Three-dimensional printing

Patent metadata

Field	Value
Publication number	US-11292189-B2
Application number	US-201716488715-A
Country	US
Kind code	B2
Filing date	Nov 17, 2017
Priority date	Nov 17, 2017
Publication date	Apr 5, 2022
Grant date	Apr 5, 2022

Abstract

In an example of a method for three-dimensional (3D) printing, a polymeric or polymeric composite build material is applied. A dielectric agent is selectively applied on at least a portion of the polymeric or polymeric composite build material. The dielectric agent includes a dielectric material having an effective relative permittivity (εr) value ranging from 1.1 to about 10,000. A fusing agent is selectively applied on the at least the portion of the polymeric or polymeric composite build material, and the polymeric or polymeric composite build material is exposed to radiation to fuse the at least the portion of the polymeric or polymeric composite build material to form a region of a layer of a 3D part. The region exhibits a dielectric property, a piezoelectric property, or a combination thereof.

First claim

What is claimed is:

1. A method for three-dimensional (3D) printing, comprising:
applying a polymeric or polymeric composite build material;
selectively applying a dielectric agent on at least a portion of the polymeric or polymeric composite build material, the dielectric agent having a potential hydrogen (pH) value ranging from about 7 to about 9 and including a dielectric material having an effective relative permittivity (ε r ) value ranging from 1.1 to about 10,000;
based on a 3D object model, selectively applying a fusing agent on the at least the portion of the polymeric or polymeric composite build material; and
exposing the polymeric or polymeric composite build material to radiation to fuse the at least the portion of the polymeric or polymeric composite build material to form a region of a layer of a 3D part, wherein the region exhibits a dielectric property, a piezoelectric property, or a combination thereof.

2. The method as defined in claim 1 wherein the effective ε r value ranges from about 2 to about 80.

3. The method as defined in claim 1 wherein the effective ε r value ranges from about 3 to about 10.

4. The method as defined in claim 1 wherein the region exhibits the dielectric property, the piezoelectric property, or the combination at a frequency ranging from greater than 0 Hz to about 80 GHz.

5. The method as defined in claim 1 wherein:
the at least the portion is less than all of the polymeric or polymeric composite build material;
the method further comprises selectively applying, based on the 3D object model, the fusing agent on an other portion of the polymeric or polymeric composite build material; and
during the exposing, the other portion of the polymeric or polymeric composite build material fuses to form a remaining region of the layer of the 3D part.

6. The method as defined in claim 5 wherein the remaining region does not exhibit a dielectric property or a piezoelectric property.

7. The method as defined in claim 1 wherein the dielectric material is selected from the group consisting of barium titanate nanoparticles, lead zirconium titanate nanoparticles, silicon dioxide nanoparticles, silicon nitride nanoparticles, aluminum oxide nanoparticles, zirconium oxide nanoparticles, titanium oxide nanoparticles, tantalum pentoxide nanoparticles, barium strontium titanate nanoparticles, strontium titanate oxide nanoparticles, and combinations thereof.

8. The method as defined in claim 1 wherein the dielectric material has an average particle size ranging from about 10 nm to about 150 nm.

9. The method as defined in claim 1 wherein the dielectric material is present in the dielectric agent in an amount ranging from about 2 wt % to about 50 wt %, based on a total weight of the dielectric agent.

10. The method as defined in claim 1 wherein the dielectric agent further includes:
water;
a co-solvent; and
a surfactant.

11. A method for three-dimensional (3D) printing, comprising:
applying a polymeric or polymeric composite build material;
selectively applying a dielectric agent on a portion of the polymeric or polymeric composite build material, the dielectric agent having a potential hydrogen (pH) value ranging from about 7 to about 9 and including a dielectric material having an effective relative permittivity (ε r ) value ranging from 1.1 to about 10,000;
based on a 3D object model, selectively applying a fusing agent on a section of the polymeric or polymeric composite build material, the section including at least the portion;
exposing the polymeric or polymeric composite build material to radiation to fuse the section of the polymeric or polymeric composite build material to form a layer of a 3D part, wherein the portion of the polymeric or polymeric composite build material forms a region of the layer, and wherein the region of the layer exhibits a dielectric property, a piezoelectric property, or a combination thereof; and
repeating the applying of the polymeric or polymeric composite build material, the selectively applying of the dielectric agent, the selectively applying of the fusing agent, and the exposing, wherein the repeating forms the 3D part including the layer.

12. The method as defined in claim 11 wherein the effective ε r value ranges from about 3 to about 10.

13. A dielectric agent, consisting of:
a dielectric material having an effective relative permittivity (ε r ) value ranging from 1.1 to about 10,000;
water;
a co-solvent;
a surfactant;
a radiation absorber in an amount ranging from 0 wt % to about 12 wt %, based on a total weight of the dielectric agent; and
an anti-kogation agent in an amount ranging from 0 wt % to about 0.65 wt %, based on the total weight of the dielectric agent;
wherein a potential hydrogen (pH) value of the dielectric agent ranges from about 7 to about 9.

14. The dielectric agent as defined in claim 13 wherein the effective ε r value ranges from about 3 to about 10.

15. A method for three-dimensional (3D) printing, comprising:
first, applying a polymeric or polymeric composite build material;
then, based on a 3D object model, selectively applying a fusing agent on at least a portion of the polymeric or polymeric composite build material;
then, selectively applying a dielectric agent on the at least the portion of the polymeric or polymeric composite build material, the dielectric agent having a potential hydrogen (pH) value ranging from about 7 to about 9 and including a dielectric material having an effective relative permittivity (ε r ) value ranging from 1.1 to about 10,000; and then
exposing the polymeric or polymeric composite build material to radiation to fuse the at least the portion of the polymeric or polymeric composite build material to form a region of a layer of a 3D part, wherein the region exhibits a dielectric property, a piezoelectric property, or a combination thereof.

Assignees

• Hewlett Packard Development Co

Inventors

• Van Brocklin Andrew
• Dekam Kevin P
• Kasperchik Vladek
• Holroyd Johnathon
• Pederson Douglas
• Chaffins Sterling

Classifications

• B33Y70/10

  Composites of different types of material, e.g. mixtures of ceramics and polymers or mixtures of metals and biomaterials · CPC title

• B82Y30/00

  Nanotechnology for materials or surface science, e.g. nanocomposites · CPC title

• B33Y10/00

  Processes of additive manufacturing · CPC title

• B29C64/165 Primary

  using a combination of solid and fluid materials, e.g. a powder selectively bound by a liquid binder, catalyst, inhibitor or energy absorber · CPC title

• B29K2995/0006

  Dielectric · CPC title