Aqueous surface treatment composition for paper and board

Patent metadata

Field	Value
Publication number	US-11286621-B2
Application number	US-201615752285-A
Country	US
Kind code	B2
Filing date	Aug 12, 2016
Priority date	Aug 14, 2015
Publication date	Mar 29, 2022
Grant date	Mar 29, 2022

Abstract

Embodiments disclosed herein provide enzymatic formulations comprising a polypeptide having amylase activity for producing a paper product. Also provided are aqueous surface treatment compositions for paper and board comprising degraded starch. Further provided are methods for producing paper and board using the aqueous surface treatment composition, and to corrugated boards produced from this paper.

First claim

The invention claimed is:

1. An aqueous surface treatment composition for paper and board, the composition comprising from 1 to 40 wt % of a degraded starch having a weight-average molecular weight Mw of from 10,000 to 12,000,000 and a polydispersity index (Mw/Mn) of from 1.3 to 49 wherein Mn is a number averaged molecular weight and Mw is a weight-average molecular weight,
wherein the degraded starch is obtained by a method comprising:
a) preparing a suspension of water and starch,
b) adding an enzymatic formulation comprising from 0.0001 wt % to 1 wt % of a polypeptide having an amylase activity, based on the total weight of the starch, hereby obtaining a mixture, and
c) heating the mixture to a temperature of from 60 to 100° C. for from 5 to 60 minutes, thereby obtaining the degraded starch which is enzymatically and thermally treated starch, and
wherein the polypeptide having an amylase activity comprises the amino acid sequence of SEQ ID NO:12.

2. The aqueous surface treatment composition of claim 1 , wherein the degraded starch has a weight-average molecular weight Mw of from 400,000 to 12,000,000 and a polydispersity index (Mw/Mn) of from 10 to 49.

3. The aqueous surface treatment composition of claim 1 , wherein the enzymatic formulation further comprises at least one selected from the group consisting of a glucoamylase and a debranching enzyme.

4. The aqueous surface treatment according to of claim 3 , wherein:
the enzymatic formulation further comprises a debranching enzyme; and
the debranching enzyme is a hemicellulase, an isoamylase, a beta amylase, a gamma amylase, an exo-amylase, a pullulanase, a xylanase, a mannanase, an alpha gluconase, an endocellulase, an exocellulase, or a combination thereof.

5. The aqueous surface treatment composition of claim 1 , wherein the enzymatic formulation further comprises a protease, a lipase, a peroxidase, a laccase, a tyrosinase, a cellubiohydrolase, a glucose oxidase; a transferase, a glycosyl transferase, a pectinase, an esterase, a cellobiose oxidoreductase, a glyoxal oxidase, an epimerase, an invertase, a chlorophyllase, or a combination thereof.

6. The aqueous surface treatment composition of claim 1 , comprising from 2 to 30 wt % of the degraded starch.

7. The aqueous surface treatment composition of claim 1 , wherein the degraded starch has a weight-average molecular weight Mw of from 400,000 to 5,000,000 and a polydispersity index (Mw/Mn) of from 10 to 49.

8. The aqueous surface treatment composition of claim 1 , wherein the composition comprises the degraded starch in an amount in a range of 3 to 25 wt%.

9. The aqueous surface treatment composition of claim 1 , wherein the composition comprises the degraded starch in an amount in a range of 6 to 12 wt%.

10. The aqueous surface treatment composition of claim 9 , wherein the composition has a viscosity of 3 to 90 mPas at 80° C., 100 rpm.

11. A method for producing paper and board, the method comprising:
a) treating a paper stock with a paper auxiliary, a filler, or a combination thereof,
b) draining the paper stock treated by a), with a sheet formation, thereby obtaining a paper web, and
c) treating the paper web obtained by b) with the surface treatment composition of claim 1 , and
d) drying the paper web treated in c), thereby producing paper and board.

12. The method according to claim 11 , wherein the degraded starch of the surface treatment composition has a weight-average molecular weight Mw of from 400,000 to 12,000,000 and a polydispersity index (Mw/Mn) of from 10 to 49 and the surface treatment composition is applied by size press application technique.

13. The method according to claim 12 , wherein the degraded starch of the surface treatment composition has a weight-average molecular weight Mw of from 400,000 to 500,000 and a polydispersity index (Mw/Mn) of from 10 to 49 and the surface treatment composition is applied by film-press application technique.

14. A paper and board obtained by the method according to claim 11 .

15. A corrugated board produced from the paper and board of claim 14 .

16. A method for producing the aqueous surface treatment composition of claim 1 for paper or board, the method comprising: (a) providing a polypeptide having an amylase activity, wherein the polypeptide comprises the amino acid sequence of SEP ID NO: 12;
(b) preparing a suspension of water and a starch:
(c) adding an enzymatic formulation comprising from 0,0001 wt % to 1 wt % of the polypeptide, based on the total weight of the starch, hereby obtaining a mixture, and
(d) heating the mixture to a temperature of from 60 to 100° C. for from 5 to 60 minutes to hydrolyzing the starch and to obtain a degraded starch winch is enzymatically and thermally treated, thereby producing the aqueous paper surface treatment composition of claim 1 , the composition comprising from 1 to 40 wt % of the degraded starch having a weight-average molecular weight (Mw) of from 10,000 to 12,000,000 and a polydispersity index (Mw/Mn) of from 1.3 to 49,
wherein Mn is a number averaged molecular weight and Mw is a weight-average molecular weight.

17. The method according to claim 16 , wherein the paper surface treatment composition comprises from 2 to 30 wt % of the degraded starch.

18. The method according to claim 16 , wherein the degraded starch has a weight-average molecular weight Mw of from 400,000 to 5,000,000 and a polydispersity index (Mw/Mn) of from 10 to 49.

19. The method according to claim 16 , wherein the enzymatic formulation comprises from 0.01 ppm to 1000 ppm of the polypeptide, based on the weight of the starch.

20. The method according to claim 13 , further comprising providing a protease, a lipase, a peroxidase, a laccase, a tyrosinase, a cellobiohydrolase, a glucose oxidase, a transferase, a glycosyl transferase, a pectinase, an esterase, a cellobiose oxidoreductase, a glyoxal oxidase, an epimerase, an invertase, a chlorophyllase, or any combination thereof.

21. The method according to claim 16 , further comprising providing a glucoamylase, a debranching enzyme, or a combination thereof.

22. The method according to claim 21 , wherein the debranching enzyme is contained and is a hemicellulase, an isoamylase, a beta amylase, a gamma amylase, an exo-amylase, a pullulanase, a xylanase, a mannanase, an alpha gluconase, an endocellulase, an exocellulase, or a combination thereof.

23. The method according to claim 16 , wherein the starch is from rice, corn, barley, wheat, legumes, potato, Tapioca, soybean oat, rye, beet or sugar cane.

24. The method according to claim 16 , comprising inactivating the polypeptide having an amylase activity.

Assignees

• Basf Se

Inventors

• Hamers Christoph
• Karanikas Konstantino
• Barrett Kenneth
• Tan Zheng

Classifications

• D21H21/18

  Reinforcing agents · CPC title

• C12P19/16

  produced by the action of an alpha-1, 6-glucosidase, e.g. amylose, debranched amylopectin (non-biological hydrolysis of starch C08B30/00) · CPC title

• D21H27/40

  at least one of the sheets being non-planar, e.g. crêped (crêping or corrugating paper B31F) · CPC title

• C12P19/18

  produced by the action of a glycosyl transferase, e.g. alpha-, beta- or gamma-cyclodextrins · CPC title

• D21H17/28 Primary

  Starch · CPC title