Adhesive resin composition and laminate

Patent metadata

Field	Value
Publication number	US-11292945-B2
Application number	US-201917046626-A
Country	US
Kind code	B2
Filing date	Apr 5, 2019
Priority date	Apr 25, 2018
Publication date	Apr 5, 2022
Grant date	Apr 5, 2022

Abstract

An adhesive resin composition of the invention includes an ethylene polymer (A) including an ethylene polymer graft-modified with an unsaturated carboxylic acid or a derivative thereof, and satisfies the following requirements (1) to (4). (1) The melt flow rate (MFR) measured at a temperature of 190° C. and a load of 2160 g in accordance with ASTM D 1238 is 0.1 to 3 g/10 min. (2) The density is 910 to 930 kg/m3. (3) The proportion of fractions that elute at 50° C. and below in crystallization elution fractionation chromatography measurement is not less than 20 mass %. (4) The proportion of fractions that elute at 90° C. and above in crystallization elution fractionation chromatography measurement is not less than 25 mass %.

First claim

The invention claimed is:

1. An adhesive resin composition comprising an ethylene polymer (A) comprising an ethylene polymer graft-modified with an unsaturated carboxylic acid or a derivative thereof, the adhesive resin composition satisfying the following requirements (1) to (4),
wherein the ethylene polymer (A) comprises an ethylene polymer (A1) described below and an ethylene polymer (A2) described below, and
at least one of the ethylene polymer (A1) and the ethylene polymer (A2) comprises an ethylene polymer graft-modified with an unsaturated carboxylic acid or a derivative thereof:
(1) the melt flow rate (MFR) measured at a temperature of 190° C. and a load of 2160 g in accordance with ASTM D 1238 is 0.1 to 3 g/10 min,
(2) the density is 910 to 930 kg/m 3 ,
(3) the proportion of fractions that elute at 50° C. and below in crystallization elution fractionation chromatography measurement is not less than 20 mass %, and
(4) the proportion of fractions that elute at 90° C. and above in crystallization elution fractionation chromatography measurement is not less than 25 mass %;
(A1) the ethylene polymer has a density of 930 to 965 kg/m 3 and a melt flow rate (MFR) of 0.1 to 10 g/10 min as measured at a temperature of 190° C. and a load of 2160 g in accordance with ASTM D 1238,
(A2) the ethylene polymer has a density of 858 to 929 kg/m 3 and a melt flow rate (MFR) of 0.1 to 10 g/10 min as measured at a temperature of 190° C. and a load of 2160 g in accordance with ASTM D 1238.

2. The adhesive resin composition according to claim 1 , wherein the ethylene polymer (A) comprises 20 to 40 mass % of the ethylene polymer (A1) and 60 to 80 mass % of the ethylene polymer (A2) the proviso that the total of the ethylene polymer (A1) and the ethylene polymer (A2) is 100 mass %.

3. A laminate comprising a layer (I) including an ethylene polymer, an adhesive layer (II) including an adhesive resin composition described in claim 1 , and a layer (III) including an ethylene/vinyl alcohol copolymer and/or a layer (IV) including a polyamide resin, the layer (II) being in direct contact with at least one of the layer (III) and the layer (IV).

4. The laminate according to claim 3 , wherein the ethylene/vinyl alcohol copolymer is a polymer obtained by saponifying an ethylene/vinyl acetate copolymer having a content of ethylene-derived structural units of 20 to 30 mol %.

5. The laminate according to claim 3 , wherein the ethylene/vinyl alcohol copolymer is a polymer further including 10 to 40 mass % of a styrene elastomer.

6. The laminate according to claim 3 , wherein the polyamide resin comprises at least one of nylon 6, nylon 66, nylon 610, nylon 12, nylon 11, MXD nylon, amorphous nylons and copolymer nylons.

7. A film comprising a laminate described in claim 3 .

8. A bag comprising a film described in claim 7 .

9. A packaging container comprising a laminate described in claim 3 .

Assignees

• Mitsui Chemicals Inc

Inventors

• Iwashita Akihiko
• Ogawa Yoshiyuki

Classifications

• B32B7/12

  using interposed adhesives or interposed materials with bonding properties · CPC title

• B32B27/32

  comprising polyolefins {(comprising vinyl (co)polymers or acrylic (co)polymers B32B27/30)} · CPC title

• B32B2307/7242

  Non-permeable · CPC title

• B32B27/34

  comprising polyamides · CPC title

• C09J123/26 Primary

  modified by chemical after-treatment · CPC title