Acidic gas absorbent, acidic gas removal method and acidic gas removal apparatus

Patent metadata

Field	Value
Publication number	US-11291948-B2
Application number	US-201916297163-A
Country	US
Kind code	B2
Filing date	Mar 8, 2019
Priority date	Sep 18, 2018
Publication date	Apr 5, 2022
Grant date	Apr 5, 2022

Abstract

The embodiments provide an acidic gas absorbent having low diffusibility, an acidic gas removal method, and an acidic gas removal apparatus. The acidic gas absorbent according to the embodiment comprises: an amine compound having a vapor pressure of 0.001 to 10 Pa at 20° C.; a water-soluble polymer compound having a mass-average molecular weight of 900 to 200000 and not containing a functional group having a pKa value greater than 7 except for hydroxy; and water.

First claim

The invention claimed is:

1. An acidic gas absorbent comprising:
an aminoalcohol having a vapor pressure of 0.005 to 5 Pa at 20° C.;
a water-soluble polymer compound which has a mass-average molecular weight of 900 to 20000) and which does not contain a functional group having a pKa value greater than 7 except for hydroxy; and
water,
wherein
said water-soluble polymer compound is at least one selected from the group consisting of carboxy vinyl polymer, alkali metal salts of carboxy vinyl polymer, polyvinyl alcohol, carboxymethyl cellulose, methyl cellulose, alginic acid, and polysaccharide, and
said absorbent comprises the aminoalcohol in an amount of 5 to 80 wt % based on a total mass of the absorbent.

2. The acidic gas absorbent according to claim 1 , wherein the aminoalcohol is methyldiethanolamine.

3. The acidic gas absorbent according to claim 1 , which has a viscosity of 10 to 200 mPa·s at 20° C. before brought into contact with an acidic gas.

4. The acidic gas absorbent according to claim 1 , which contains said water-soluble polymer compound in an amount of 0.001 to 1 wt % provided that the whole amount of the absorbent is regarded as 100 wt %.

5. The acidic gas absorbent according to claim 1 , further comprising at least one additive agent selected from the group consisting of oxidation inhibitors, pH adjusters, defoaming agents, and anticorrosive agents.

6. An acidic gas removal method, comprising: contacting a gas containing an acidic gas with the acidic gas absorbent according to claim 1 so as to remove the acidic gas from the acidic gas-containing gas.

7. An acidic gas removal apparatus comprising:
an absorption unit in which a gas containing an acidic gas is brought into contact with the acidic gas absorbent according to claim 1 , so that the absorbent absorbs the acidic gas to remove it from the acidic gas-containing gas; and
a regeneration unit in which the absorbent holding the acidic gas is made to desorb the acidic gas so as to be regenerated;
so that the absorbent regenerated in the regeneration unit is reused in the absorption unit.

Assignees

• Toshiba Kk
• Toshiba Energy Systems & Solutions Corp

Inventors

• Suzuki Akiko
• Nakano Yoshihiko
• Yoshimura Reiko
• Imada Toshihiro
• Kuboki Takashi
• Sano Kenji
• Udatsu Mitsuru

Classifications

• B01D2252/504

  Mixtures of two or more absorbents · CPC title

• B01D2252/20489

  with two or more hydroxyl groups · CPC title

• B01D53/62

  Carbon oxides · CPC title

• B01D53/1493

  Selection of liquid materials for use as absorbents · CPC title

• B01D53/78 Primary

  with gas-liquid contact · CPC title