Solvent recovery from sweep gas streams

Patent metadata

Field	Value
Publication number	US-11291944-B2
Application number	US-201716473882-A
Country	US
Kind code	B2
Filing date	Dec 19, 2017
Priority date	Dec 28, 2016
Publication date	Apr 5, 2022
Grant date	Apr 5, 2022

Abstract

A method for removing solvent from a solvent containing sweep gas stream obtained from a fertilizer coating process is disclosed. The method can include directly contacting the solvent containing sweep gas stream with an aqueous composition comprising 50% wt/wt to 100% wt/wt of water, condensing at least a portion of the solvent out of the solvent containing sweep gas stream into the aqueous composition to produce a solvent-enriched aqueous composition and a recovered sweep gas stream, and removing the recovered sweep gas stream from the solvent-enriched aqueous composition.

First claim

The invention claimed is:

1. A method for removing solvent from a solvent containing sweep gas stream obtained from a fertilizer coating process, the method comprising:
(a) directly contacting the solvent containing sweep gas stream with an aqueous composition comprising 50% wt/wt to 100% wt/wt of water;
(b) condensing at least a portion of the solvent out of the solvent containing sweep gas stream into the aqueous composition to produce a solvent-enriched aqueous composition and a recovered sweep gas;
(c) removing the recovered sweep gas from the solvent-enriched aqueous composition; and
(d) contacting the solvent-enriched aqueous composition with steam to separate at least a portion of the solvent from the solvent-enriched aqueous composition to produce a recovered solvent and a recovered aqueous composition.

2. The method of claim 1 , further comprising recycling at least a portion of:
(i) the recovered sweep gas as sweep gas in the fertilizer coating process;
(ii) the recovered aqueous composition for use in the aqueous composition in step (a); and/or
(iii) the recovered solvent as solvent in the fertilizer coating process.

3. The method of claim 1 , wherein all or a part of any remaining water in the recovered solvent is further removed from the recovered solvent.

4. The method of claim 3 , wherein all or a part of any remaining water is removed by physisorption or chemisorption, or a combination thereof.

5. The method of claim 1 , wherein the solvent in the solvent containing sweep gas stream is an organic solvent.

6. The method of claim 5 , wherein the organic solvent comprises chloroform, toluene, methylene chloride, acetonitrile, 1,1,2-trichloroethane, dichlorobenzene, or methyl ethyl ketone, or any combination thereof.

7. The method of claim 1 , wherein a sweep gas in the solvent containing sweep gas stream comprises carbon dioxide (CO 2 ), flue gas, or air, or any combination thereof.

8. The method of claim 1 , wherein the temperature of the aqueous composition in step (a) is 4° C. to 50° C.

9. The method of claim 1 , wherein the flow rate of the solvent containing sweep gas stream in step (a) is 0.5 to 2.5 MT solvent containing sweep gas/MT of a fertilizer to be coated.

10. The method of claim 9 , wherein the temperature and pressure of the solvent containing sweep gas stream in step (a) are 40° C. to 150° C. and 0.5 to 3 atmospheres (0.05 to 0.3 MPa), respectively.

11. The method of claim 1 , wherein the fertilizer coating process used to obtain the solvent containing sweep gas stream comprises:
(i) contacting fertilizer particles with a liquid composition comprising a coating material and the solvent in an interior volume of a coating container having a side wall to obtain coated fertilizer particles;
(ii) evaporating the solvent from the coated fertilizer particles by heating the coated fertilizer particles; and
(iii) removing the evaporated solvent from the interior volume of the coating container with a sweep gas to produce the solvent containing sweep gas stream.

12. The method of claim 11 , wherein the sweep gas is heated and wherein the solvent is evaporated from the coated fertilizer particles by contacting the coated particles with the heated sweep gas.

13. The method of claim 11 , wherein the coated fertilizer particles are heated: (a) with electromagnetic radiation to evaporate the solvent by heating the coated particles directly and/or with electromagnetic radiation to evaporate the solvent by heating the particles indirectly through heating the coating container and/or an internal container therein containing the fertilizer particles and/or the coated fertilizer particles, wherein the internal container is disposed in the interior volume of the coating container; (b) with heat generated from an external heat source that is positioned outside of the interior volume of the coating container and is configured to externally heat a portion of the side wall of the coating container and/or internal container to evaporate the solvent; and/or (c) with heat generated from a heat source internal to the coating container and configured to heat the internal container.

14. The method of claim 13 , wherein the coated fertilizer particles are heated with electromagnetic radiation to evaporate the solvent, the electromagnetic radiation comprising or consisting of ultraviolet radiation or infrared radiation, or a combination thereof.

15. The method of claim 13 , wherein the fertilizer particles are moved from a location where the fertilizer particles are contacted with the liquid composition to a location where the coated fertilizer particles are heated and wherein an electromagnetic radiation source is positioned downstream from where the liquid composition contacts the fertilizer particles in step (i).

16. The method of claim 11 , wherein the coated fertilizer particles are heated with heat generated from an external heat source that is positioned outside of the interior volume of the coating container to evaporate the solvent, wherein the fertilizer particles are moved from a location where the fertilizer particles are contacted with the liquid composition to a location where the coated fertilizer particles are heated, and wherein the external heat source is positioned downstream from where the liquid composition contacts the fertilizer particles in step (i).

17. A method for removing solvent from a solvent containing sweep gas stream obtained from a fertilizer coating process, the method comprising:
(a) directly contacting the solvent containing sweep gas stream with an aqueous composition comprising 50% wt/wt to 100% wt/wt of water;
(b) condensing at least a portion of the solvent out of the solvent containing sweep gas stream into the aqueous composition to produce a solvent-enriched aqueous composition and a recovered sweep gas; and
(c) removing the recovered sweep gas from the solvent-enriched aqueous composition, wherein the fertilizer coating process used to obtain the solvent containing sweep gas stream comprises:
(i) contacting fertilizer particles with a liquid composition comprising a coating material and the solvent in an interior volume of a coating container having a side wall to obtain coated fertilizer particles;
(ii) moving the coated fertilizer particles away from the location where the liquid composition contacts the fertilizer particles in step (i);
(iii) evaporating the solvent from the coated fertilizer particles by heating the coated fertilizer particles with heat generated from a heat source positioned external to an internal container containing the coated fertilizer particles, the heat source configured to heat the internal container, wherein the internal container is comprised in the interior volume of the coating container, and wherein the heat source is positioned downstream from where the liquid composition contacts the fertilizer particles in step (i); and
(iv) removing the evaporated solvent from the interior volume of the coating container with a sweep gas to produce the solvent containing sweep gas stream.

Assignees

• Sabic Global Technologies Bv

Inventors

• Uraizee Farooq
• Tirtowidjojo Danil
• Rameswaran Ramesh
• Chandrasekaran Jayachandran

Classifications

• C05C9/005

  Post-treatment · CPC title

• F26B3/28 Primary

  by radiation, e.g. from the sun · CPC title

• B01D53/77

  Liquid phase processes · CPC title

• B01D53/72

  Organic compounds not provided for in groups B01D53/48 - B01D53/70, e.g. hydrocarbons · CPC title

• B01D5/0027

  by direct contact between vapours or gases and the cooling medium · CPC title