosphere, so that the graphene oxide is reduced to be graphene. In this manner, a graphene layer with a practically uniform thickness can be formed even on a surface of the uneven object.

First claim

What is claimed is:

1. An electrode comprising:
a current collector;
an active material layer over the current collector, the active material layer having an uneven surface comprising projections and depressions; and
a plurality of graphene layers over the uneven surface,
wherein the active material layer comprises silicon,
wherein a first part of the plurality of graphene layers is in contact with the uneven surface,
wherein a space is formed between a second part of the plurality of graphene layers and one of the depressions of the uneven surface,
wherein a number of layers of the plurality of graphene layers is 50 or less,
wherein each of the plurality of graphene layers has at least one pore, and
wherein the pore of a first layer of the plurality of graphene layers does not overlap the pore of a second layer adjacent to the first layer of the plurality of graphene layers.

2. The electrode according to claim 1 ,
wherein the uneven surface comprises a plurality of silicon whiskers.

3. The electrode according to claim 2 ,
wherein the plurality of silicon whiskers comprise a first whisker and a second whisker; and
wherein the first part of the plurality of graphene layers connects the first whisker to the second whisker.

4. The electrode according to claim 1 ,
wherein a thickness of the plurality of graphene layers over the uneven surface is substantially uniform.

5. The electrode according to claim 1 ,
wherein a concentration of elements other than carbon and hydrogen contained in the plurality of graphene layers is lower than or equal to 15 atomic %, and
wherein a concentration of oxygen contained in the plurality of graphene layers is higher than or equal to 5 atomic % and lower than or equal to 15 atomic %.

6. A lithium-ion secondary battery comprising the electrode according to claim 1 , wherein the electrode is used as an electrode of the lithium-ion secondary battery.

7. An electrode comprising:
a current collector;
an active material layer over the current collector, the active material layer having an uneven surface comprising projections and depressions; and
a plurality of graphene layers over the uneven surface,
wherein the active material layer comprises silicon,
wherein a part of the plurality of graphene layers is in contact with the uneven surface,
wherein a number of layers of the plurality of graphene layers is 50 or less,
wherein each of the plurality of graphene layers has at least one pore, and
wherein the pore of a first layer of the plurality of graphene layers does not overlap the pore of a second layer adjacent to the first layer of the plurality of graphene layers.

8. The electrode according to claim 7 ,
wherein the uneven surface comprises a plurality of silicon whiskers.

9. The electrode according to claim 8 ,
wherein the plurality of silicon whiskers comprise a first whisker and a second whisker; and
wherein the part of the plurality of graphene layers connects the first whisker to the second whisker.

10. The electrode according to claim 7 ,
wherein the number of layers of the plurality of graphene layers over the uneven surface is substantially uniform.

11. The electrode according to claim 7 ,
wherein a concentration of elements other than carbon and hydrogen contained in the plurality of graphene layers is lower than or equal to 15 atomic %, and
wherein a concentration of oxygen contained in the plurality of graphene layers is higher than or equal to 5 atomic % and lower than or equal to 15 atomic %.

12. A lithium-ion secondary battery comprising the electrode according to claim 7 , wherein the electrode is used as an electrode of the lithium-ion secondary battery.

13. An electrode comprising:
a current collector;
an active material layer over the current collector, the active material layer having an uneven surface; and
a plurality of graphene layers over the uneven surface,
wherein the active material layer comprises silicon,
wherein a number of layers of the plurality of graphene layers is 20 or less,
wherein each of the plurality of graphene layers has at least one pore, and
wherein the pore of a first layer of the plurality of graphene layers does not overlap the pore of a second layer adjacent to the first layer of the plurality of graphene layers.

14. The electrode according to claim 13 ,
wherein the uneven surface comprises a plurality of silicon whiskers.

15. The electrode according to claim 14 ,
wherein the plurality of silicon whiskers comprise a first whisker and a second whisker; and
wherein a part of the plurality of graphene layers connects the first whisker to the second whisker.

16. The electrode according to claim 13 ,
wherein the number of layers of the plurality of graphene layers over the uneven surface is substantially uniform.

17. The electrode according to claim 13 ,
wherein a thickness of the plurality of graphene layers over the uneven surface is substantially uniform.

18. A lithium-ion secondary battery comprising the electrode according to claim 13 , wherein the electrode is used as an electrode of the lithium-ion secondary battery.

Assignees

• Semiconductor Energy Lab

Inventors

• Oguni Teppei
• Osada Takeshi
• Takeuchi Toshihiko
• Nomoto Kuniharu

Classifications

• C25D13/16

  Wires; Strips; Foils · CPC title

• B82Y40/00

  Manufacture or treatment of nanostructures · CPC title

• B82Y30/00

  Nanotechnology for materials or surface science, e.g. nanocomposites · CPC title

• H01M4/1393

  of electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx · CPC title

• Y10T428/24355

  Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.] · CPC title